📜三羟甲基丙烷,硬酯酸甲酯c18置于3C9H14No3S(1+)*o40Pw12(3-)体系中,化学反应 3.5H,反应生成三羟甲基丙烷三硬脂酸酯
参考文献:Heteropolyacid Salts As Self-Separation And Recyclable Catalysts For Transesterification Of Trimethylolpropane
标题:Heteropolyacid Salts As Self-Separation And Recyclable Catalysts For Transesterification Of Trimethylolpropane
摘要:A Series Of Heteropolyacid (Hpa) Salts As Catalysts Were Prepared And Characterized. Transesterifications Of Trimethylolpropane (Tmp) Were Carried Out Using These Catalysts. The Influence Of Organic Cations And Heteropolyanions On The Reaction,Optimization Of Reaction Conditions,And Catalytic Reusability Were Investigated. The Results Show That The Heteropolyacid (Hpa) Salts Present A Self-Separation Performance After Reaction,Which Can Be Easily Recovered And Quite Steadily Reused As Demonstrated By A Eight-Run Recycling Test. Moreover,The Pyridinium With Pw12O403-As The Anion ([pybs](3)Pw12O40) Showed The Best Catalytic Performance Among The Heteropolyacid Salts For The Transesterification Of Trimethylolpropane With Various Methyl Esters. (C) 2010 Elsevier B.V. All Rights Reserved.
Doi:10.1016/j.Apcata.2010.11.011