CAS: 101-48-4; Phenylacetaldehyde Dimethyl Acetal

该化合物是一个有机化合物,其特点是其丙烯功能组,其产物为苯乙二烯,以其香味闻名,在香味和调味行业有用,该化合物一般没有色素,可粉黄液体,在有机溶剂中可溶解,但由于其疏水芳香结构,其溶解性在水中有限.其化学配方反映其苯和甲酰二甲胺的功能,有助于其再活动,并有可能在有机合成中的潜在应用.作为乙酰,在中性条件下相对稳定,但在酸或基地存在时可进行水解,恢复到相应的甲酰胺.安全数据表明,应谨慎处理该化合物,因为它在与皮肤或眼睛接触时可能会引起刺激.

结构式图片

相似化合物

6314-97-2 23786-13-2 101-41-7

欧盟法规

REACH注册ECHA物质C&L通报REACH预注册

上下游产品

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合成工艺路线路线简述

    [(1-Methoxy-2-Phenylethyl)Sulfanyl]Benzene置于对甲苯磺酸体系中,用 甲醇 用作溶剂,化学反应 2.0H,以72%的收率获得1,1-二甲氧基-2-苯基乙烷
    参考文献:Synthetic Application Of Phenylthio-And Phenylsulfonylmethyl Ethers To Aldehydes,Methylals,Carboxylic Acids,And Enol Or Dienol Ethers
    标题:Synthetic Application Of Phenylthio-And Phenylsulfonylmethyl Ethers To Aldehydes,Methylals,Carboxylic Acids,And Enol Or Dienol Ethers
    摘要:
    Doi:10.1016/s0040-4039(01)99830-2

    专利信息


    专利号:US-2010099894-A1
    优先权日:2006-10-09
    标 题 :Method for the Synthesis of Cyclic Acetals by the Reactive Extraction of a Polyol in a Concentrated Solution
    发明人:DUBOIS JEAN-LUC; IBORRA CHORNET SARA; VELTY ALEXANDRA I LUCIENNE; CORMA CANOS AVELINO
    权利人:DUBOIS JEAN-LUC; IBORRA CHORNET SARA; VELTY ALEXANDRA I LUCIENNE; CORMA CANOS AVELINO
    摘要:A method for the synthesis of cyclic acetals comprises reacting at least one carbonyl-function compound selected from aldehydes, ketones, and/or linear acetals, on a polyol in a concentrated aqueous solution exceeding 20 wt % in a reactor containing an acidic catalyst. The carbonyl-function compound is selected so that the cyclic acetal obtained has a water solubility lower than 20000 mg/kg. During the catalytic reaction for the cyclic acetal synthesis, at least one portion of the organic phase containing the cyclic acetal is separated. The acidic catalysis is either homogeneous when using a water-soluble strong acid, or heterogeneous when using a solid acid such as a resin, a zeolite, or any appropriately acidified solid. The extractive reaction method can be used for obtaining high conversions and selectivity.

    专利号:US-2528978-A
    优先权日:1949-05-21
    标题 :Synthesis of pyridine bases
    发明人:SMITH CURTIS W; BALLARD SEAVER A
    权利人:SHELL DEV

    专利号:US-12076423-B2
    优先权日:2015-12-23
    标题 :Spiculisporic acid-based composition
    发明人:AGNAOU REDA; MARION CATHERINE
    权利人:OREAL
    摘要:Composition in the form of an oil-in-water emulsion that includes at least 1% of an oil phase, and an aqueous phase. The composition includes 0.1 to 15 wt % spiculisporic acid relative to the total weight of the composition, at least one base selected from amino acids and alkanolamines in an amount suitable for forming at least a monosalt of spiculisporic acid, less than 3% glycol(s) and/or polyol(s) relative to the total weight of the composition, at least one UV filter and/or an additive selected from volatile aromatic materials such as essential oils and fragrance substances, fillers, dyeing materials such as pigments, mother-of-pearl or particles with a metallic sheen, moisturizers, anti-wrinkle or anti-age agents, peeling agents, antioxidants, active ingredients stimulating the synthesis of epidermal and/or dermal macromolecules, dermo-relaxing agents, depigmentation agents, deodorant agents and mixtures thereof.

    专利号:EP-2076505-A1
    优先权日:2006-10-09
    标 题 :Method for the synthesis of cyclic acetals by the reactive extraction of a polyol in a concentrated solution

    专利号:JP-2001505558-A
    优先权日:1996-11-15
    标 题:Combinatorial synthesis of hydrocarbon libraries

    专利号:WO-2008043947-A1
    优先权日:2006-10-09
    标题 :Method for the synthesis of cyclic acetals by the reactive extraction of a polyol in a concentrated solution
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    合成参考文献


    摘要:Spivey, A. C.; Tseng, C.-C., Science of Synthesis Knowledge Updates, (2010) 1, 37.
    摘要:Molander, G. A.; Beaumard, F., Science of Synthesis Knowledge Updates, (2013) 3, 139.
    摘要:Mérour, J.-Y.; Joseph, B., Science of Synthesis Knowledge Updates, (2016) 3, 18.
    摘要:Fowler, L. S.; Sutherland, A., Science of Synthesis Knowledge Updates, (2010) 3, 124.
    摘要:Fowler, L. S.; Sutherland, A., Science of Synthesis Knowledge Updates, (2010) 3, 146.
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