CAS: 4206-75-1; Chloro(Phenyl)Silicon

该化合物是有机硅化合物,其特点是存在一个附于苯环的氯硅集团,该化合物一般表现出明显的黄色液体形式,由于存在硅-氯的结合物,可以进行水解,从而形成硅醇组;叶丝绸运动提高了该化合物在各种化学反应中的效用,特别是在硅氧和其他含硅材料的合成方面.此外,(Crlorosylyl)苯可以作为聚合物化学中的联结剂,并用于地表改造过程,其芳香性质有助于其稳定性和有机合成的潜在应用.然而,处理该化合物需要谨慎小心,因为它具有再活性和潜在毒性,需要在实验室和工业环境中采取适当的安全措施.

结构式图片

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

CAS号694-53-1 苯硅烷 | CAS号98-13-5 苯基三氯硅烷 | CAS号775-12-2 二苯基硅烷 | CAS号17962-59-3 phenyl(phenylsi... | CAS号26799-07-5 Bis(phenylsilyl... | CAS号121232-83-5 Tris(phenylsily... | CAS号27484-20-4 phenyl(phenylsi... | CAS号694-53-1 苯硅烷 | CAS号775-12-2 二苯基硅烷 | CAS号50518-29-1 phenyl-bis(phen... | CAS号76-86-8 三苯基氯硅烷 | CAS号80-10-4 二苯基二氯硅烷 | CAS号17897-66-4 decyl(phenyl)silane

合成工艺路线路线简述

  • 合成目标产物 Chlorophenylsilane 97 主要起始原料 Phenyltrichlorosilane
  • 16523-54-9 + 694-53-1 = 4206-75-1 + 829-84-5
    反应条件:1.1 Catalysts: 9-Borabicyclo[3.3.1]Nonane Solvents: Acetonitrile,1,2-Difluorobenzene; 8 H,60 °C
    标题:9-Bbn And Chloride Catalyzed Reduction Of Chlorophosphines To Phosphines And Diphosphines
    作者:Elser,Iris; Et Al
    参考文献:Chemical Communications (Cambridge 日期:2022 卷标:58(11) 页码:1740-1743
📜苯基三氯硅烷置于盐酸,Sodium Hydride,Lithium Chloride体系中,用 乙醚,二乙二醇二甲醚 作为反应溶剂,化学反应 49.25H,反应生成 氯苯基硅烷
参考文献: Synthesis Of Organo Chlorosilanes From Organosilanes[fr] Synthèse D'Organo-Chlorosilanes à Partir D'Organosilanes
标题: Synthesis Of Organo Chlorosilanes From Organosilanes[fr] Synthèse D'Organo-Chlorosilanes à Partir D'Organosilanes

海关参考信息

专利信息


专利号:US-8637695-B2
优先权日:2011-12-30
标 题:Synthesis of organohalosilane monomers from conventionally uncleavable Direct Process Residue
发明人:LEWIS KENRICK MARTIN; NEELY JOHN DAVID
权利人:LEWIS KENRICK MARTIN; NEELY JOHN DAVID; MOMENTIVE PERFORMANCE MAT INC
摘要:Disclosed herein is a catalytic process for the synthesis of organohalosilane monomers from tetraorganodihalodisilanes and other compounds that are not cleaved during the conventional hydrochlorination of Direct Process Residue. The process is characterized by the use of a catalyst containing (1) one or more heterocyclic amines and/or one or more heterocyclic ammonium halides, and (2) one or more quaternary Group 15 onium compounds.

专利号:US-2023192731-A1
优先权日:2020-05-29
标 题 :Process for the stepwise synthesis of silahydrocarbons
发明人:AUNER NORBERT; STURM ALEXANDER G; SANTOWSKI TOBIAS; FELDER THORSTEN
权利人:MOMENTIVE PERFORMANCE MAT INC
摘要:The invention relates to a process for the stepwise synthesis of silahydrocarbons bearing up to four different organyl substituents at the silicon atom, wherein the process includes at least one step a) of producing a bifunctional hydridochlorosilane by a redistribution reaction, selective chlorination of hydridosilanes with an ether/HCl reagent, or by selective chlorination of hydridosilanes with SiCl 4 , at least one step b) of submitting a bifunctional hydridochloromonosilane to a hydrosilylation reaction, at least one step c) of hydrogenation of a chloromonosilane, and a step d) in which a silahydrocarbon compound is obtained in a hydrosilylation reaction.

专利号:US-2025197431-A1
优先权日:2023-12-15
标 题:Methods and systems for forming a layer comprising silicon and composition and synthesis of silicon precursor
发明人:ROMERO PATRICIO EDUARDO; VERVUURT RENÉ HENRICUS JOZEF; DEZELAH CHARLES; PORE VILJAMI J
权利人:ASM IP HOLDING BV
摘要:Disclosed are methods and systems for forming a silicon-containing layer on a substrate. Further disclosed are composition and synthesis of silicon-containing precursor. The methods for forming a silicon-containing layer comprise executing a plurality of deposition cycles. A deposition cycle comprises a first precursor pulse that comprises exposing the substrate to a first precursor. The first precursor comprises a molecule comprising a P—Si bond. A deposition cycle further comprises a plasma pulse that comprises exposing the substrate to a plasma treatment. The plasma treatment comprises generating a plasma.

专利号:US-9249165-B2
优先权日:2013-08-30
标题 :Slurry phase direct synthesis of organohalosilanes from cyclone fines
发明人:LEWIS KENRICK MARTIN; ZHU YANJUN; MEREIGH ABELLARD T; RAZZANO JOHN; NEELY JOHN DAVID
权利人:MOMENTIVE PERFORMANCE MAT INC
摘要:The present invention is directed to a process for the synthesis of organohalosilane monomers, comprising the steps of (1) forming a slurry of cyclone fines, ultra fines and/or spent contact mass in a thermally stable solvent and reacting the agitated slurry with an organohalide of the formula R 1 X in the presence of an additive for a time and at a temperature sufficient to produce organohalosilane monomers having the formulae R 1 SiHX 2 , R 1 2 SiHX, R 1 3 SiX, R 1 SiX 3 , and R 1 2 SiX 2 ; wherein R 1 is a saturated or unsaturated aromatic group, a saturated or unsaturated aliphatic group, alkaryl group, or cycloaliphatic hydrocarbyl group, and X is a halogen; and (2) recovering said organohalosilane monomers.

专利号:US-7153991-B2
优先权日:2000-12-01
标 题:Rochow-Müller direct synthesis using nanosized copper catalyst precursors
发明人:LEWIS KENRICK M; RITSCHER JAMES S
权利人:GEN ELECTRIC
摘要:A Direct Synthesis of making organohalosilanes with greater selectivity to the dialkyldihalosilane is disclosed herein. By using nanosized copper catalyst precursors, and preferably nanosized promoters as well, D/T values of greater than 10, and preferably greater than 15, are obtainable with silicon conversions in excess of 80 wt. %. Shorter induction times are realized using the nanosized copper catalysts in the Direct Synthesis. The nanosized copper catalyst precursors most preferably have an average particle size of less than 100 nanometers.

专利号:US-8697901-B2
优先权日:2011-12-30
标题 :Synthesis of organohalosilane monomers via enhanced cleavage of direct process residue
发明人:LEWIS KENRICK MARTIN; NEELY JOHN DAVID
权利人:LEWIS KENRICK MARTIN; NEELY JOHN DAVID; MOMENTIVE PERFORMANCE MAT INC
摘要:Discloses herein is a catalytic process for producing organohalosilane monomers from a high-boiling residue resulting from the Direct Reaction of an organohalide with silicon. The high-boiling residue contains more conventionally cleavable compounds than conventionally uncleavable compounds. The process includes heating the residue in the presence of a catalyst comprising (1) one or more heterocyclic amines and/or one or more heterocyclic ammonium halides, and (2) one or more quaternary Group 15 onium compounds.

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📌 第三方产品分析报告

✅ COA系统入驻 | 共享模式

主要参考文献

参考标题:Lewis Base Catalyzed Selective Chlorination Of Monosilanes
作者:Alexander G. Sturm,Julia I. Schweizer,Lioba Meyer,Tobias Santowski,Norbert Auner,Max C. Holthausen |发布日期:2018.12.3
摘要:A Preparatively Facile, Highly Selective Synthesis Of Bifunctional Monosilanes R2Sihcl, Rsihcl2 And Rsih2Cl Is Reported. By Chlorination Of R2Sih2 And Rsih3 With Concentrated Hcl/ether Solutions, The Stepwise Introduction Of Si−cl Bonds Is Readily Controlled By Temperature And Reaction Time For A Broad Range Of Substrates. In A Combined Experimental And Computational Study, We Establish A New Mode

合成参考文献


摘要:Nishimoto, Y.; Yasuda, M.; Baba, A., Science of Synthesis Knowledge Updates, (2017) 1, 203.
摘要:Hlina, J. A., Science of Synthesis Knowledge Updates, (2021) 1, 82.
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