CAS: 16532-02-8; Bromomethyldimethylsilyl Chloride

上下游产品

chloro-trimethyl-silane(bromomethyl)trimethylsilane 1,3-bis(bromomethyl)-1,1,3,3-tetramethyldisiloxane (bromomethyl)dimethylphenylsilane (bromomethyl)dimethylsilane

📜三甲基氯硅烷 反应生成溴甲基二甲基氯硅烷
参考文献:Transannular Interactions Of The Silyl Center With Distant Keto Groups In The Mass Spectra Of Medium-Sized Organosilicon Heterocycles. Improved Synthetic Routes To Six-,Seven-,And Eight-Membered Silicon Ring Systems
标题:Transannular Interactions Of The Silyl Center With Distant Keto Groups In The Mass Spectra Of Medium-Sized Organosilicon Heterocycles. Improved Synthetic Routes To Six-,Seven-,And Eight-Membered Silicon Ring Systems
摘要:
Doi:10.1021/jo00825A012

专利信息

专利号:US-7183417-B2
优先权日:2004-04-09
标题:Simple stereocontrolled synthesis of salinosporamide A
发明人：COREY ELIAS J
权利人:HARVARD COLLEGE
摘要:A simple and effective stereocontrolled synthesis of salinosporamide A(1) n nhas been developed which follows the pathway outlined in the FIGURE. The process, the first total synthesis of salinosporamide A, is capable of providing the compound in substantial quantities for further biological studies. In addition to the method of Scheme I, the present invention also includes several novel synthetic intermediate compounds, several intermediate steps of the preferred synthetic process; and the uses of these compounds in the preparation of synthetic derivatives of the compound Salinosporamide A. Salinosporamide A is of special interest as a synthetic target because of its protein in vitro cytotoxic activity against many tumor cell lines (IC 50 values of 10 nM or less).

专利号:US-6127489-A
优先权日:1996-05-20
标题:Silyl linker for solid phase organic synthesis of aryl-containing molecules
发明人：NEWLANDER KENNETH A; MOORE MICHAEL L
权利人:SMITHKLINE BEECHAM CORP
摘要:This invention relates to improved silyl linkers, methods for their preparation and their use in the solid phase synthesis of aromatic carbocycles, especially electron deficient aromatic carbocycles.

专利号:US-8183402-B2
优先权日:2007-06-27
标 题:Industrial method for the synthesis of 17-acetoxy-11β[4-(dimethylamino)-phenyl]-21-methoxy-19-norpregna-4,9-dien-3,20-dione and the key intermediates of the process
发明人：BODI JOZSEF; VISKY GYOERGY; SZELES JANOS; MAHO SANDOR; SANTA CSABA; CSOERGEI JANOS; TUBA ZOLTAN; TERDY LASZLO; MOLNAR CSABA; ARANYI ANTAL; HORVATH ZOLTAN; BALOGH GABOR
权利人:BODI JOZSEF; VISKY GYOERGY; SZELES JANOS; MAHO SANDOR; SANTA CSABA; CSOERGEI JANOS; TUBA ZOLTAN; TERDY LASZLO; MOLNAR CSABA; ARANYI ANTAL; HORVATH ZOLTAN; BALOGH GABOR; RICHTER GEDEON NYRT
摘要:The present invention relates to a process for the synthesis of the 17-acetoxy-11β-[4-(dimethylamino)-phenyl]-21-methoxy-19-norpregna-4,9-dien-3,20-dione of formula (I): n nfrom 3,3-[1,2-etandiyl-bis(oxy)]-oestr-5(10),9(11)-dien-17-one of formula (II):

专利号:US-7164018-B2
优先权日:2001-01-29
标 题 :Polymers based on N-carbamyl-N'-dimethylsilyl methyl-piperazine traceless linkers for the solid phase synthesis of phenyl based libraries
发明人：CEREDA ENZO; PELLEGRINI CARLO MARIA; QUAI MONICA; BARBAGLIA WALTER
权利人:BOEHRINGER INGELHEIM INT
摘要:The present invention relates to polymers characterized by novel silicon linkers based on the carbamyl piperazine moiety, methods of preparing these polymers and their use in the solid phase synthesis of compounds or libraries of compounds embracing a phenyl ring in their structure.

专利号:US-2024010511-A1
优先权日:2019-05-02
标 题 :Methods and compositions for synthesis of phosphor and its incorporation in a polymer matrix for light conversion
发明人：SAHI SUNIL
权利人:SOLGO INC; SOLGRO INC
摘要:The invention relates to methods and compositions for synthesizing a phosphor and preparing a surface-modified phosphor comprising a phosphor, a silica, and a silane, and articles comprising same. The invention also relates to a method of dispersion of the disclosed surface-modified phosphor with a blue emitting agent in a polymer matrix and uses thereof.

专利号:US-9683010-B2
优先权日:2014-02-17
标 题 :Process for the production of 21-methoxy-11-beta-phenyl-19-nor-pregna-4,9-diene-3,20-dione derivatives
发明人：Mahó Sándor; Sà NTA CSABA; Csörgei János; Szabó Gábor; SCHÄFER TAMà S; BÉNI ZOLTà N
权利人:RICHTER GEDEON NYRT
摘要:The present invention relates to a process for the synthesis of compounds of formula (I), n nwherein the meaning of R is dimethylamino or acetyl group, using the compound of formula (III) or (IV), wherein the meaning of R′ is dimethylamino or 2-methyl-1,3-dioxan-2-yl group, as starting material and methoxymethyl lithium as reagent.