3,5-二甲基溴苄置于乙醚,Magnesium体系中,化学反应生成 3,5-二甲基苯乙酸 参考文献:Wahl; Livovschi,Bulletin De La Societe Chimique De France,1938,Vol. <5>5,P. 653,655,664 标题:Wahl; Livovschi,Bulletin De La Societe Chimique De France,1938,Vol. <5>5,P. 653,655,664
专利号:US-8114993-B2 优先权日:2007-02-06 标题:Use of aryl chlorides in palladium-catalyzed C-H bond functionalization 发明人:DAUGULIS OLAFS; CHIONG HENDRICH 权利人:DAUGULIS OLAFS; CHIONG HENDRICH; UNIV HOUSTON SYSTEM 摘要:A one-step method for efficiently converting carbon-hydrogen bonds into carbon-carbon bonds using chloroarenes and palladium catalysts is disclosed. This method allows faster introduction of complex molecular entities, a process that would otherwise require many more steps. This invention is particularly relevant for the organic synthesis of complex molecules such as, but not limited to, pharmacophores.
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专利号:US-2020149034-A1 优先权日:2017-03-17 标题:Methods and Compositions for Synthesis of Encoded Libraries
专利号:DE-102012224021-A1 优先权日:2012-05-09 标 题 :A process for the synthesis of phenylacetic acid by carbonylation of toluene
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