CAS: 97-74-5; Tetramethylthiuram Monosulfide

• ⚠️《化妆品禁用原料目录》
• 英文名称Tetramethylthiuram Monosulfide
• 中文名称硫化物,二(二甲基硫代氨基甲酰基)(8CI)
• IUPAC名称dimethylcarbamothioyl N,N-dimethylcarbamodithioate
• 其它别名一硫化四甲基秋兰姆; Tmtm
• CAS编号97-74-5
• MFCD编号:MFCD00014870
• EINECS号:202-605-7
• FDA UNII编号:01W430XXSQ
• 分子式:C6H12N2S3
• 分子量:208.37
• 产品CID: 2022832
• 产品分类有机原料→分子砌块→脂肪链类化合物

• 相似结构搜索
• InChIKey: REQPQFUJGGOFQL-UHFFFAOYSA-N
• InChI=1S/C6H12N2S3/c1-7(2)5(9)11-6(10)8(3)4/h1-4H3…
• 计算化学: 氢键受体数3.0氢键供体数0.0可旋转键数0.0

相似化合物

物理性质

• 熔点107-111 °C
• 沸点260.9±23.0 °C at 760 mmHg
• 闪点111.6±22.6 °C
• 密度1.3±0.1 g/cm3
• pKa:0.93±0.50(预测)
• PSA:6.48
• LogP:1.4126
• 折射率1.641
• 蒸汽压0.0±0.5 mmHg at 25°C
• 溶解性Chloroform, Methanol (Slightly)
• 敏感性1、避免与强氧化剂接触。2、溶于苯、丙酮、二氯乙烷、二硫化碳、甲苯、氯仿，微溶于乙醇和乙醚，不溶于汽油和水。无臭、无味、无毒。储藏稳定。
• 外观形态黄色粉末
• 储存条件安瓿瓶, 冰箱
• 产品应用用作天然橡胶与合成橡胶的硫化促进剂.
• 性质描述淡黄色结晶粉末.熔点104°C.溶于乙醇,氯仿,苯,丙酮,二氯乙烷,二硫化碳,微溶于冷乙醚,不溶于水,气油.无臭,无味.贮藏稳定.

MSDS等安全信息

• GHS象形图
• GHS符号GHS07 & GHS09;
  注释: Exclamation mark & Environment
• 危险类别急性毒性 类别4(经口)
  皮肤致敏 类别1
  水生慢性毒性 类别2
  致突变性 类别2
  急性毒性 类别4(吸入)
  水生急性毒性 类别1
  水生慢性毒性 类别1
  特定目标器官毒性-重复接触 类别2
• 警示词Warning(警告)
• 危险描述H302 |吞咽有害.
  H317 |可能引起皮肤过敏反应.
  H411 |对水生生物有毒并具有长期持续影响.
  H341 |怀疑导致遗传缺陷.
  H332 |吸入有害.
  H400 |对水生生物毒性极大.
  H410 |对水生生物毒性极大并具有长期持续影响.
  H373 |长期或反复接触可能损害器官.
• 防范说明P261-P264-P270-P273-P284-P304+P340-P330-P391-P501
• 危险等级9
• UN编号3077.0
• 危险品标志Xn,N
• 包装等级Ⅲ
• 安全声明24-26-37-61
• 危险类别码22-43-51/53
• WGK Germany3

欧盟法规

上下游产品

合成工艺路线路线简述

• 128-04-1 + 79-44-7 = 97-74-5
  反应条件:1.1 Solvents: Tetrachloroethylene
  标题:Preparation Of Tetraalkylthiuram Monosulfides
  参考文献:Japan]
  
  = 97-74-5 [标题:Reaction Conditions
  标题:Method For Manufacturing Tetramethylthiuram Monosulfide Rubber Vulcanization Acceleratorsynthesis Of Heterocyclic Compounds And New Routes For The Preparation Of Certain Dithiocarbonates And Sulfides From Potassium Cyanodithioimidocarbonatetetramethylthiuram Monosulfide
  作者:Ruminski,Peter G.; Et Al
  参考文献:China 日期:1984 卷标:19(3) 页码:335-44]
  
  = 97-74-5
  反应条件:1.1 16 H,Rt2.1 Solvents: Acetonitrile; Overnight,Rt
  标题:Bis(Dialkylaminethiocarbonyl)Disulfides As Potent And Selective Monoglyceride Lipase Inhibitors
  作者:Kapanda,Coco N.; Et Al
  参考文献:Journal Of Medicinal Chemistry 日期:2009 卷标:52(22) 页码:7310-7314]
  
  128-03-0 = 97-74-5
  反应条件:1.1 Reagents: Iodine Solvents: Ethanol2.1 Reagents: Potassium Cyanide Solvents: Ethanol1.1 Reagents: Sulfur Monochloride Solvents: Benzene2.1 Solvents: Benzene3.1 Reagents: Potassium Cyanide Solvents: Ethanol1.1 Reagents: Sulfur Dichloride Solvents: Benzene2.1 Solvents: Benzene3.1 Reagents: Potassium Cyanide Solvents: Ethanol
  标题:On Chalcogenolates. 185. Bis(N,N-Dimethylthiocarbamoyl)Sulfaneson Chalcogenolates. 185. Bis(N,N-Dimethylthiocarbamoyl)Sulfaneson Chalcogenolates. 185. Bis(N,N-Dimethylthiocarbamoyl)Sulfanes
  作者:Knoth,W.; Et Al Knoth,W.; Et Al Knoth,W.; Et Al
  参考文献:Zeitschrift Fuer Anorganische Und Allgemeine Chemie 日期:1988 卷标:(1988) 页码:141-5]
  
  79-45-8 = 97-74-5
  反应条件:1.1 Reagents: Hydrogen Peroxide; 45 °C; 3 H,45 °C2.1 Reagents: Sodium Cyanide; 45 °C -> 80 °C; 2.5 H,80 °C
  标题:Method For Preparing Tetramethylthiuram Disulfide
  参考文献:China]
  
  = 97-74-5 + 540-72-7
  反应条件:1.1 Reagents: Sodium Nitrite; Rt -> 80 °C; 2.5 H,80 °C
  标题:Preparation Of Rubber Accelerator Tetramethyl Thiuram Monosulfide And Its Spectral Analysis
  作者:Wang,Zhen-Xiang; Et Al
  参考文献:Guangpuxue Yu Guangpu Fenxi 日期:2015 卷标:35(7) 页码:1875-1878]
  
  = 97-74-5 + 3878-45-3 + 540-72-7
  反应条件:1.1 Solvents: Ethanol,Water; 10 - 15 °C; 1.5 H,15 °C -> 20 °C1.2 Reagents: Hydrogen Peroxide Solvents: Water; 15 - 20 °C; 2.5 H,15 - 20 °C1.3 Solvents: Water; 15 - 20 °C; 1.5 H,15 - 20 °C1.4 Solvents: Ethanol; 15 - 20 °C; 3.5 H,15 - 20 °C
  标题:Preparation Of Tetraalkylthiuram Monosulfide
  参考文献:China]
  
  = 97-74-5
  反应条件:1.1 Reagents: Sodium Cyanide,Ammonium Chloride1.1 Reagents: Hexaethylphosphorous Triamide Solvents: Methanol; 14 H,23 °C1.1 Reagents: Sodium Cyanide; 45 °C -> 80 °C; 2.5 H,80 °C
  标题:Synthesis Of Tetramethylthiuram Monosulfideone-Step Simultaneous Synthesis Of An Industrially Important Rubber Accelerator And A Lubricant Additive By Disulfide Bond Contractionmethod For Preparing Tetramethylthiuram Disulfide
  作者:Milosavjevic,Milutin; Et Al Xu,Hao-Xing; Et Al
  参考文献:Hemijska Industrija 日期:1992 卷标:34(1) 页码:193-6]
  
  16420-13-6 + 79-45-8 = 97-74-5
  反应条件:1.1 Solvents: Acetonitrile; Overnight,Rt
  标题:Bis(Dialkylaminethiocarbonyl)Disulfides As Potent And Selective Monoglyceride Lipase Inhibitors
  作者:Kapanda,Coco N.; Et Al
  参考文献:Journal Of Medicinal Chemistry 日期:2009 卷标:52(22) 页码:7310-7314]
  
  16420-13-6 + 128-04-1 = 97-74-5
  反应条件:1.1 Solvents: Acetonitrile; 1 - 2 H,0 - 5 °C
  标题:Substituted Carbamothioic Amine-1-Carbothioic Thioanhydrides As Novel Trichomonicidal Fungicides: Design,Synthesis,And Biology
  作者:Mandalapu,Dhanaraju; Et Al
  参考文献:European Journal Of Medicinal Chemistry 日期:2018 卷标:143 页码:632-645]
  
  128-04-1 = 97-74-5
  反应条件:1.1 Reagents: Potassium Ferricyanide Solvents: Water
  标题:Water-Soluble Dithioformate Raft Reagent And Preparation Method
  参考文献:China]
  
  = 97-74-5
  反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Ethyl Acetate,Water; 30 Min,0 - 5 °C2.1 Solvents: Acetonitrile; 1 - 2 H,0 - 5 °C1.1 2 H,45 °C2.1 Reagents: Hydrogen Peroxide; 45 °C; 3 H,45 °C3.1 Reagents: Sodium Cyanide; 45 °C -> 80 °C; 2.5 H,80 °C
  标题:Substituted Carbamothioic Amine-1-Carbothioic Thioanhydrides As Novel Trichomonicidal Fungicides: Design,Synthesis,And Biologymethod For Preparing Tetramethylthiuram Disulfide
  作者:Mandalapu,Dhanaraju; Et Al
  参考文献:European Journal Of Medicinal Chemistry 日期:2018 卷标:143 页码:632-645]
  
  2801-10-7 = 97-74-5
  反应条件:1.1 Solvents: Benzene2.1 Reagents: Potassium Cyanide Solvents: Ethanol
  标题:On Chalcogenolates. 185. Bis(N,N-Dimethylthiocarbamoyl)Sulfanes
  作者:Knoth,W.; Et Al
  参考文献:Zeitschrift Fuer Anorganische Und Allgemeine Chemie 日期:1988 卷标:556 页码:141-5]
  
  97-91-6 = 97-74-5
  反应条件:1.1 Solvents: Benzene2.1 Reagents: Potassium Cyanide Solvents: Ethanol
  标题:On Chalcogenolates. 185. Bis(N,N-Dimethylthiocarbamoyl)Sulfanes
  作者:Knoth,W.; Et Al
  参考文献:Zeitschrift Fuer Anorganische Und Allgemeine Chemie 日期:1988 卷标:556 页码:141-5]
  
  = 97-74-5 + 597-82-0
  反应条件:1.1 Solvents: Acetonitrile; 10 H,80 °C1.1 Solvents: Acetonitrile; 10 H,80 °C1.1 Solvents: Acetonitrile; 1 Min,80 °C; 10 H,80 °C
  标题:One-Step Simultaneous Synthesis Of An Industrially Important Rubber Accelerator And A Lubricant Additive By Disulfide Bond Contractionone-Step Simultaneous Synthesis Of An Industrially Important Rubber Accelerator And A Lubricant Additive By Disulfide Bond Contractiongreen Method For The Simultaneous Production Of Rubber Accelerator Tetramethylthiuram Monosulfide And Lubricating Oil Additive Triphenyl Thiophosphate
  作者:Xu,Hao-Xing; Et Al Xu,Hao-Xing; Et Al
  参考文献:Synlett 日期:2023 卷标:34(1) 页码:57-62]
  
  79-45-8 = 97-74-5 + 540-72-7
  反应条件:1.1 Reagents: Hydrogen Peroxide Solvents: Water; 45 °C; 3 H,45 °C2.1 Reagents: Sodium Nitrite; Rt -> 80 °C; 2.5 H,80 °C
  标题:Preparation Of Rubber Accelerator Tetramethyl Thiuram Monosulfide And Its Spectral Analysis
  作者:Wang,Zhen-Xiang; Et Al
  参考文献:Guangpuxue Yu Guangpu Fenxi 日期:2015 卷标:35(7) 页码:1875-1878]
  
  = 97-74-5 + 540-72-7
  反应条件:1.1 Reagents: Hydrogen Peroxide,Polyethylene Glycol Mono(4-Tert-Octylphenyl) Ether Solvents: Water; 0.1 Mpa,40 - 45 °C; 2 H,45 °C2.1 Reagents: Hydrogen Peroxide Solvents: Water; 45 °C; 3 H,45 °C3.1 Reagents: Sodium Nitrite; Rt -> 80 °C; 2.5 H,80 °C
  标题:Preparation Of Rubber Accelerator Tetramethyl Thiuram Monosulfide And Its Spectral Analysis
  作者:Wang,Zhen-Xiang; Et Al
  参考文献:Guangpuxue Yu Guangpu Fenxi 日期:2015 卷标:35(7) 页码:1875-1878

海关参考信息

• 2921199090-其他无环单胺
  2930909099-其他有机硫化合物
• 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
• 详情请参考：📖 海关编码查询和海关进出口税则

专利信息

其他信息查阅

• ➥ 象形图和危险代码
• ➥ 防范代码详解
• ➥ 危险代码说明
• ➥ Globally Harmonized System
• ➥ REACH监管