CAS: 93804-29-6; Methoxydimethyl(Octyl)Silane

该化合物是一种有机硅化合物,其特征为辛基磺酰混合物和甲基二甲基硅烷功能,该硅烷主要用作表面修饰剂或合金剂,具有疏水特性,有机材料和无机材料之间的粘合性得到改善,其长的烷基链(辛基)可增进与非极基质的兼容性,而甲基氧混合物组则有利于水解和与水氧化表面(如玻璃,金属或矿物)的结合.该化合物因其热稳定性和对环境退化的耐受性而受到重视,使其适合涂层,粘合剂和复合应用.其与表面的反作用可以进行耐久的修改,提高水的抗力和工程材料的阻力.

结构式图片

相似化合物

71808-65-6 18642-94-9 85712-15-8

物理性质

MSDS等安全信息

欧盟法规

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上下游产品

methanol allyldimethyl°Ctylsilane dimethyl(1-°Ctyl)(2-pyridyl)silane trimethyl-°Ctyl-silane°Ctanol °Ctyldimethylhydrosilane

合成工艺路线路线简述

  • 合成目标产物 Dimethylmethoxy-N-Octylsilane 主要起始原料 Trimethyl(Octyl)Silane
  • 81272-80-2 = 93804-29-6
    反应条件:1.1 Reagents: Methanol,Tetraethylammonium P-Toluenesulfonate Solvents: Methanol
    标题:Electrochemical Oxidation Of Organosilicon Compounds. I. Oxidative Cleavage Of Carbon-Silicon Bond In Allylsilanes And Benzylsilanes
    作者:Yoshida,Junichi; Murata,Toshiki; Isoe,Sachihiko
    参考文献:Tetrahedron Letters 日期:1986 卷标:27(29) 页码:3373-6]

    93804-29-6 = 93804-29-6
    反应条件:1.1 Reagents: Magnetite (Fe3O4); 40 °C
    标题:New Nanostructures Derived From Magnetic Polymer Hybrids And Functional Silanes
    作者:Somoghi,R.; Ianchis,R.; Ghiurea,M.; Purcar,V.; Donescu,D.
    参考文献:Journal Of Optoelectronics And Advanced Materials 日期:2013 卷标:15(5-6) 页码:583-588
📜三甲基(辛基)硅烷置于(1,5-Cyclooctadiene)(Methoxy)Iridium(I) Dimer,3,4,7,8-四甲基-1,10-菲罗啉,Potassium Methanolate,Potassium Tert-Butylate体系中,用 甲基叔丁基醚,二甲基亚砜 作为反应溶剂,化学反应 48.0H,反应生成 甲氧基(二甲基)辛基硅烷
参考文献:通过化学选择性的c(sp 3)-h在硅上甲基上的硼氢化反应,将三甲基甲硅烷基用作羟基的合成当量
标题:通过化学选择性的c(sp 3)-h在硅上甲基上的硼氢化反应,将三甲基甲硅烷基用作羟基的合成当量
摘要:基于铱催化的硅上甲基的化学选择性c(sp 3)-H硼化,可将三甲基甲硅烷基烷烃转化为相应的醇.用H2O 2处理由c(sp 3)-h硼化形成的(硼甲基)甲硅烷基然后,在tamoo条件下,将所得的(羟甲基)甲硅烷基通过布鲁克重排转化为羟基,然后将所得的甲氧基甲硅烷基氧化.还建立了通过swern氧化通过由(羟甲基)甲硅烷基形成的甲硅烷基甲硅烷基进行的替代途径.该方法适用于取代的三甲基甲硅烷基环烷烃和1,1-二甲基-1-硅环戊烷,以转化成相应的立体定义的环烷基醇和1,4-丁二醇.
DOI:10.1021/acs.Joc.6B02917

海关参考信息

专利信息


专利号:US-2009311556-A1
优先权日:2006-04-17
标 题 :SYNTHESIS, FUNCTIONALIZATION AND ASSEMBLY OF MONODISPERSE HIGH-COERCIVITY SILICA-CAPPED FePt NANOMAGNETS OF TUNABLE SIZE, COMPOSITION AND THERMAL STABILITY FROM IMCROEMULSIONS
发明人：GANAPATHIRAMAN RAMANATH; YAN QINGYU; PURKAYASTHA ARUP
权利人:RENSSELAER POLYTECH INST
摘要:A nanoparticle includes a metal core and an outer shell. The metal core includes a magnetic alloy of platinum and at least one additional metal. The outer shell is selected from the group consisting of silica, titania, metal nitride, and metal sulfide.

专利号:AU-2006290509-A2
优先权日:2005-09-15
标题 :Method for attachment of silicon-containing compounds to a surface and for the synthesis of hypervalent silicon-compounds

专利号:AU-2006290509-A1
优先权日:2005-09-15
标题:Method for attachment of silicon-containing compounds to a surface and for the synthesis of hypervalent silicon-compounds

专利号:AU-2006290509-B2
优先权日:2005-09-15
标 题 :Method for attachment of silicon-containing compounds to a surface and for the synthesis of hypervalent silicon-compounds

专利号:CA-2622087-C
优先权日:2005-09-15
标 题 :Method for attachment of silicon-containing compounds to a surface and for the synthesis of hypervalent silicon-compounds

专利号:CA-2622087-A1
优先权日:2005-09-15
标题:Method for attachment of silicon-containing compounds to a surface and for the synthesis of hypervalent silicon-compounds

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[参考文献]: Alejandra Nieto, Et Al. Surface Engineering Of Porous Silicon Microparticles For Intravitreal Sustained Delivery Of Rapamycin. Invest Ophthalmol Vis Sci. 2015 Jan 22;56(2):1070-80.

合成参考文献


参考文献:10.1007/bf02290374
摘要:Eppert G, Liebscher G, Schinke I. Investigations into the chromatographic behaviour of silica gels produced from ester silicates. Chromatographia. 1989 Jul;28(1-2):9–14. doi: 10.1007/bf02290374.
参考文献:10.1007/s11051-012-1233-6
摘要:Ianchis R, Corobea MC, Donescu D, Rosca ID, Cinteza LO, Nistor LC, Vasile E, Marin A, Preda S. Advanced functionalization of organoclay nanoparticles by silylation and their polystyrene nanocomposites obtained by miniemulsion polymerization. Journal of Nanoparticle Research. 2012 Oct 21;14(11):1233. doi: 10.1007/s11051-012-1233-6.
参考文献:10.1007/s40089-022-00388-8
摘要:Deshmukh RK, Hakim L, Akhila K, Ramakanth D, Gaikwad KK. Nano clays and its composites for food packaging applications. International Nano Letters. 2022 Nov 23;():1–23. doi: 10.1007/s40089-022-00388-8.
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