CAS: 2051-24-3; Decachlorobiphenyl

上下游产品

biphenyl 9-fluorenone 2-nitrobiphenyl 2,3,5,6,2',3',5',6'-°Ctachloro-benzidinebiphenyl 1,1,2,2-tetrachloroethylene hexachlorobenzene °Ctachlorostyrene

📜五氯碘苯置于铜体系中,用 N,N-二甲基甲酰胺 用作溶剂,以81%的收率获得十氯联苯
参考文献:多卤代芳族化合物.第43部分:多氯芳族化合物与铜的分子间和分子内反应
标题:多卤代芳族化合物.第43部分:多氯芳族化合物与铜的分子间和分子内反应
摘要:聚氯碘代芳烃与铜在二甲基甲酰胺中的反应产生了非常好的联芳基收率.4Bromotetrachloropyridine产生卤素交换和还原以及偶合的产物.五氯吡啶仅给出四氯吡啶.提供了针对自由基或吡啶炔中间体的证据,并且假定反应通过吡啶基铜化合物进行,尽管不排除电子转移机理.与铜反应时,一些4-(邻-卤代苯氧基)-和4-(邻-卤代硫代苯氧基)四卤代吡啶吡啶产生环化,还原和卤素转移的产物.最初,铜至少部分与吡啶基反应,而不是与邻位反应.-卤代芳基.结果再次与涉及吡啶基铜中间体的反应途径一致.
Doi:10.1039/p19800001682

专利信息

专利号:US-10870917-B2
优先权日:2016-07-08
标 题:Functionalized foams
发明人：DARLING SETH B; ELAM JEFFREY W; MANE ANIL U; SNYDER SETH W
权利人:UCHICAGO ARGONNE LLC
摘要:A method of fabricating an foam includes providing a foam comprising a base material. The base material is coated with an inorganic material using at least one of an atomic layer deposition (ALD), a molecular layer deposition (MLD), or sequential infiltration synthesis (SIS) process. The SIS process includes at least one cycle of exposing the foam to a first metal precursor for a first predetermined time and a first partial pressure. The first metal precursor infiltrates at least a portion of the base material and binds with the base material. The foam is exposed to a second co-reactant precursor for a second predetermined time and a second partial pressure. The second co-reactant precursor reacts with the first metal precursor, thereby forming the inorganic material on the base material. The inorganic material infiltrating at least the portion of the base material. The inorganic material is functionalized with a material.