CAS: 888-54-0; Acrolein 2,4-Dinitrophenylhydrazone

• 英文名称Acrolein 2,4-Dinitrophenylhydrazone
• 中文名称丙烯醛2,4-二硝基苯腙
• IUPAC名称2,4-dinitro-N-[(E)-prop-2-enylideneamino]aniline
• 其它别名2-丙烯醛2
• CAS编号888-54-0
• MFCD编号:MFCD00191599
• EINECS号:626-989-4
• FDA UNII编号:AL5M3P8R7K
• 分子式:C9H8N4O4分子量:236.18
• 产品CID: 1908998
• 产品分类有机原料→分子砌块→芳环类化合物→苯类化合物

• 相似结构搜索
• InChIKey: JJPZHGIYUVFTGG-UHFFFAOYSA-N
• InChI=1S/C9H8N4O4/c1-2-5-10-11-8-4-3-7(12(14)15)6-9(8)13(16)17/h2-6,11H,1H2
• 计算化学: 氢键受体数6.0氢键供体数1.0可旋转键数5.0

物理性质

• 熔点221-222 °C
• 沸点392.8±42.0 °C at 760 mmHg
• 闪点191.4±27.9 °C
• 密度1.4±0.1 g/cm3
• pKa:11.74±0.10(预测)
• PSA:110.67
• LogP:2.0867
• 折射率1.615
• 蒸汽压0.0±0.9 mmHg at 25°C
• 溶解性Chloroform (Slightly, Sonicated), Methanol (Slightly, Sonicated)
• 外观形态橙色至极深橙色
• 储存条件2-8°C

MSDS等安全信息

• GHS象形图
• GHS符号GHS07;
  注释: Exclamation mark
• 危险类别特定目标器官毒性 - 单次接触 类别3
  皮肤腐蚀/刺激 类别2
  严重眼刺激 类别2
  易燃固体 类别2
• 警示词Warning(警告)
• 危险描述H335 |可能引起呼吸道刺激.
  H315 |造成皮肤刺激.
  H319 |造成严重眼刺激.
  H228 |易燃固体.
• 防范说明P261-P264-P271-P280-P302+P352-P304+P340-P362+P364-P405-P501
• 危险等级4.1
• UN编号1325.0
• 危险品标志Xi,Xn,F
• 包装等级Ⅱ
• 安全声明26-36/37-16
• 危险类别码36/37/38-36-20/21/22-11
• WGK Germany3

欧盟法规

上下游产品

合成工艺路线路线简述

• 合成目标产物 Acrolein 2,4-Dinitrophenylhydrazone 主要起始原料 Chlorobenzene
• 119-26-6 = 888-54-0
  反应条件:1.1 Reagents: Formic Acid Solvents: Acetonitrile; Acidified,4 °C1.2 1 H,Rt
  标题:Removal Of Acrolein From Active Pharmaceutical Ingredients Using Aldehyde Scavengers
  作者:Kecili,Rustem; Nivhede,David; Billing,Johan; Leeman,Mats; Sellergren,Boerje; Et Al
  参考文献:Organic Process Research & Development 日期:2012 卷标:16(6) 页码:1225-1229]
  
  119-26-6 = 888-54-0
  反应条件:1.1 Reagents: Triphenylphosphine,Arsonium,Tetraphenyl-,(Dicarbonylrhodate)Bis[(1,2,3,4,5-η)-1,2,3,4,5-Pentameth... Solvents: Hexane1.2 -
  标题:Carbonylation Of Ethene To Acrolein In The Presence Of The Early-Late Heterobimetallic Complex [asph4][(η5-C5Me5)2Zr(μ-S)2Rh(Co)2].Thf
  作者:Kalck,Philippe; Serra,Carole; Machet,Corinne; Broussier,Roland; Gautheron,Bernard; Et Al
  参考文献:Organometallics 日期:1993 卷标:12(4) 页码:1021-2]
  
  119-26-6 = 888-54-0 [标题:Reaction Conditions
  标题:Measurements Of Aldehydes In Ambient Air
  作者:Kirschmer,Paul
  参考文献:Staub - Reinhaltung Der Luft 日期:1989 卷标:49 页码:263-6]
  
  119-26-6 = 888-54-0 [标题:Reaction Conditions
  标题:Halogenation Of Substituted Hydrazones. A Facile Route For The Synthesis Of Some New Hydrazidoyl Halides
  作者:Tewari,Ram S.; Parihar,Padma
  参考文献:Journal Of Chemical And Engineering Data 日期:1981 卷标:26(4) 页码:418-20]
  
  119-26-6 = 888-54-0 [标题:Reaction Conditions
  标题:Kinetics Of Silver(I)-Catalyzed Oxidation Of Allyl Alcohol By Peroxodiphosphate In Acetate Buffers
  作者:Sharma,Priyamvada; Sailani,Riya; Pareek,Deepmala; Khandelwal,Chandra Lata
  参考文献:Turkish Journal Of Chemistry 日期:2018 卷标:42(1) 页码:158-169]
  
  119-26-6 = 888-54-0
  反应条件:1.1 Solvents: Acetonitrile; 2 H,40 °C
  标题:Application Of Screening Experimental Designs To Assess Chromatographic Isotope Effect Upon Isotope-Coded Derivatization For Quantitative Liquid Chromatography-Mass Spectrometry
  作者:Szarka,Szabolcs; Prokai-Tatrai,Katalin; Prokai,Laszlo
  参考文献:Analytical Chemistry (Washington 日期:2014 卷标:86(14) 页码:7033-7040]
  
  119-26-6 = 888-54-0
  反应条件:1.1 Reagents: Sulfuric Acid
  标题:Determination Of Aldehydes And Ketones In Natural Gas Combustion In The Ppb Range By High-Performance Liquid Chromatography
  作者:Goetze,H. J.; Harke,S.
  参考文献:Fresenius' Zeitschrift Fuer Analytische Chemie 日期:1989 卷标:335(3) 页码:286-8]
  
  119-26-6 = 888-54-0
  反应条件:1.1 Catalysts: Propanenitrile,2-Oxo-
  标题:Determination Of Formaldehyde And Acetaldehyde In Mainstream Cigarette Smoke By High-Performance Liquid Chromatography
  作者:Houlgate,Peter R.; Dhingra,Kulbir S.; Nash,Stephen J.; Evans,William H.
  参考文献:Analyst (Cambridge 日期:1989 卷标:114(3) 页码:355-60]
  
  58948-97-3 + 119-26-6 = 888-54-0
  反应条件:1.1 Reagents: Hydrochloric Acid
  标题:Syntheses And Some Properties Of N-Unsubstituted Sulfilimines
  作者:Tamura,Y.; Matsushima,H.; Minamikawa,J.; Ikeda,M.; Sumoto,K.
  参考文献:Tetrahedron 日期:1975 卷标:31(24) 页码:3035-40]
  
  641144-66-3 = 888-54-0 + 641144-81-2 + 641144-74-3 + 28918-41-4 + 641144-75-4 + 641144-80-1
  反应条件:1.1 Reagents: Potassium Hydroxide Solvents: Water; 5 - 6 H,90 - 92 °C1.2 Solvents: Diethyl Ether1.3 Reagents: Hydrochloric Acid Solvents: Water
  标题:Rearrangement-Cleavage Of Ammonium Salts Containing A 3-Methyl-2-Naphthylmethyl Group
  作者:Oganesyan,N. R.; Grigoryan,Dzh. V.; Babayan,L. A.; Kocharyan,S. T.
  参考文献:Russian Journal Of General Chemistry (Translation Of Zhurnal Obshchei Khimii) 日期:2003 卷标:73(6) 页码:951-956

海关参考信息

• 2901210000-乙烯
  2901220000-丙烯
• 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
• 详情请参考：📖 海关编码查询和海关进出口税则

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