CAS: 3032-81-3; 1,3-Dichloro-5-Iodobenzene

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CAS号626-43-7 3,5-二氯苯胺 | CAS号108-70-3 均三氯苯 | CAS号68716-51-8 3,5-二氯苯硼酸频哪醇酯 | CAS号541-73-1 间二氯苯 | CAS号19752-55-7 3,5-二氯-1-溴苯 | CAS号618-62-2 3,5-二氯硝基苯 | CAS号554-00-7 2,4-二氯苯胺 | CAS号697-90-5 2,4-二氯-6-碘苯胺 | CAS号41464-42-0 2,3',5,5'四氯联苯 | CAS号37680-68-5 2',3,5-三氯联苯 | CAS号54773-20-5 3,5-二氯三氟甲苯 | CAS号39635-32-0 2,3,3',5,5'-五氯联苯 | CAS号56558-18-0 2,3',4,5',6-五氯联苯 | CAS号39652-34-1 3,5-二氯-4-甲基苯甲酸 | CAS号38444-88-1 3,4',5-三氯联苯 | CAS号20595-53-3 (E)-3-(3,5-二氯苯基)丙烯酸 | CAS号33284-52-5 3,3',5,5'-四氯联苯 | CAS号73575-52-7 2,3',4,5'-四氯联苯

1,3-二氯苯置于copper(L) Iodide,1,10-菲罗啉,(1,5-Cyclooctadiene)(Methoxy)Iridium(I) Dimer,4,4'-Di-Tert-Butyl-2,2'-Bipyridine,Potassium Iodide体系中,用 四氢呋喃,甲醇,水 用作溶剂,化学反应 25.0H,反应生成3,5-二氯碘苯
参考文献:通过铱催化的c-h硼化作用对芳烃进行立体控制的碘化
标题:通过铱催化的c-h硼化作用对芳烃进行立体控制的碘化
摘要:报道了一种通过连续的c-h硼化和碘化制备芳基和杂芳基碘化物的温和方法.该过程的区域选择性由c-h硼化步骤中的空间效应控制,是对现有形成芳基碘化物的方法的补充.硼酸酯的碘化具有放射性标记的芳基碘化物的合成潜力,正如spect成像的潜在示踪剂的简明合成所证明的那样.
Doi:10.1021/ol303164H

专利信息

专利号:US-8114993-B2
优先权日:2007-02-06
标题:Use of aryl chlorides in palladium-catalyzed C-H bond functionalization
发明人：DAUGULIS OLAFS; CHIONG HENDRICH
权利人:DAUGULIS OLAFS; CHIONG HENDRICH; UNIV HOUSTON SYSTEM
摘要:A one-step method for efficiently converting carbon-hydrogen bonds into carbon-carbon bonds using chloroarenes and palladium catalysts is disclosed. This method allows faster introduction of complex molecular entities, a process that would otherwise require many more steps. This invention is particularly relevant for the organic synthesis of complex molecules such as, but not limited to, pharmacophores.

专利号:US-4652584-A
优先权日:1984-07-13
标 题 :Acetylenic phenoxypropanol derivatives and pharmaceutical compositions for the treatment of hypertension
发明人：CARSON JOHN R
权利人:MCNEILAB INC
摘要:Phenoxypropanol derivatives having a 2-acetylenic moiety on the phenyl group thereof of the following formula (I): ##STR1## and their use as anti-hypertensives, e.g. in man. Also part of the invention are pharmaceutical compositions and intermediates used in the synthesis.

专利号:EP-3210987-A1
优先权日:2007-08-06
标 题:Process for the synthesis of proteasome inhibitors

专利号:CN-116425623-A
优先权日:2023-04-10
标 题:Method for one-pot synthesis of 3,5-dichloro-4-methylbenzoic acid

专利号:US-4742084-A
优先权日:1983-11-21
标 题 :Aralykyl (arylethynyl)aralkyl amines and their use as vasodilators and antihypertensives
发明人：CARSON JOHN R
权利人:MCNEILAB INC
摘要:Acetylenes of the formula (I): (I) wherein Y, m, R1, R2, q, Alk, R3 n and R4 are as defined herein and Ar1 and Ar2 are aromatic, including the salts and ammonium derivatives of formula (I), in treating angina, hypertension and cardiac arrhythmias. Pharmaceutical compositions, methods of use and synthesis and novel intermediates are also part of the invention.

专利号:US-4661635-A
优先权日:1983-11-21
标题 :Aralykyl (arylethynyl)aralkyl amines and their use as vasodilators and antihypertensives
发明人：CARSON JOHN R
权利人:MCNEILAB INC
摘要:Acetylenes of the formula (I): (I) wherein Y, m, R1, R2+L, q, Alk, R3, n and R4 are as defined herein and Ar1 and Ar2 are aromatic, including the salts and ammonium derivatives of formula (I), in treating angina, hypertension and cardiac arrhythmias. Pharmaceutical compositions, methods of use and synthesis and novel intermediates are also part of the invention.