专利号:US-11826833-B2 优先权日:2013-04-12 标 题 :Synthesis of bimetallic nanoparticle catalysts using microwave irradiation 发明人:HUMPHREY SIMON M; GARCIA STEPHANY 权利人:UNIV TEXAS 摘要:The present invention provides compositions and methods of making bimetallic metal alloys of composition for example, Rh/Pd; Rh/Pt; Rh/Ag; Rh/Au; Rh/Ru; Rh/Co; Rh/Ir; Rh/Ni; Ir/Pd; Ir/Pt; Ir/Ag; Ir/Au; Pd/Ni; Pd/Pt; Pd/Ag; Pd/Au; Pt/Ni; Pt/Ag; Pt/Au; Ni/Ag; Ni/Au; or Ag/Au prepared using microwave irradiation.
专利号:WO-2019185730-A1 优先权日:2018-03-27 标题 :Catalytic synthesis of biarylic compounds 发明人:DE VOS DIRK; TOMKINS PATRICK; VERCAMMEN JANNICK 权利人:UNIV LEUVEN KATH 摘要:The invention relates to methods for synthesizing a biarylic compound from two arene compounds, comprising the step of reacting said arene compounds in the presence of an ordered, porous material, a catalytic transition metal and an 5 oxidant, wherein the two arene compounds can be different or identical, wherein each of the two different or wherein the identical arene compounds contains at least one H-substituent, and wherein at least one of the arene compounds or wherein the identical arenes are substituted with at least one substituent, different from H.10
专利号:US-11591231-B2 优先权日:2020-11-10 标 题:Organotemplate-free synthesis of a zeolite of ton framework type 发明人:SCHMIDT JOEL EDWARD; OJO ADEOLA FLORENCE; CHEN CONG-YAN 权利人:CHEVRON USA INC 摘要:An organotemplate-free synthetic process for the production of a zeolite of TON framework type structure is provided. The process includes the steps of: (1) preparing a mixture comprising: (a) an alumina-coated silica; (b) a source of an alkali metal; (c) an alcohol; (d) a source of hydroxide ions; (e) seed crystals comprising a zeolitic material having a TON framework type structure; and (f) water; and (2) crystallizing the mixture obtained in step (1).
专利号:US-9272334-B2 优先权日:2011-04-12 标 题:Synthesis of platinum-alloy nanoparticles and supported catalysts including the same 发明人:CARPENTER MICHAEL K 权利人:GM GLOBAL TECH OPERATIONS INC 摘要:Methods of synthesizing platinum-nickel-alloy nanoparticles and supported catalysts comprising the nanoparticles are provided. The methods may comprise forming a reaction mixture in a reaction vessel; heating the reaction mixture sealed in the reaction vessel to a reaction temperature; maintaining the temperature of the reaction vessel for a period of time; cooling the reaction vessel; and removing platinum-alloy nanoparticles from the reaction vessel. The reaction mixture may comprise a platinum precursor, a nickel precursor, a formamide reducing solvent, and optionally a cobalt precursor. In some embodiments the reaction temperature is at or below the boiling point of the formamide reducing solvent, such as from about 120° C. to about 150° C., for example. The platinum-alloy nanoparticles provide favorable electrocatalytic activity when supported on a catalyst support material.
专利号:US-11167996-B1 优先权日:2020-06-03 标题:Synthesis of SZR framework type molecular sieves 发明人:SCHMIDT JOEL EDWARD; CHEN CONG-YAN 权利人:CHEVRON USA INC 摘要:A method is provided for synthesizing molecular sieves of SZR framework type using 1,2,3-trimethylimidazolium cations as a structure directing agent and alumina-coated silica as a combined source of silicon and aluminum.
专利号:US-11007514-B2 优先权日:2019-04-05 标 题 :Ammonia facilitated cation loading of zeolite catalysts 发明人:GOFFE RANDAL A 权利人:PACCAR INC 摘要:The present disclosure features a high metal cation content zeolite-based binary catalyst (e.g., a high copper and/or iron content zeolite-based binary catalyst, where the zeolite can be a chabazite) for NO x reduction, having relatively low N 2 O make, and having low corresponding metal oxide content; where the metal in the metal oxide corresponds to the metal of the metal cation. The present disclosure also describes the synthesis of the zeolite-based binary catalyst having high metal cation content.
参考文献:10.1038/s41929-023-00983-8 摘要:Jiang D, Wan G, Halldin Stenlid J, García-Vargas CE, Zhang J, Sun C, Li J, Abild-Pedersen F, Tassone CJ, Wang Y. Dynamic and reversible transformations of subnanometre-sized palladium on ceria for efficient methane removal. Nat Catal. 2023 Jul 20;6(7):618–27. doi: 10.1038/s41929-023-00983-8. 参考文献:10.1134/s1061934824700709 摘要:Shaposhnik AV, Zviagin AA, Ryabtsev SV. Determination of Hydrogen Sulphide in Air with an Indium Oxide Semiconductor Sensor. J Anal Chem. 2024 Sep;79(9):1338–44. doi: 10.1134/s1061934824700709.