CAS: 821-41-0; 5-Hexen-1-Ol

• 英文名称5-Hexen-1-Ol
• 中文名称5-己烯-1-醇
• IUPAC名称hex-5-en-1-ol
• 其它别名5-己基-1-醇; 5己烯1醇
• CAS编号821-41-0
• MFCD编号:MFCD00002981
• EINECS号:212-477-4
• FDA UNII编号:57PD1RF6G7
• 分子式:C6H12O
• 分子量:100.16
• 产品CID: 1812996
• 产品分类有机原料→分子砌块→脂肪链类化合物

• 相似结构搜索
• 产品信息参考;;;;
• InChIKey: UIZVMOZAXAMASY-UHFFFAOYSA-N
• InChI=1S/C6H12O/c1-2-3-4-5-6-7/h2,7H,1,3-6H2…
• 计算化学: 氢键受体数1.0氢键供体数1.0可旋转键数4.0

相似化合物

物理性质

• 熔点<-20°C
• 沸点78-80 °C at 25 mmHg
• 闪点47°C
• 密度0.8±0.1 g/cm3
• PH:7 (H2O)
• pKa:15.17±0.10(预测)
• PSA:20.23
• LogP:1.335
• 折射率1.431
• 蒸汽压1.5±0.6 mmHg at 25°C
• 溶解性18.6G/l
• 敏感性常温常压下稳定，避免氧化物接触
• 外观形态透明无色液体
• 储存条件密封干燥,2-8°C
• 产品应用该化合物用于与三溴化磷发生反应后制成六溴-HEX-1-EN.
• 性质描述熔点 <-20°C ,沸点 78-80°C25mm Hg ,密度 0.834g/mLat 25°C ,折光率 n 20/D 1.435 ,闪点 117°F

MSDS等安全信息

• GHS象形图
• GHS符号GHS02 & GHS05;
  注释: Flame & Corrosion
• 危险类别易燃液体 类别3
  皮肤腐蚀 类别1B
  严重眼损伤 类别1
• 警示词Danger(危险)
• 危险描述H226 |易燃液体和蒸气.
  H314 |造成严重皮肤灼伤和眼损伤.
  H318 |造成严重眼损伤.
• 防范说明P210-P233-P240-P241-P242-P243-P260-P264-P280-P301+P330+P331-P304+P340-P363-P370+P378-P405-P501
• 危险等级3
• UN编号1987.0
• 危险品标志F
• 风险等级Flammable
• 包装等级Ⅲ
• 安全声明16-24/25
• 危险类别码10
• WGK Germany1

欧盟法规

上下游产品

合成工艺路线路线简述

• 928-90-5 = 821-41-0
  反应条件:1.1 Reagents: Formic Acid Catalysts: Quinuclidine,Gold (Amino-Functionalized Silica-Supported) Solvents: Acetone; 6 H,60 °C
  标题:Gold-Amine Cooperative Catalysis For Reductions And Reductive Aminations Using Formic Acid As Hydrogen Source
  作者:Fiorio,Jhonatan L.; Et Al
  参考文献:Applied Catalysis 日期:2020 卷标:267]
  
  176729-87-6 = 821-41-0
  反应条件:1.1 Reagents: 1-Butanaminium,N,N,N-Tributyl-,Salt With Peroxydisulfuric Acid ([(Ho)So2]2O2) ... Solvents: Acetonitrile1.2 Reagents: Sodium Methoxide Solvents: Methanol1.3 Reagents: Sulfuric Acid Solvents: Water
  标题:Tetrabutylammonium Peroxydisulfate In Organic Synthesis; Xi. A Novel And Selective Approach To The Oxidative Deprotection Of Allyl Ethers With Tetrabutylammonium Peroxydisulfate
  作者:Chen,Fen-Er; Et Al
  参考文献:Synthesis 日期:2001 卷标:(12) 页码:1772-1774]
  
  54653-25-7 = 821-41-0
  反应条件:1.1 Reagents: Lithium Aluminum Hydride Solvents: Diethyl Ether
  标题:Synthesis Of C3-C9-Alkenyl 2,3-Unsaturated Glucosides From Glucose And Some Alkenols
  作者:Konstantinovic,S.; Et Al
  参考文献:Indian Journal Of Chemistry 日期:2001 卷标:(9) 页码:802-805]
  
  40200-18-8 = 821-41-0 [标题:Reaction Conditions
  标题:Preparative Flash Vacuum Thermolysis. Selective Elimination Of 6-Chloro-1-Hexene From Esters Of 6-Chloro-1-Hexanol With Schoenberg Rearrangement Of The S-Methyl Xanthate
  作者:Jenneskens,Leonardus W.; Et Al
  参考文献:Journal Of Organic Chemistry 日期:1989 卷标:54(24) 页码:5811-14]
  
  10353-53-4 = 821-41-0
  反应条件:1.1 Catalysts: Methanesulfonic Acid,1,1,1-Trifluoro-,Erbium(3+) Salt (3:1),Dichloro[2-(Diphenylphosphino-Kp)-N-[2-(Diphenylphosphino-Kp)Ethyl]Ethanamine-Kn... Solvents: Tetrahydrofuran; 5 Min,23 °C1.2 Reagents: Ammonia Borane Solvents: Tetrahydrofuran; 8 H,45 °C
  标题:Erbium-Catalyzed Regioselective Isomerization-Cobalt-Catalyzed Transfer Hydrogenation Sequence For The Synthesis Of Anti-Markovnikov Alcohols From Epoxides Under Mild Conditions
  作者:Liu,Xin; Et Al
  参考文献:Acs Catalysis 日期:2020 卷标:10(22) 页码:13659-13667]
  
  10353-53-4 = 821-41-0
  反应条件:1.1 Catalysts: Borate(1-),Tetrafluoro-,Iron(2+) (2:1),Hexahydrate,Tris[2-(Diphenylphosphino)Phenyl]Phosphine,Zinc Triflate Solvents: 1,4-Dioxane; 3 Min,Rt1.2 Reagents: Formic Acid; 18 H,45 °C
  标题:Highly Selective And Practical Iron-Catalyzed Formal Hydrogenation Of Epoxides To Primary Alcohols Using Formic Acid
  作者:Yao,Yi-Xuan; Et Al
  参考文献:European Journal Of Organic Chemistry 日期:2023 卷标:26(14)]
  
  10353-53-4 = 821-41-0
  反应条件:1.1 Reagents: Trifluoroacetic Acid,Hydrogen Catalysts: Borate(1-),Tetrafluoro-,Iron(2+) (2:1),Tris[2-(Diphenylphosphino)Ethyl]Phosphine Solvents: 1,4-Dioxane; 18 H,40 Bar,80 °C
  标题:Iron-Catalyzed Regioselective Hydrogenation Of Terminal Epoxides To Alcohols Under Mild Conditions
  作者:Liu,Weiping; Et Al
  参考文献:Nature Catalysis 日期:2019 卷标:2(6) 页码:523-528]
  
  15912-74-0 + 20705-59-3 = 821-41-0
  反应条件:1.1 Reagents: Phosphorous Acid,Dihexyl Ester Solvents: Dimethyl Sulfoxide
  标题:Surprising Formation Of 5-Hexen-1-Ol By The Wittig Reaction Of 4-(2-Tetrahydropyranyloxy)-2-Butanone With Triphenylphosphinemethylene
  作者:Janistyn,Boris; Et Al
  参考文献:Chemische Berichte 日期:1975 卷标:108(4) 页码:1036-9]
  
  207795-48-0 = 821-41-0
  反应条件:1.1 Reagents: Montmorillonite ((Al1.33-1.67Mg0.33-0.67)(Ca0-1Na0-1)0.33Si4(Oh)2O10.Xh2O),Ammonium Nitrate
  标题:Microwave Thermolysis. Iv. Selective Deprotection Of Mpm Ethers Using Clay Supported Ammonium Nitrate "Clayan" In Dry Media
  作者:Yadav,J. S.; Et Al
  参考文献:Tetrahedron Letters 日期:1998 卷标:39(19) 页码:3043-3046]
  
  627-32-7 = 821-41-0
  反应条件:1.1 Reagents: Lithium Chloride,Ammonium Bromide,Polyethylene Glycol Catalysts: Palladium Diacetate,Copper Diacetate Monohydrate Solvents: Dimethylformamide,Water; 12 H,0 °C
  标题:Palladium-Catalyzed Electrochemical Allylic Alkylation Between Alkyl And Allylic Halides In Aqueous Solution
  作者:Lai,Yin-Long; Et Al
  参考文献:Organic Letters 日期:2017 卷标:19(8) 页码:2022-2025]
  
  503-30-0 + 762-72-1 = 821-41-0
  反应条件:1.1 Reagents: Titanium Tetrachloride Solvents: Dichloromethane
  标题:The Electrophilic Substitution Of Allylsilanes And Vinylsilanes
  作者:Fleming,Ian; Et Al
  参考文献:Organic Reactions (Hoboken 日期:1989 卷标:37]
  
  821-41-0 = 821-41-0
  反应条件:1.1 Reagents: Chlorotrimethylsilane,[6-[bis(1-Methylethyl)Silyl]Hexyl]Benzene (Wang Resin-Bound) Solvents: Dichloromethane; 0.5 H,Rt1.2 Reagents: Trifluoromethanesulfonic Acid Solvents: Dichloromethane; 0.5 H,Rt1.3 Reagents: 4-(Dimethylamino)Pyridine,Diisopropylethylamine Solvents: Dichloromethane; 1 H,Rt
  标题:An Efficient Synthesis Of Polymer-Supported Silyl Linkers Using A Di-Grignard Reagent
  作者:Doi,Takayuki; Et Al
  参考文献:Tetrahedron Letters 日期:2004 卷标:45(29) 页码:5723-5726]
  
  928-90-5 = 821-41-0
  反应条件:1.1 Reagents: Hydrogen Catalysts: Palladium,Carbon Solvents: Ethanol; 3.4 H,1 Atm,Rt
  标题:Selective Semihydrogenation Of Alkynes Catalyzed By Pd Nanoparticles Immobilized On Heteroatom-Doped Hierarchical Porous Carbon Derived From Bamboo Shoots
  作者:Ji,Guijie; Et Al
  参考文献:Chemsuschem 日期:2017 卷标:10(17) 页码:3427-3434]
  
  928-90-5 = 821-41-0
  反应条件:1.1 Reagents: Dimethylamine-Borane Catalysts: Gold,Titania Solvents: Ethanol; 0.5 H,25 °C
  标题:Cis-Semihydrogenation Of Alkynes With Amine Borane Complexes Catalyzed By Gold Nanoparticles Under Mild Conditions
  作者:Vasilikogiannaki,Eleni; Et Al
  参考文献:Chemical Communications (Cambridge 日期:2015 卷标:51(12) 页码:2384-2387]
  
  = 821-41-0
  反应条件:1.1 Reagents: Triphenylphosphine,Oxygen Catalysts: Rhenium Oxide (Re2O7); 1 H,Rt -> 165 °C
  标题:Rhenium-Catalyzed Deoxydehydration Of Renewable Triols Derived From Sugars
  作者:Wozniak,Bartosz; Et Al
  参考文献:Green Chemistry 日期:2018 卷标:20(19) 页码:4433-4437]
  
  = 821-41-0
  反应条件:1.1 Reagents: 3-Octanol Catalysts: Titania,Ammonium Perrhenate; 1 H,170 °C
  标题:Reox/tio2: A Recyclable Solid Catalyst For Deoxydehydration
  作者:Sandbrink,Lennart; Et Al
  参考文献:Acs Catalysis 日期:2016 卷标:6(2) 页码:677-680]
  
  176729-87-6 = 821-41-0
  反应条件:1.1 Catalysts: Ruthenium(1+),(η5-2,4-Cyclopentadien-1-Yl)(η3-2-Propen-1-Yl)(2-Quinolinecarboxy... Solvents: Methanol
  标题:Ruthenium(1+),(η5-2,4-Cyclopentadien-1-Yl)(η3-2-Propen-1-Yl)(2-Quinoline-Carboxylato-Kn1,Ko2)-,Hexafluorophosphate(1-) (1:1)1,2
  作者:Tanaka,Shinji; Et Al
  参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2010 卷标:1 页码:1-3]
  
  43216-12-2 = 821-41-0
  反应条件:1.1 Reagents: Indium Solvents: Methanol; 4.5 H,Rt; Rt -> 65 °C; 3 - 5 H,60 - 65 °C
  标题:Ultrasound-Accelerated Synthesis Of Chiral Allylic Alcohols Promoted By Indium Metal
  作者:Yadav,J. S.; Et Al
  参考文献:Tetrahedron 日期:2003 卷标:59(28) 页码:5333-5336]
  
  43216-12-2 = 821-41-0
  反应条件:1.1 Reagents: Triethylamine,Tetrabutylammonium Iodide Catalysts: Borane,Bromodimethyl- Solvents: Dichloromethane
  标题:Exceptionally Mild And Stereospecific Ring Fragmentations Promoted By Dimethylboron Bromide
  作者:Gauthier,Jacques Yves; Et Al
  参考文献:Tetrahedron Letters 日期:1987 卷标:28(48) 页码:5985-8]
  
  764-59-0 = 821-41-0
  反应条件:1.1 Reagents: Pinacolborane Catalysts: 2423988-10-5; 12 H,60 °C1.2 Reagents: Methanol; 6 H,60 °C
  标题:Palladium-Catalyzed Selective Reduction Of Carbonyl Compounds
  作者:Sarkar,Nabin; Et Al
  参考文献:European Journal Of Inorganic Chemistry 日期:2020 卷标:2020(23) 页码:2295-2301]
  
  764-59-0 = 821-41-0
  反应条件:1.1 Reagents: Cesium Carbonate,Hydrogen Catalysts: Silver Solvents: Tetrahydrofuran; 12 H,15 Atm,60 °C
  标题:Remarkable Effect Of Bases On Core-Shell Agnp@ceo2 Nanocomposite-Catalyzed Highly Chemoselective Reduction Of Unsaturated Aldehydes
  作者:Mitsudome,Takato; Et Al
  参考文献:Chemistry Letters 日期:2013 卷标:42(6) 页码:660-662]
  
  95650-46-7 = 821-41-0 [标题:Reaction Conditions
  标题:Study Of Interactions Between Alcohol And Amine Functions. Ii. Thermolysis Of N-Oxides Of ω-(Dialkylamino)-1-Alkanols
  作者:Barbry,Didier; Et Al
  参考文献:Collection Of Czechoslovak Chemical Communications 日期:1984 卷标:49(10) 页码:2410-14]
  
  1315481-26-5 = 821-41-0
  反应条件:1.1 Reagents: Sodium Solvents: Tetrahydrofuran; Rt
  标题:M-Terphenyl Ethers,A New Hydroxy Protecting Group Cleavable Under Reductive Single Electron Transfer Reaction Conditions
  作者:Azzena,Ugo; Et Al
  参考文献:Synthesis 日期:2011 卷标:(10) 页码:1575-1580]
  
  185999-03-5 = 821-41-0
  反应条件:1.1 Catalysts: 2,4,6-Triphenylpyrylium Tetrafluoroborate Solvents: Dichloromethane; 5 Min,Rt; 2 H,Rt
  标题:Photocatalytic Cleavage Of Trityl Protected Thiols And Alcohols
  作者:Murakami,Sho; Et Al
  参考文献:Synthesis 日期:2023 卷标:55(9) 页码:1367-1374]
  
  1260112-02-4 = 821-41-0
  反应条件:1.1 Reagents: Oxygen Catalysts: Triethylamine,Rose Bengal Solvents: Ethanol; 12 H,Rt
  标题:Visible-Light-Mediated Aerobic Oxidation Of Organoboron Compounds Using In Situ Generated Hydrogen Peroxide
  作者:Weng,Wei-Zhi; Et Al
  参考文献:Organic Letters 日期:2018 卷标:20(16) 页码:4979-4983]
  
  18922-04-8 = 821-41-0
  反应条件:1.1 Reagents: Tert-Butyllithium,Oxygen Solvents: Diethyl Ether,Pentane
  标题:Preparation And Regiospecific Cyclization Of Alkenyllithiums
  作者:Bailey,William F.; Et Al
  参考文献:Journal Of The American Chemical Society 日期:1987 卷标:109(8) 页码:2442-8]
  
  2423988-14-9 = 821-41-0
  反应条件:1.1 Reagents: Silica Solvents: Methanol; 6 H,60 °C
  标题:Aluminium-Catalyzed Selective Hydroboration Of Esters And Epoxides To Alcohols: C-O Bond Activation
  作者:Sarkar,Nabin; Et Al
  参考文献:Chemistry - A European Journal 日期:2023 卷标:29(4)]
  
  2423988-14-9 = 821-41-0
  反应条件:1.1 Reagents: Methanol; 6 H,60 °C
  标题:Palladium-Catalyzed Selective Reduction Of Carbonyl Compounds
  作者:Sarkar,Nabin; Et Al
  参考文献:European Journal Of Inorganic Chemistry 日期:2020 卷标:2020(23) 页码:2295-2301]
  
  627-32-7 = 821-41-0
  反应条件:1.1 Reagents: Lithium Chloride,Ammonium Bromide,Polyethylene Glycol Catalysts: Palladium Diacetate,Copper Diacetate Monohydrate Solvents: Dimethylformamide,Water; 12 H,0 °C
  标题:Palladium-Catalyzed Electrochemical Allylic Alkylation Between Alkyl And Allylic Halides In Aqueous Solution
  作者:Lai,Yin-Long; Et Al
  参考文献:Organic Letters 日期:2017 卷标:19(8) 页码:2022-2025]
  
  503-30-0 + 762-72-1 = 821-41-0
  反应条件:1.1 Catalysts: Titanium Tetrachloride
  标题:Trimethylene Oxide
  作者:Henegar,Kevin E.
  参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2001]
  
  503-30-0 + 762-72-1 = 821-41-0
  反应条件:1.1 Catalysts: Titanium Tetrachloride Solvents: Dichloromethane
  标题:Titanium Tetrachloride Promoted Reactions Of Allylic Trimethylsilanes And Oxetane
  作者:Carr,Steve A.; Et Al
  参考文献:Journal Of Organic Chemistry 日期:1985 卷标:50(15) 页码:2782-5

海关参考信息

• 2901210000-乙烯
  2901220000-丙烯
  2905121000-正丙醇
  2905130000-正丁醇
• 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
• 详情请参考：📖 海关编码查询和海关进出口税则

专利信息

其他信息查阅

• ➥ 象形图和危险代码
• ➥ 防范代码详解
• ➥ 危险代码说明
• ➥ Globally Harmonized System
• ➥ REACH监管