CAS: 13601-08-6; Tetraamminepalladium(Ii) Nitrate

该化合物是一个协调化合物,其成分为,为中央金属离子,环绕四周有四氨离子和两硝酸离子;该化合物一般是黄色晶状固体,以其在水和其他极溶剂中的溶解性而著称;氨离子的存在具有独特的特性,包括能够参与各种化学反应,特别是催化和有机合成;四甲胺二硝酸盐经常用于有机金属化学领域,可以作为催化剂的前体;其稳定性和再活性可能受到诸如pH和温度等因素的影响;此外,该化合物显示出有趣的电化学特性,使其成为材料科学和电化学研究的一个课题;在处理该化合物时,应采取安全防范措施,因为如果浸入或吸入,可能会对健康造成危害;应当使用适当的保护设备.

结构式图片

欧盟法规

REACH注册ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

ammonia

合成工艺路线路线简述

    专利信息


    专利号:US-11826833-B2
    优先权日:2013-04-12
    标 题 :Synthesis of bimetallic nanoparticle catalysts using microwave irradiation
    发明人:HUMPHREY SIMON M; GARCIA STEPHANY
    权利人:UNIV TEXAS
    摘要:The present invention provides compositions and methods of making bimetallic metal alloys of composition for example, Rh/Pd; Rh/Pt; Rh/Ag; Rh/Au; Rh/Ru; Rh/Co; Rh/Ir; Rh/Ni; Ir/Pd; Ir/Pt; Ir/Ag; Ir/Au; Pd/Ni; Pd/Pt; Pd/Ag; Pd/Au; Pt/Ni; Pt/Ag; Pt/Au; Ni/Ag; Ni/Au; or Ag/Au prepared using microwave irradiation.

    专利号:WO-2019185730-A1
    优先权日:2018-03-27
    标题 :Catalytic synthesis of biarylic compounds
    发明人:DE VOS DIRK; TOMKINS PATRICK; VERCAMMEN JANNICK
    权利人:UNIV LEUVEN KATH
    摘要:The invention relates to methods for synthesizing a biarylic compound from two arene compounds, comprising the step of reacting said arene compounds in the presence of an ordered, porous material, a catalytic transition metal and an 5 oxidant, wherein the two arene compounds can be different or identical, wherein each of the two different or wherein the identical arene compounds contains at least one H-substituent, and wherein at least one of the arene compounds or wherein the identical arenes are substituted with at least one substituent, different from H.10

    专利号:US-11591231-B2
    优先权日:2020-11-10
    标 题:Organotemplate-free synthesis of a zeolite of ton framework type
    发明人:SCHMIDT JOEL EDWARD; OJO ADEOLA FLORENCE; CHEN CONG-YAN
    权利人:CHEVRON USA INC
    摘要:An organotemplate-free synthetic process for the production of a zeolite of TON framework type structure is provided. The process includes the steps of: (1) preparing a mixture comprising: (a) an alumina-coated silica; (b) a source of an alkali metal; (c) an alcohol; (d) a source of hydroxide ions; (e) seed crystals comprising a zeolitic material having a TON framework type structure; and (f) water; and (2) crystallizing the mixture obtained in step (1).

    专利号:US-9272334-B2
    优先权日:2011-04-12
    标 题:Synthesis of platinum-alloy nanoparticles and supported catalysts including the same
    发明人:CARPENTER MICHAEL K
    权利人:GM GLOBAL TECH OPERATIONS INC
    摘要:Methods of synthesizing platinum-nickel-alloy nanoparticles and supported catalysts comprising the nanoparticles are provided. The methods may comprise forming a reaction mixture in a reaction vessel; heating the reaction mixture sealed in the reaction vessel to a reaction temperature; maintaining the temperature of the reaction vessel for a period of time; cooling the reaction vessel; and removing platinum-alloy nanoparticles from the reaction vessel. The reaction mixture may comprise a platinum precursor, a nickel precursor, a formamide reducing solvent, and optionally a cobalt precursor. In some embodiments the reaction temperature is at or below the boiling point of the formamide reducing solvent, such as from about 120° C. to about 150° C., for example. The platinum-alloy nanoparticles provide favorable electrocatalytic activity when supported on a catalyst support material.

    专利号:US-11167996-B1
    优先权日:2020-06-03
    标题:Synthesis of SZR framework type molecular sieves
    发明人:SCHMIDT JOEL EDWARD; CHEN CONG-YAN
    权利人:CHEVRON USA INC
    摘要:A method is provided for synthesizing molecular sieves of SZR framework type using 1,2,3-trimethylimidazolium cations as a structure directing agent and alumina-coated silica as a combined source of silicon and aluminum.

    专利号:US-11007514-B2
    优先权日:2019-04-05
    标 题 :Ammonia facilitated cation loading of zeolite catalysts
    发明人:GOFFE RANDAL A
    权利人:PACCAR INC
    摘要:The present disclosure features a high metal cation content zeolite-based binary catalyst (e.g., a high copper and/or iron content zeolite-based binary catalyst, where the zeolite can be a chabazite) for NO x reduction, having relatively low N 2 O make, and having low corresponding metal oxide content; where the metal in the metal oxide corresponds to the metal of the metal cation. The present disclosure also describes the synthesis of the zeolite-based binary catalyst having high metal cation content.
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    合成参考文献


    参考文献:10.1038/s41929-023-00983-8
    摘要:Jiang D, Wan G, Halldin Stenlid J, García-Vargas CE, Zhang J, Sun C, Li J, Abild-Pedersen F, Tassone CJ, Wang Y. Dynamic and reversible transformations of subnanometre-sized palladium on ceria for efficient methane removal. Nat Catal. 2023 Jul 20;6(7):618–27. doi: 10.1038/s41929-023-00983-8.
    参考文献:10.1134/s1061934824700709
    摘要:Shaposhnik AV, Zviagin AA, Ryabtsev SV. Determination of Hydrogen Sulphide in Air with an Indium Oxide Semiconductor Sensor. J Anal Chem. 2024 Sep;79(9):1338–44. doi: 10.1134/s1061934824700709.
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