CAS: 82001-53-4; 12-Mercaptododecanoic Acid

该化合物是一种硫醇功能化脂肪酸,其特征为12碳烷基链,在碳箱酸组中终止,在蛋白酸组中终止,而美甲酸组位置有甲卡普托(硫醇),这种双功能结构具有独特的反应性,有利于在表面改变,聚合化学和金属协调方面应用.硫醇组有利于对金属表面的强大结合,使其对自组单层和纳米粒子稳定具有价值,而碳箱酸组则允许进一步的衍生或溶解调.其闪光性也支持了水系统中的小鼠形成.由于该化合物的双重功能和控制的相互特性,该化合物在材料科学,催化和生物功能化方面非常有用.

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物理性质

MSDS等安全信息

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ECHA物质C&L通报

上下游产品

CAS号73367-80-3 12-溴十二烷酸 | CAS号60908-53-4 12-((ethoxy(thi... | CAS号5876-87-9 1,11-十二碳二烯 | CAS号5675-51-4 1,12-十二烷二醇 | CAS号3344-77-2 12-溴-1-十二烷醇 | CAS号113297-35-1 12-[11-carboxyu...

合成工艺路线路线简述

  • 合成目标产物 12-Mercaptododecanoic Acid 主要起始原料 Dodecanoic Acid, 12-[(Ethoxythioxomethyl)Thio]-
  • 26825-95-6 = 82001-53-4
    反应条件:1.1 Reagents: Thiourea Solvents: Ethanol,Water; 4 H,Reflux1.2 Reagents: Sodium Hydroxide; 2 H,Reflux1.3 Reagents: Sulfuric Acid Solvents: Water; Acidified
    标题:Controlling The Adsorption Of Single Poly(Styrenesulfonate) Sodium On Nh3+-Modified Gold Surfaces On A Molecular Scale
    作者:Zhu,M.; Schneider,M.; Papastavrou,G.; Akari,S.; Moehwald,H.
    参考文献:Langmuir 日期:2001 卷标:17(21) 页码:6471-6476]

    82001-53-4 = 82001-53-4
    反应条件:1.1 Reagents: Triphenylphosphine (Gold Undecanuclear Cluster Complex),Gold (Undecanuclear Cluster,Triphenylphosphine Chloro Complex) Solvents: Chloroform,Water; 12 H,Ph 8,55 °C1.2 Reagents: Hydrochloric Acid Solvents: Water; Ph 2
    标题:Thiol-Functionalized Undecagold Clusters By Ligand Exchange: Synthesis,Mechanism,And Properties
    作者:Woehrle,Gerd H.; Hutchison,James E.
    参考文献:Inorganic Chemistry 日期:2005 卷标:44(18) 页码:6149-6158]

    73367-80-3 + 140-89-6 = 82001-53-4
    反应条件:1.1 Solvents: Acetone1.2 Reagents: Ethylenediamine,Sodium Borohydride Solvents: Ethanol
    标题:Synthesis Of A Bipolar Phosphatidylethanolamine: A Model Compound For A Membrane-Spanning Probe
    作者:Delfino,Jose M.; Stankovic,Charles J.; Schreiber,Stuart L.; Richards,Frederic M.
    参考文献:Tetrahedron Letters 日期:1987 卷标:28(21) 页码:2323-6]

    352439-40-8 = 82001-53-4
    反应条件:1.1 Reagents: Sodium Methoxide Solvents: Methanol; 1 H,Rt1.2 Reagents: Dowex; Ph 5,Rt
    标题:Fluorinated And Charged Hydrogenated Alkanethiolates Grafted On Gold: Expanding The Diversity Of Mixed-Monolayer Nanoparticles For Biological Applications
    作者:Bidoggia,Silvia; Milocco,Francesca; Polizzi,Stefano; Canton,Patrizia; Saccani,Alessandra; Et Al
    参考文献:Bioconjugate Chemistry 日期:2017 卷标:28(1) 页码:43-52]

    = 82001-53-4
    反应条件:1.1 Reagents: Potassium Hydroxide Solvents: Water; 4 H,100 - 110 °C1.2 Reagents: Sulfuric Acid Solvents: Water; Ph 1,Rt
    标题:Preparations Of Universal,Functionalized Long-Chain Alkylthiol Linkers For Self-Assembled Monolayers
    作者:Yoo,Dong Jin; Lee,Kyong-Sub; Kim,Ae Rhan; Nahm,Kee Suk
    参考文献:Hwahak Konghak 日期:2011 卷标:49(3) 页码:330-337]

    352439-40-8 = 82001-53-4
    反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Methanol,Water; 3 H,Rt1.2 Reagents: Hydrochloric Acid Solvents: Water
    标题:A Bola-Phospholipid Bearing Tetrafluorophenylazido Chromophore As A Promising Lipid Probe For Biomembrane Photolabeling Studies
    作者:Xia,Yi; Sengupta,Kheya; Maggiani,Alain; Qu,Fanqi; Peng,Ling
    参考文献:Organic & Biomolecular Chemistry 日期:2013 卷标:11(30) 页码:5000-5005]

    73367-80-3 = 82001-53-4
    反应条件:1.1 Reagents: Thiourea Solvents: Ethanol; 1 D,Reflux; Reflux -> Rt1.2 Reagents: Sodium Hydroxide Solvents: Ethanol; 6 H,Heated1.3 Reagents: Hydrochloric Acid Solvents: Water
    标题:Development Of 11C-Labeled ω-Sulfhydryl Fatty Acid Tracer For Myocardial Imaging With Pet
    作者:Wu,Xiangxiang; Wang,Peizhi; Liu,Ruixin; Zeng,Huahui; Chao,Fangfang; Et Al
    参考文献:European Journal Of Medicinal Chemistry 日期:2018 卷标:143 页码:1657-1666
📜12-溴十二烷酸置于sodium Tetrahydroborate,乙二胺体系中,用 乙醇,丙酮 作为反应溶剂,化学反应 39.0H,反应生成 12-巯基癸酸
参考文献:A Bola-Phospholipid Bearing Tetrafluorophenylazido Chromophore As A Promising Lipid Probe For Biomembrane Photolabeling Studies
标题:A Bola-Phospholipid Bearing Tetrafluorophenylazido Chromophore As A Promising Lipid Probe For Biomembrane Photolabeling Studies
摘要:为了通过光标记方法研究生物膜,我们合成了一种在跨膜二酰链中间带有四氟苯基叠氮发色团的波拉磷脂探针,并对其进行了表征.该探针显示了波拉脂在巨囊形成过程中的稳定性优势,以及四氟苯叠氮发色团带来的优异光化学特性,因此是一种很有希望用于生物膜光标记研究的探针.
DOI:10.1039/c3Ob40659H

海关参考信息

专利信息


专利号:US-11180507-B2
优先权日:2016-07-08
标题:Synthesis of functionalizable or functionalized poly(3,4-ethylenedioxythiphene)-based polymers and monomers therefor
发明人：CUI XINYAN; CAO BIN
权利人:UNIV PITTSBURGH COMMONWEALTH SYS HIGHER EDUCATION; UNIV OF PITTSBURGH—OF THE COMMONWEALTH SYSTEM OF HIGHER EDUCATION
摘要:A method of forming a compound having the formula (I′): (I′) includes the reaction: (II′) in the presence of a base, wherein X is a halo atom selected from the group consisting of Cl, Br and I.

专利号:US-2015328616-A1
优先权日:2014-05-13
标题:Surface mediated synthesis of polynucleotides, polypeptides and polysaccharides and related materials, methods and systems
发明人：GETHERS MATTHEW; GODDARD III WILLIAM A; WEISS PAUL S; RANDALL JOHN
权利人:CALIFORNIA INST OF TECHN
摘要:Surface mediated polymer synthesizing methods and related systems and materials are described where monomers are attached to monomer binding regions on a surface and subsequently form chemical bonds with adjacent monomers on the surface to form linear polymers selected from polynucleotide, polypeptides and polysaccharides.

专利号:US-2024271165-A1
优先权日:2021-08-12
标题:Method for production of ammonia, using inorganic nanoparticle-microbial complex
发明人：LEE DOH CHANG; KOH SUNGJUN; CHOI YOOJIN; LEE ILSONG; KIM GUI-MIN
权利人:KOREA ADVANCED INST SCI & TECH
摘要:The present invention relates to a method for production of ammonia, using an inorganic nanoparticle-microbial complex in which a nitrogen fixation reaction in a microorganism is improved by increasing the amount of inorganic nanoparticles entrapped in the microorganism. The present invention can produce ammonia at low temperature and low pressure conditions, compared to the conventional Haber-Bosch process of producing ammonia in high temperature and high pressure conditions and in a friendly environmental manner without emission of carbon dioxide that is released during conventional chemical synthesis processes, whereby the present invention may be a competitive alternative to the prior art for production of ammonia that has an unlimited potential as a future energy resource.

专利号:US-2023132381-A9
优先权日:2016-07-08
标 题 :Synthesis of functionalizable or functionalized poly(3,4-ethylenedioxythiphene)-based polymers and monomers therefor

专利号:WO-2023113033-A1
优先权日:2021-12-16
标题 :Gas diffusion electrode
发明人：KONDO SHOICHI; MAEDA SHINICHI; SHIGA NORIHITO
权利人:NISSAN CHEMICAL CORP
摘要:[Problem] The present invention addresses the problem of increasing the rate of reaction by controlling ammonium ions, which are generated by ammonia as the objective of the electrolytic synthesis of ammonia and protons that are supplied to the cathode, by means of the cathode and the cathode catalyst layer. [Solution] The present invention provides a gas diffusion electrode which is integrated with a catalyst layer that uses a material selected from the group consisting of cathode catalyst layer materials. Examples of the cathode catalyst layer materials include a fired body and an ionic liquid.

专利号:US-2020181163-A1
优先权日:2016-07-08
标 题 :Synthesis of functionalizable or functionalized poly(3,4-ethylenedioxythiphene)-based polymers and monomers therefor

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合成参考文献


参考文献:10.1007/s12155-024-10797-6
摘要:Shah MA, Farooq W, Shahnaz T, Akilarasan M. Bioenergy and Value-Added Chemicals Derived Through Electrocatalytic Upgradation of Biomass: a Critical Review. Bioenerg. Res. 2024 Aug 16;17(4):2029–49. doi: 10.1007/s12155-024-10797-6.
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