专利号:US-6610802-B2 优先权日:2001-05-29 标题 :Process for synthesis of polymer compositions, polymer compositionS obtainable by the process, and use of the same 发明人:ROOS SEBASTIAN; EISENBERG BORIS; HARPE CAROLIN 权利人:ROHMAX ADDITIVES GMBH 摘要:The present invention relates to a process for synthesis of polymer compositions with reduced catalyst content, wherein ethylenically unsaturated monomers containing less than 0.5 wt % of ethylenically unsaturated monomers with at least one carboxylic group, sulfonic acid group and/or at least one phosphonic acid group relative to the total weight of the ethylenically unsaturated monomers are polymerized by means of initiators containing a transferable group of atoms and of one or more catalysts comprising at least one transition metal in the presence of ligands which can form a coordination compound with the metal catalyst or catalysts and, after the polymerization, the catalyst contained in the polymer is at least partly separated. For this purpose, the polymer composition is filtered, after the polymerization, in the presence of at least one filter aid which contains at least 0.5 wt %, relative to the total weight of the filter aid, of repeating units that contain at least one carboxylic acid group, sulfonic acid group and/or at least one phosphonic acid group.
专利号:US-6610801-B1 优先权日:2000-11-13 标题:Processes for synthesis of polymer compositions 发明人:SCHERER MARKUS 权利人:ROHMAX ADDITIVES GMBH 摘要:The present invention relates to processes for synthesis of poly(meth)acrylate compositions, wherein ethylenically unsaturated monomers are transformed to polymers by means of initiators containing a transferable group of atoms and of one or more catalysts comprising at least one transition metal in the presence of ligands which can form a coordination compound with the metal catalyst or catalysts, wherein ethylenically unsaturated monomers containing 50 to 100 wt %, relative to the total weight of ethylenically unsaturated monomers, of (meth)acrylates of formula (I) are polymerizedwherein R denotes hydrogen or methyl, R1 denotes a straight-chain or branched alkyl group with 8 to 40, carbon atoms, R2 and R3 independently denote hydrogen or a group of the formula -COOR1, wherein R' denotes hydrogen or a straight-chain or branched alkyl group with 8 to 40, carbon atoms, in the presence of copper, the total concentration of copper of oxidation numbers (I) and (II) in the polymerization composition being <=200 ppm relative to the total weight of the composition.
专利号:US-6639029-B1 优先权日:2000-11-13 标 题 :Process for continuous synthesis of polymer compositions as well as use of same 发明人:SCHERER MARKUS; BOLLINGER JOSEPH MARTIN; COOPER JR DAVID J; TILLERY LARRY STEPHEN; WOODRUFF ROBERT 权利人:ROHMAX ADDITIVES GMBH 摘要:The present invention relates to a process for synthesis of polymer compositions, wherein ethylenically unsaturated monomers are polymerized by means of initiators containing a transferable atom or group of atoms and of one or more catalysts comprising at least one transition metal in the presence of ligands which can form a coordination compound with the metal catalyst or catalysts, the process being characterized in that the polymerization takes place by means of continuous process operation.
专利号:US-4210599-A 优先权日:1978-04-14 标题 :Synthesis of boroxarophenanthrenes 发明人:BRIDGER ROBERT F 权利人:MOBIL CORP 摘要:Improved synthesis of boroxarophenanthrenes, comprising the step of adding gaseous BCl 3 to a liquid hydrocarbon slurry of 2-hydroxybiphenyl at a specified temperature. Known methods involve the reaction of BCl 3 with the phenol at -70° C., the reaction being carried out in methylene chloride.
专利号:US-6689844-B2 优先权日:2001-05-29 标题 :Process for synthesis of polymer compositions with reduced halogen content, polymer composition with reduced halogen content as well as use of this composition 发明人:ROOS SEBASTIAN; BOLLINGER JOSEPH MARTIN; SCHERER MARKUS 权利人:ROHMAX ADDITIVES GMBH 摘要:Polymer compositions with reduced living halogen content are used as additive to lubricating oils and are prepared by polymerizing at least one ethylenically unsaturated monomer using a) at least one initiator containing a transferable halogen and b) one or more metal catalysts containing at least one transition metal, in the presence of ligands which can form a coordination compound with the one or more metal catalysts, to obtain a polymer composition having a living halogen content, and after the polymerizing, reacting the polymer composition having a living halogen content with at least one organic nitrogen compound in the presence of a nonpolar solvent, thereby reducing the living halogen content to obtain the polymer composition having a reduced halogen content.
专利号:US-7429555-B2 优先权日:2004-04-30 标 题:Lubricating grease with high water resistance 发明人:SCHERER MARKUS; FISCHER MATTHIAS; MUELLER MICHAEL; KINKER BERNARD; PAUKER ALEXANDRA 权利人:ROHMAX ADDITIVES GMBH 摘要:The present invention relates to lubricating greases comprising at least one thickening agent and at least one lubricating oil, wherein the lubricating grease contains at least one polymeric structure improver that can be obtained by polymerization of monomer compositions, which are composed ofn a) 0 to 40 wt %, relative to the weight of the monomer compositions for synthesis of the polymeric structure improvers, of at least one (meth)acrylate of formula (I) nn nin which R represents hydrogen or methyl, R 1 denotes a straight-chain or branched alkyl moiety having 1 to 5 carbon atoms,n b) 40 to 99.99 wt %, relative to the weight of the monomer compositions for synthesis of the polymeric structure improvers, of at least one (meth)acrylate of formula (II) n nin which R represents hydrogen or methyl, R 2 denotes a straight-chain or branched alkyl moiety having 6 to 30 carbon atoms,n c) 0.01 to 20 wt %, relative to the weight of the monomer compositions for synthesis of the polymeric structure improvers, of monomers containing acid groups or salts thereof, d) 0 to 59.99 wt %, relative to the weight of the monomer compositions for synthesis of the polymeric structure improvers, of comonomer.
参考文献:10.1007/s10534-022-00382-9 摘要:Gajera HP, Hirpara DG, Bhadani RV, Golakiya BA. Green synthesis and characterization of nanosilver derived from extracellular metabolites of potent Bacillus subtilis for antifungal and eco-friendly action against phytopathogen. Biometals. 2022 Jun;35(3):479–97. doi: 10.1007/s10534-022-00382-9.