CAS: 179101-81-6; Pyridalyl

化学文摘社编号179101-81-6,主要用作农业应用中的杀虫剂,属于被称为衍生物的化学品类别,具有独特的分子结构,包括一个环;盘旋醇针对各种害虫,特别是控制青蒿素昆虫,展示了范围广泛的活动,使其在作物保护方面变得宝贵;其行动方式涉及干扰昆虫...

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3,5-dichloro-4-(3-hydroxypropyloxy)-1-(3,3-dichloro-2-propenyloxy)benzene 2-chloro-5-trifluoromethylpyridine 3,3-dichloroallyl chloride

合成工艺路线路线简述

    3,5-Dichloro-4-(3-(5-Trifluoromethyl-2-Pyridyloxy)Propoxy)Phenol,1,1,3-三氯丙烯置于potassium Carbonate体系中,用 N,N-二甲基甲酰胺 用作溶剂,以47%的收率获得三氟甲吡醚
    参考文献:Dihalopropene Compounds,Insecticidal/acaricidal Agents Containing Same,
    标题:Dihalopropene Compounds,Insecticidal/acaricidal Agents Containing Same,
    摘要:通式为\x9Bi!的二卤代丙烯化合物具有优异的杀虫/杀螨活性,因此它们对于控制有害昆虫,螨和蜱是相当有效的.

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    专利信息


    专利号:WO-2025056767-A1
    优先权日:2023-09-15
    标题 :Process for the preparation of enantiomerically enriched aliphatic amines
    发明人:BOU HAMDAN FARHAN; GODINEAU EDOUARD; SMEJKAL TOMAS; DUMEUNIER RAPHAEL; BOUSSEMGHOUNE MOHAMED ABDELOUAHAB; BLUM MATHIAS
    权利人:SYNGENTA CROP PROTECTION AG
    摘要:The present invention relates to a process for the preparation of enantiomerically enriched cyclobutylamines of formula (I) from α-tertiary cyclobutanones and reacting said enantiomerically enriched cyclobutylamines to enantiomerically enriched cyclobutylamides. Such compounds are useful intermediates in the synthesis of microbiocidal thiazole compounds.

    专利号:US-2007232495-A1
    优先权日:2006-03-24
    标题:Compositions and methods to add value to plant products, increasing the commercial quality, resistance to external factors and polyphenol content thereof
    发明人:NAPPA ALVARO O; LORENZINI FELIPE C; SANHUEZA ANDRES L
    权利人:NAPPA ALVARO O; LORENZINI FELIPE C; SANHUEZA ANDRES L
    摘要:The invention is related to compositions and methods that naturally protect plant tissues against ultraviolet radiation and temperature, thus giving protection against sunburn to plants, plant parts, fruits and/or flowers during their development. The invention is also related to compositions and methods to naturally improve the color of plants, plant parts, fruits and/or flowers by inducing the natural synthesis of flavonoids and anthocyanins present in plants. Likewise, the present invention is directed to improving the nutritional value of plants, plant parts, fruits and/or flowers by increasing the normal levels of polyphenolic compounds, especially flavonoids, present therein. Additionally, the present invention is related to compositions and methods that give more resistance to plants, plant parts, fruits and/or flowers against pathogens as bacteria and fungi. Finally, the present invention is related to plants, plant parts, fruits, flowers and/or propagating material treated with the compositions described in the present document.

    专利号:US-2011230343-A1
    优先权日:2008-10-24
    标题 :Method for the Manufacture of Microparticles Comprising an Effect Substance
    发明人:SCHROERS MICHAEL; DYLLICK-BRENZINGER RAINER; MERK MICHAEL; BARG HEIKO
    权利人:BASF SE
    摘要:A subject matter of the present invention is a process for the preparation of effect compound-comprising microparticles M comprising A) the formation of a crude suspension of microparticles A by means of enzymatic polyester synthesis in an inverse miniemulsion comprising enzyme, effect compound and polyester monomers; and B) the polymerization of wall monomers from the group consisting of ethylenically unsaturated monomers, polyisocyanates and polyepoxides in the crude suspension of microparticles A. Furthermore, the present invention relates to microparticles M which can be obtained by means of the process according to the invention and also to an agrochemical formulation comprising microparticles M. In addition, the present invention relates to the use of microparticles M prepared according to the invention as component in colorants, cosmetics, drugs, biocides, plant protection agents, fertilizers, additives for food or animal fodder, or auxiliaries for polymers, paper, textiles, leather, detergents or cleaners. Finally, the invention also relates to a method for combating undesirable plant growth, to a method for combating undesirable insect or acarid infestation on plants and/or for combating phytopathogenic fungi, and to seeds treated with the agrochemical formulation.

    专利号:US-8937089-B2
    优先权日:2004-07-01
    标 题:Synergistic mixtures of anthranilamide invertebrate pest control agents
    发明人:ANNAN ISAAC BILLY; FLEXNER JOHN LINDSEY; PORTILLO HECTOR EDUARDO; LAHM GEORGE PHILIP; SELBY THOMAS PAUL; STEVENSON THOMAS MARTIN
    权利人:ANNAN ISAAC BILLY; FLEXNER JOHN LINDSEY; PORTILLO HECTOR EDUARDO; LAHM GEORGE PHILIP; SELBY THOMAS PAUL; STEVENSON THOMAS MARTIN; DU PONT
    摘要:Disclosed are mixtures and compositions for controlling invertebrate pests relating to combinations comprising (a) 3-bromo-N-[4-chloro-2-methyl-6-[(methylamino)carbonyl]phenyl]-1-(3-chloro-2-pyridinyl)-1H-pyrazole-5-carboxamide, and its N-oxides, and suitable salts thereof n n n n n n n n n n n n andn na component (b) wherein the component (b) is at least one compound or agent selected from neonicotinoids, cholinesterase inhibitors, sodium channel modulators, chitin synthesis inhibitors, ecdysone agonists, lipid biosynthesis inhibitors, macrocyclic lactones, GABA-regulated chloride channel blockers, juvenile hormone mimics, ryanodine receptor ligands, octopamine receptor ligands, mitochondrial electron transport inhibitors, nereistoxin analogs, pyridalyl, flonicamid, pymetrozine, dieldrin, metaflumizone, biological agents, and suitable salts of the foregoing.n n n n n n Also disclosed are methods for controlling an invertebrate pest comprising contacting the invertebrate pest or its environment with a biologically effective amount of a mixture or composition of the invention.

    专利号:US-11213031-B2
    优先权日:2017-11-13
    标 题:Tetrazolylpropyl derivatives and their use as fungicides
    发明人:SUDAU ALEXANDER; HOFFMANN SEBASTIAN; DAHMEN PETER; WEBSTER ROBERT ALAN; MEISSNER RUTH; GOERTZ ANDREAS; MILLER RICARDA; COQUERON PIERRE-YVES; BERNIER DAVID; NICOLAS LIONEL; BRUNET STEPHANE; KENNEL PHILIPPE; TOQUIN VALERIE; GOURGUES MATHIEU; LOQUE DOMINIQUE; THOMAS VINCENT
    权利人:BAYER AG; BAYER CROPSCIENCE AG
    摘要:The present invention relates to tetrazolylpropyl derivatives of formula (I) n nwherein one of V 1 and V 2 represents CR 3 and the other one of V 1 and V 2 represents N, Q represents a 6-membered aromatic cycle as defined in the specification, and R 1 , R 2 , R 3 , R 4 , and R 5 are defined as disclosed in the specification, to compositions comprising such compounds, to the use of said compounds as fungicides, as well as to particular intermediates useful in the synthesis of said tetrazolylpropyl derivatives.

    专利号:EP-1771070-B1
    优先权日:2004-07-26
    标题:Mixtures of anthranilamide invertebrate pest control agents
    发明人:ANNAN ISAAC BILLY; HUGHES KENNETH ANDREW; LAHM GEORGE PHILIP; SELBY THOMAS PAUL; STEVENSON THOMAS MARTIN
    权利人:DU PONT
    摘要:Disclosed are mixtures and compositions for controlling invertebrate pests relating to combinations comprising (a) 3-bromo-N-[4-cyano-2-methyl-6­[(methylamino)carbonyl]phenyl]-1-(3-chloro-2-pyridinyl)-1H-pyrazole-5-carboxamide, an N-oxide, or a salt thereof, Formula (1) and (b) at least one invertebrate pest control agent selected from neonicotinoids, cholinesterase inhibitors, sodium channel modulators, chitin synthesis inhibitors, ecdysone agonists, lipid biosynthesis inhibitors, macrocyclic lactones, GABA-regulated chloride channel blockers, juvenile hormone mimics, ryanodine receptor ligands, octopamine receptor ligands, mitochondrial electron transport inhibitors, nereistoxin analogs, pyridalyl, flonicamid, pymetrozine, dieldrin, metaflumizone, biological agents, and salts of the foregoing. Also disclosed are methods for controlling an invertebrate pest comprising contacting the invertebrate pest or its environment with a biologically effective amount of a mixture or composition of the invention.
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    主要参考文献


    1: Farouk M, Hussein LA, El Azab NF. New HPLC and fluorometric methods for the determination of pyriproxyfen and pyridalyl insecticide residues in tomatoes. J AOAC Int. 2014 Jan-Feb;97(1):188-96. doi: 10.1007/s10661-015-4767-0. Epub 2015 Jul 30. doi: 10.1007/s10661-015-4361-5. Epub 2015 Feb 20. doi: 10.1002/ps.3827. Epub 2014 Jun 5. doi: 10.1016/j.ibmb.2011.03.007. Epub 2011 Apr 8. doi: 10.1016/j.foodchem.2016.06.099. Epub 2016 Jun 29. doi: 10.1002/arch.20252. doi: 10.1016/j.bmc.2015.09.030. Epub 2015 Sep 21. doi: 10.1021/jf9026469. doi: 10.1124/dmd.109.028878. Epub 2009 Sep 22. doi: 10.1021/acs.jafc.5b02279. Epub 2015 Aug 25. doi: 10.1124/dmd.109.031914. Epub 2010 Feb 17. doi: 10.1002/ps.3417. Epub 2012 Nov 9. doi: 10.3390/molecules201219811. doi: 10.1093/jee/tov155. Epub 2015 Jun 6. doi: 10.1016/j.bmcl.2016.04.094. Epub 2016 May 7. doi: 10.1002/ps.3243. Epub 2012 May 3.

    合成参考文献


    摘要:USEPA/Office of Prevention, Pesticides and Toxic Substances; Pesticide Fact Sheet - Pyridalyl p.9 (April 24, 2008). Available from, as of December 27, 2010:
    摘要:National Pesticide Information Retrieval System's USEPA/OPP Chemical Ingredients Database on Pyridalyl (179101-81-6). Available from, as of January 5, 2011:
    摘要:USEPA/Prevention, Pesticides, and Toxic Substances; Citizen's Guide to Pest Control and Pesticide Safety p.22 (March 2005) EPA 730-K-04-002
    摘要:Franke C et al; Chemosphere 29: 1501-14 (1994)
    摘要:Purdue University; National Pesticide Information Retrieval System, Pyridalyl PC Code: 295149. Available from, as of January 25, 2011: https://npirspublic.ceris.purdue.edu/ppis/
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