CAS: 122-72-5; 3-Phenylpropyl Acetate
该化合物是按酯类分类的有机化合物,由3-苯丙丙胺-1-醇和乙酸形成,该化合物一般是一种无色的淡黄色液体,带有甜甜的果味,在香味和香味工业中有用,其分子式为C12H14O2, 其沸点相对较低,导致其挥发性.3-苯丙丙基乙酸因在有机溶剂中的溶性而闻名,而在水中溶性较低.该化合物在标准条件下具有中度稳定性,但在有强酸或碱的情况下可能进行水解.重要的是要谨慎地处理该物质,因为它可能会对皮肤和接触的眼产生刺激.此外,与许多酯一样,该物质在储存和使用期间可能是易燃的,需要适当的安全措施.总体,3-苯丙基乙酸酯对于其芳酸性和多种用途具有价值.
- 英文名称3-Phenylpropyl Acetate
- 中文名称3-苯丙基乙酸酯
- IUPAC名称3-phenylpropyl acetate
- 其它别名3-phenyl-1-propano acetate; 3-phenyl-1-propyl acetate; 3-phenylpropyl acetate; hydr°Cinnamyl acetate; phenylpropyl acetate
- CAS编号122-72-5
- MFCD编号:MFCD00026216
- EINECS号:204-569-8
- FDA UNII编号:AKW166708I
- 分子式:C11H14O2分子量:178.23
- 产品CID: 326092
- 产品分类有机原料→香精香料→青绿香→香脂香（树脂甜暖）
相似化合物
122-97-4 2021-28-5 103-25-3物理性质
- 熔点-60 °C
- 沸点244 °C at 760 mmHg
- 闪点>230 °F
- 密度1.012 g/mL at 25 °C(文献)
- PSA:26.3
- LogP:2.1823
- 折射率n20/D 1.496(文献)
- 蒸汽压0.0106mmHg at 25°C
- 溶解性0.69G/l
- 外观形态无色至几乎无色透明液体
- 储存条件存储低于 +30°C.
- 产品应用该化合物用于香水成分中,它与LINALOOL家族,STYRAX和YLANG,LABDANUM,AMYSALICYLATE等"玫瑰酒精"混杂在一起.它的中性甜度使它具有多种特性,但不会给成分带来太多臭味.少量的香料,水果组合和某些果类口味,包括樱桃.这种口味的浓度相当于功能产品的0.5至10PPM.
- 性质描述沸点252.3°C , 熔点 -60°C , 密度 1.012g/mLat 25°C , 折光率 n 20/D 1.496
MSDS等安全信息
欧盟法规
REACH注册ECHA物质C&L通报REACH预注册上下游产品
CAS号122-97-4 3-苯丙醇 | CAS号108-24-7 乙酸酐 | CAS号127-09-3 乙酸钠 | CAS号104-52-9 3-苯基-1-氯丙烷 | CAS号631-61-8 乙酸铵 | CAS号103-54-8 乙酸桂酯 | CAS号75-36-5 乙酰氯 | CAS号64-19-7 冰醋酸 | CAS号21040-45-9 乙酸(肉)桂酯 | CAS号108-22-5 醋酸异丙烯酯 | CAS号106797-55-1 2-hydroxy-1-[4-... | CAS号122-97-4 3-苯丙醇 | CAS号108-95-2 苯酚 | CAS号5848-56-6 (3-ethoxypropyl... | CAS号2290-40-6 1-Phenyl-3-(tri... | CAS号30134-12-4 Benzene,[(3-phe... | CAS号7334-41-0 (3-oxo-3-phenyl... | CAS号21763-02-0 1-Brom-3-acetox... | CAS号58810-86-9 3-(4-acetylphen... | CAS号58810-87-0 4-(3-羟基丙基)苯甲酸合成工艺路线路线简述
- 合成目标产物 3-Phenylpropyl Acetate 主要起始原料 3-Phenyl-1-Propanol And Ammonium Acetate
- (文献来源)合成步骤主要原料 3-Phenyl-1-Propanol 和 Ammonium Acetate
📜3-溴苄溴置于三氯溴甲烷,(4,4'-Di-Tert-Butyl-2,2'-Dipyridyl)-Bis-(2-Phenylpyridine(-1H))-Iridium(III) Hexafluorophosphate,Sodium Hydride体系中,用 四氢呋喃,二氯甲烷,Mineral Oil 用作溶剂,化学反应 36.5H,反应生成乙酸-3-苯基丙酯
参考文献:通过o-α-Sp可见光推荐烷基苄基醚转化成烷基酯或醇3 C-H裂解
标题:通过o-α-Sp可见光推荐烷基苄基醚转化成烷基酯或醇3 C-H裂解
摘要:开发了一种温和且高产的可见光促进的烷基苄基醚向烷基酯或烷基醇的转化.机制研究涉及的均裂自由基链反应提供了证据ö-α-Sp 3 C-H键在基板的传播的步骤之一.我们建议α-溴醚是转化的关键中间体.
Doi:10.1021/acs.Orglett.5B00663
海关参考信息
- 2902600000-乙苯
2905121000-正丙醇
2909110000-乙醚
2912110000-甲醛 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
专利信息
专利号:US-2004152905-A1
优先权日:2003-01-31
标题:Universal building blocks and support media for synthesis of oligonucleotides and their analogs
发明人：GUZAEV ANDREI P; MANOHARAN MUTHIAH
摘要:Compounds for the synthesis of oligomeric compounds, particularly oligonucleotides and chemically modified oligonucleotide analogs, are provided. In addition, methods for functionalization of a support medium with a first monomeric subunit and methods for the synthesis of oligomeric compounds utilizing the novel compounds bound to support media are provided.
专利号:US-4182719-A
优先权日:1977-05-17
标题 :Synthesis of optically active vitamin E
发明人：COHEN NOAL; SAUCY GABRIEL
权利人:HOFFMANN LA ROCHE
摘要:Synthesis of optically active vitamin E from 2-methyl-5-oxotetrahydro-2-furoic acid including intermediates in this synthesis.
专利号:US-4598160-A
优先权日:1983-07-15
标题 :Intermediate phenolic compounds for the catalytic synthesis of chromans
发明人：TRUESDALE LARRY K
权利人:HOFFMANN LA ROCHE
摘要:A catalytic synthesis of chromans in racemic or optically active forms, including intermediates thereto; the synthesis employs an asymmetric palladium (II) catalyzed oxidative cyclization of a 2-homoallylphenol and provides intermediates useful in making chromans, especially vitamin E in racemic or optically active forms.
专利号:US-4208332-A
优先权日:1977-05-17
标 题:Synthesis of optically active vitamin E
发明人：COHEN NOAL; SAUCY GABRIEL
权利人:HOFFMANN LA ROCHE
摘要:Synthesis of optically active vitamin E from 2-methyl-5-oxotetrahydro-2-furoic acid including intermediates in this synthesis.
专利号:US-4208331-A
优先权日:1977-05-17
标 题:Synthesis of optically active vitamin E
发明人：COHEN NOAL; SAUCY GABRIEL
权利人:HOFFMANN LA ROCHE
摘要:Synthesis of optically active vitamin E from 2-methyl-5-oxotetrahydro-2-furoic acid including intermediates in this synthesis.
专利号:US-4151177-A
优先权日:1977-05-17
标题:Synthesis of optically active vitamin E
发明人：COHEN NOAL; SAUCY GABRIEL
权利人:HOFFMANN LA ROCHE
摘要:Synthesis of optically active vitamin E from 2-methyl-5-oxotetrahydro-2-furoic acid including intermediates in this synthesis.
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
合成参考文献
摘要:Takeda, T.; Tsubouchi, A., Science of Synthesis Knowledge Updates, (2011) 3, 12.
摘要:Champagne, P. A.; Drouin, M.; Paquin, J.-F., Science of Synthesis Knowledge Updates, (2016) 1, 425.
摘要:Rueda-Becerril, M.; Sammis, G. M., Science of Synthesis Knowledge Updates, (2017) 2, 215.
摘要:Driver, T. G., Science of Synthesis: Cross Coupling and Heck-Type Reactions, (2012) 2, 307.
摘要:Mace Weldy, N.; Blakey, S. B., Science of Synthesis: Catalytic Transformations via CH Activation, (2015) 2, 269.
📝 需求与反馈
尽可能描述清楚需求与问题信息
