CAS: 16834-13-2; 5,10,15,20-Tetra(4-Pyridyl)-21H,23H-Porphine

该化合物是一种合成激素衍生物,其特征是附于porphyrin核心的四个丙烯基组.该化合物展示了一种平面芳香结构,有助于其重要的电子特性,包括在可见区域进行强光吸收,使其在各种光化学应用中有用.丙烯基替代成分增强了其在极溶剂中的溶解性,并能够促进与金属离子的协调,从而能够形成金属的卤素.Tetra(4-丙烯基)porphyrin常常用于与催化,传感器有关的研究,并用作超分子化学的一个建筑块,因为它能够形成与各种子体的复合体.此外,其独特的电子和光学特性使它成为了应用光动力疗法和太阳能转换的候选体.该化合物通常使用UV-V-Vis光谱,NMR光谱谱和质量光谱测量等技术来确认其结构和纯度.

结构式图片

相似化合物

71410-72-5 40882-83-5 917-23-7

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

pyridine-4-carbaldehyde pyrrole caprinaldehyde benzo-15-crown-5-ether 5,10,15,20-tetra(N-methylpyridinium-4-yl)porphine 5,10,15,20-tetrakis(4-methylpyridinium)porphyrin tetrahydr°Chloride 5,10,15,20-tetra(4-pyridyl)porphyrin zinc dichloro-(5,10,15,20-tetrakis-(4-pyridyl)-porphyrinato)tin(IV)

合成工艺路线路线简述

    专利信息


    专利号:US-8871926-B1
    优先权日:2010-09-28
    标题:Synthesis of porphyrin nanostructures
    发明人:FAN HONGYOU; BAI FENG
    权利人:FAN HONGYOU; BAI FENG; SANDIA CORP
    摘要:The present disclosure generally relates to self-assembly methods for generating porphyrin nanostructures. For example, in one embodiment a method is provided that includes preparing a porphyrin solution and a surfactant solution. The porphyrin solution is then mixed with the surfactant solution at a concentration sufficient for confinement of the porphyrin molecules by the surfactant molecules. In some embodiments, the concentration of the surfactant is at or above its critical micelle concentration (CMC), which allows the surfactant to template the growth of the nanostructure over time. The size and morphology of the nanostructures may be affected by the type of porphyrin molecules used, the type of surfactant used, the concentration of the porphyrin and surfactant the pH of the mixture of the solutions, and the order of adding the reagents to the mixture, to name a few variables.

    专利号:US-12291513-B2
    优先权日:2021-05-03
    标 题:Pyridinium derivatives made by hydrothermal synthesis for use as anolytes in electrochemical cells
    发明人:FENG DAWEI; LYU XIULIANG; SULLIVAN PATRICK; LI WENJIE
    权利人:WISCONSIN ALUMNI RES FOUND
    摘要:Pyridinium derivatives, methods of making the pyridinium derivatives, and electrochemical cells that use the pyridinium derivatives as anolytes are provided. The pyridinium derivatives have a redox core with two or more pyridinium groups and substituents at pyridinium ring nitrogen atoms. The pyridinium derivatives can be made by reacting pyridyl reactant molecules having two or more pyridyl groups with water-soluble derivatizing reactant molecules via a hydrothermal synthesis.

    专利号:CN-120126588-A
    优先权日:2025-01-20
    标 题:A method for optimizing the synthesis of aryl porphyrin compounds

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献

    1.) Akins DL, Zhu H-R, Guo C. 1996. Aggregation of Tetraaryl-Substituted Porphyrins in Homogeneous Solution. Phys. Chem.
    100:5420-5 2.) Anderson S, Anderson HL, Bashall A, McPartlin M, Sanders JKM. 1995. Assembly and crystal structure of a photoactive array of five porphyrins. Chem., Int. Ed. Engl.
    34:1096-9 3.) Auwarter W, Weber-Bargioni A, Brink S, Riemann A, Schiffrin A, et al. 2007. Controlled metalation of self-assembled porphyrin nanoarrays in two dimensions. ChemPhysChem
    8:250- 4.) Bernadou J, Pratviel G, Bennis F, Girardet M, Meunier B. 1989. Potassium monopersulfate and a water-soluble manganese porphyrin complex, [Mn(TMPyP)](OAc)5, as an efficient reagent for the oxidative cleavage of DNA. Biochemistry

    合成参考文献


    参考文献:10.1007/s10895-021-02747-8
    摘要:Velappan K, Rajalingam R, Venkattappan A. Photoinduced Electron Transfer Reactions of Water Soluble Porphyrins in Zeolite Environment. Journal of Fluorescence. 2021 Aug 02;31(5):1575–85. doi: 10.1007/s10895-021-02747-8.
    📝 需求与反馈
    尽可能描述清楚需求与问题信息
    ×

    通知