CAS: 83282-91-1; (2,3,5,6-Tetrafluoro-4-(Methoxymethyl)Phenyl)Methanol

• 英文名称(2,3,5,6-Tetrafluoro-4-(Methoxymethyl)Phenyl)Methanol
• 中文名称(2,3,5,6-四氟-4-(甲氧基甲基)苯基)甲醇
• IUPAC名称(2,3,5,6-tetrafluoro-4-(methoxymethyl)phenyl)methanol
• 其它别名2,3,5,6-四氟-4-甲氧甲基苯甲醇; 4-Methoxymethyl-2,3,5,6-Tetrafluorobenzyl Alcohol
• CAS编号83282-91-1
• MFCD编号:MFCD08688060
• EINECS号:846-804-2
• 分子式:C9H8F4O2
• 分子量:224.15
• 产品CID: 1822194
• 产品分类有机原料→分子砌块→芳环类化合物→苯类化合物

• 相似结构搜索
• InChIKey: YFHZSPDQKWFAPH-UHFFFAOYSA-N
• InChI=1S/C9H8F4O2/c1-15-3-5-8(12)6(10)4(2-14)7(11)9(5)13/h14H,2-3H2,1H3…
• 计算化学: 氢键受体数2.0氢键供体数1.0可旋转键数3.0

物理性质

• 熔点51-53 °C
• 沸点214°C at 760 mmHg
• 闪点106.8±22.5 °C
• 密度1.4±0.1 g/cm3
• pKa:12.85±0.10(预测)
• PSA:29.46
• LogP:1.8817
• 折射率1.464
• 蒸汽压0.1±0.4 mmHg at 25°C
• 溶解性Chloroform, Methanol
• 外观形态白色固体
• 储存条件密封, 常温干燥保存
• 产品应用该化合物用于合成甲基氯氟菊酯的试剂;一种具有抗蚊虫高蒸气活性的新强合成除虫菊酯.

MSDS等安全信息

• GHS象形图
• GHS符号GHS07;
  注释: Exclamation mark
• 危险类别急性毒性 类别4(经口)
  严重眼刺激 类别2
  皮肤致敏 类别1
• 警示词Warning(警告)
• 危险描述H302 |吞咽有害.
  H319 |造成严重眼刺激.
  H317 |可能引起皮肤过敏反应.
• 防范说明P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501
• 危险等级IRRITANT
• 危险品标志Xi
• 安全声明H303+H313+H333

欧盟法规

上下游产品

合成工艺路线路线简述

• 62172-93-4 = 83282-91-1
  反应条件:1.1 Reagents: Zinc Chloride,Sodium Borohydride Solvents: Diglyme; 24 H,Rt1.2 Solvents: Diglyme; 5 H,Reflux1.3 Reagents: Sulfuric Acid Solvents: Water
  标题:A New Synthetic Route To Polyfluorobenzyl Alcohol
  作者:Zhang,Deyan; Et Al
  参考文献:Journal Of Fluorine Chemistry 日期:2009 卷标:130(10) 页码:938-941]
  
  15041-74-4 = 83282-91-1
  反应条件:1.1 Reagents: Sodium Borohydride Catalysts: Tetrabutylammonium Chloride,Aluminum Chloride Solvents: Tetrahydrofuran; Rt; Rt -> Reflux; 8 H,Reflux; Reflux -> Rt1.2 Reagents: Hydrochloric Acid Solvents: Water2.1 Reagents: Sodium Hydroxide Solvents: Toluene,Water; 40 - 50 °C; 2 H,40 - 50 °C
  标题:Research On Synthesis Of 2,3,5,6-Tetrafluoro-4-Methoxyl Methyl Benzyl Alcohol
  作者:Yuan,Qiliang; Et Al
  参考文献:Huagong Shengchan Yu Jishu 日期:2013 卷标:20(6) 页码:11-14]
  
  92339-07-6 = 83282-91-1
  反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Toluene,Water; Ph 8 - 9,20 - 25 °C; 25 °C -> 35 °C1.2 30 - 35 °C; 5 H,30 - 35 °C
  标题:Synthesis Of Tetramethylfluthrin
  作者:He,Shu-Ze
  参考文献:Xiandai Nongyao 日期:2014 卷标:13(6) 页码:22-24]
  
  92339-07-6 = 83282-91-1
  反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Toluene,Water; 40 - 50 °C; 2 H,40 - 50 °C
  标题:Research On Synthesis Of 2,3,5,6-Tetrafluoro-4-Methoxyl Methyl Benzyl Alcohol
  作者:Yuan,Qiliang; Et Al
  参考文献:Huagong Shengchan Yu Jishu 日期:2013 卷标:20(6) 页码:11-14]
  
  443650-15-5 = 83282-91-1 [标题:Reaction Conditions
  标题:Metabolism Of The Pyrethroid Insecticide Momfluorothrin In Lettuce (Lactuca Sativa L.)
  作者:Matsushima,Keita; Et Al
  参考文献:Journal Of Agricultural And Food Chemistry 日期:2021 卷标:69(22) 页码:6156-6165]
  
  1897-41-2 = 83282-91-1
  反应条件:1.1 Reagents: Potassium Fluoride Solvents: Dimethylformamide; 6 - 10 H,150 - 160 °C1.2 Reagents: Sulfuric Acid Solvents: Water; 4 - 6 H,60 - 80 °C1.3 Reagents: Thionyl Chloride Solvents: Toluene; Rt -> Reflux; 6 H,Reflux; Reflux -> Rt1.4 Reagents: Sodium Borohydride Solvents: Tetrahydrofuran; 6 H,Heated1.5 Reagents: Hydrochloric Acid Solvents: Water; Acidified1.6 Reagents: Hydrogen Bromide Solvents: Toluene; 8 - 20 H,75 - 85 °C; 85 °C -> Rt1.7 Reagents: Sodium Methoxide Solvents: Toluene; 10 - 20 H,50 - 60 °C; 60 °C -> Rt1.8 Reagents: Water
  标题:Synthesis Of 3-(2,2-Dichloroethenyl)-2,2-Dimethylcyclopropanecarboxylic Acid [2,3,5,6-Tetrafluoro-4-(Methoxymethyl)Phenyl]Methyl Ester
  作者:Chen,Jianhai; Et Al
  参考文献:Nongyao 日期:2005 卷标:44(9) 页码:405-406]
  
  1204956-85-3 = 83282-91-1
  反应条件:1.1 Reagents: Butyllithium Solvents: Diethyl Ether; 20 Min,-78 °C; 60 Min,-78 °C1.2 1 H,-60 °C; -60 °C -> Rt; Rt1.3 40 Min,Rt1.4 Reagents: Hydrochloric Acid Solvents: Water2.1 Reagents: Zinc Chloride,Sodium Borohydride Solvents: Diglyme; 24 H,Rt2.2 Solvents: Diglyme; 5 H,Reflux2.3 Reagents: Sulfuric Acid Solvents: Water
  标题:A New Synthetic Route To Polyfluorobenzyl Alcohol
  作者:Zhang,Deyan; Et Al
  参考文献:Journal Of Fluorine Chemistry 日期:2009 卷标:130(10) 页码:938-941]
  
  = 83282-91-1 [标题:Reaction Conditions
  标题:Metabolism Of The Pyrethroid Insecticide Momfluorothrin In Lettuce (Lactuca Sativa L.)
  作者:Matsushima,Keita; Et Al
  参考文献:Journal Of Agricultural And Food Chemistry 日期:2021 卷标:69(22) 页码:6156-6165

海关参考信息

• 2902300000-甲苯
  2906210000-苄醇
  2909199090-其他醚及其衍生物
• 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
• 详情请参考：📖 海关编码查询和海关进出口税则

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