CAS: 5694-00-8; Glycidamide

相似化合物

111058-32-3 82044-23-3 60456-23-7

上下游产品

CAS号107-13-1 丙烯腈 | CAS号79-06-1 丙烯酰胺 | CAS号615-34-9 2,3-二羟基丙酸甲酯 | CAS号4538-51-6 2-Cyanoethylene... | CAS号1079950-08-5 N-乙酰基-S-(3-氨基-2... | CAS号1079950-10-9 N-Acetyl-S-[2-a...

📜2,3-环氧丙腈置于sodium Hydroxide体系中,用 水 作为反应溶剂,化学反应 10.0H,反应生成 环氧丙酰胺
参考文献:Chemie Vonα-氨基三烯.13. Mitteilung.黚死教化冯-2-氧代乙基-Phosphaten("glycoladehyd-Phosphaten")aus外消旋-Oxirancarbonitril Und Anorganischem Phosphat Und黚(formale)konstitutionellezusammenhängezwischen-2-氧代乙基-Phosphaten Und寡(hexo-Und Pentopyranosyl)nucleotid-Rückgraten †
标题:Chemie Vonα-氨基三烯.13. Mitteilung.黚死教化冯-2-氧代乙基-Phosphaten("glycoladehyd-Phosphaten")aus外消旋-Oxirancarbonitril Und Anorganischem Phosphat Und黚(formale)konstitutionellezusammenhängezwischen-2-氧代乙基-Phosphaten Und寡(hexo-Und Pentopyranosyl)nucleotid-Rückgraten †
摘要:α-氨基腈的化学.由外消旋-环氧乙烷甲腈形成2-氧代乙基磷酸酯("乙二醇醛磷酸酯")以及2-氧代乙基磷酸酯与寡聚(己基和戊基吡喃糖基)核苷酸骨架之间的(正式)构型关系
DOI:10.1002/hlca.19940770815

专利信息

专利号:WO-03087075-A1
优先权日:2002-04-04
标题:Asymmetric synthesis of glycidic amides
发明人：AGGARWAL VARINDER K
权利人:UNIV BRISTOL; AGGARWAL VARINDER K
摘要:Enantiomerically enriched trans-2,3-epoxyamides of the formula (I) in which R1 is a 1-18C aliphatic hydrocarbyl optionally substituted by one or more substituent groups selected from halo, nitro, phenyl and -ORW, where RW is H, 1-6C alkyl, benzyl or phenyl, or is aryl containing from 6-12 ring carbon atoms which is optionally substituted by one or more substituent groups selected from 1-6C alkyl, halo, nitro, phenyl, benzyl and -ORW, where RW is as defined above, or is a monocyclic or fused bicyclic heterocyclic group containing at least one heteroatom selected from N, O and S which group is optionally substituted by one or more substituent groups selected from 1-6C alkyl, halo, nitro, phenyl, benzyl and -ORW, where RW is as defined above; R2 and R3 are the same or different group selected from H, 1-6C alkyl optionally substituted with one or more substituent groups selected from halo, nitro, phenyl and -ORW, where RW is as defined above, 2-6C alkenyl optionally substituted with one or more substituent groups selected from halo, nitro, phenyl and -ORW, where RW is as defined above, phenyl optionally substituted by one or more substituent groups selected from 1-6C alkyl, halo, nitro, phenyl, benzyl and -ORW, where RW is as defined above, and monocyclic heterocyclic groups containing one or more heteroatoms selected from O, S and N, optionally substituted with one or more substituent groups selected from 1-6C alkyl, halo, nitro, phenyl, benzyl and -ORW, where RW is as defined above or R2 or R3, or R2 or R3, together with the nitrogen atom to which they are attached, form a heterocyclic ring, are made by a method comprising reacting a sulfonium salt of the formula (II) wherein R2 and R3 are as defined above, R4 is a group selected from 1-12C alkyl, 6-12C aryl and 7-13C aralkyl and -SiMe3, R5 is 1-4C alkyl group and X- is a counterion, with an aldehyde of the formula R1CHO, where R1 is as defined above, in a solvent in the presence of a base. The use of this method gives excellent yields of the trans epoxides. Sulfonium salts of the formula (II), as defined above, are also disclosed.

专利号:US-5219957-A
优先权日:1990-06-14
标题 :Water-dilutable vehicles based on epoxide resins, methods for their synthesis and their use as aqueous coating materials as well as aqueous coating materials
发明人：PATZSCHKE HANS-PETER; BLUM JOACHIM; FRIEDERICHS GERHARD; BOGDAN WOLFGANG
权利人:HERBERTS & CO GMBH
摘要:Vehicles, which are water dilutable after neutralization with bases, have an acid number of 5 to 60 and are obtainable by polymerization or copolymerization of 10 to 90 parts by weight of one or several acidic, phosphoric acid-functional unsaturated monomers, which are polymerizable by a free radical mechanism and can be present in admixture with one or several ethylenically unsaturated monomers, which are also polymerizable by a free radical mechanism, with addition of a free radical initiator, in the presence of 90 to 10 parts by weight of one or several epoxide resins or modified epoxide resins, in one or several solvents. Methods of synthesizing them, aqueous coating materials containing them and their use.

专利号:AU-2003222958-A1
优先权日:2002-04-04
标题:Asymmetric synthesis of glycidic amides

专利号:GB-0207770-D0
优先权日:2002-04-04
标题:Asymmetric synthesis of glycidic amides