CAS: 144012-09-9; 2-Bromo-3-Decylthiophene

相似化合物

139100-06-4 145543-83-5 69249-61-2

上下游产品

3-decylthiophene n-decyl magnesium bromide 1-bromo dodecane 3,3'''-didecyl-2,2':5',2'':5'',2'''-quaterthiophene 3,3''-didecyl-2,2':5',2''-terthiophene 5,5'''-dibromo-3,3'''-didecyl-2,2':5',2'':5'',2'''-quaterthiophene 5,5''-dibromo-3,3''-didecyl-2,2':5',2''-terthiophene

癸基溴置于n-溴代丁二酰亚胺(Nbs),Magnesium体系中,用 四氢呋喃,N,N-二甲基甲酰胺 用作溶剂,化学反应生成2-溴-3-癸基噻吩
参考文献:Using Bis(Pinacolato)Diboron To Improve The Quality Of Regioregular Conjugated Co-Polymers
标题:Using Bis(Pinacolato)Diboron To Improve The Quality Of Regioregular Conjugated Co-Polymers
摘要:我们展示了通过suzuki同聚合反应,利用双(频哪醇基)二硼直接聚合对称,双溴,噻吩基单体,以较少步骤形成共聚物的方法.通过采用两种方法(新方法和常用的stille共聚法)制备四种噻吩基共聚物,并将这种方法与stille共聚法进行对比.通过maldi-Tof质谱分析,我们证明这种方法能生成高质量,均一的聚合物,其端基分布狭窄.通过改变单体的电负性,我们初步实现了对这些端基的控制,按照电负性增加的顺序,分别形成双氢端基,单氢单溴端基或双溴端基的聚合物.
Doi:10.1039/c0Jm02359K

专利信息

专利号:US-10832800-B2
优先权日:2017-01-03
标 题 :Synthetic pathway engine
发明人：KOBILKA BRANDON M; KUCZYNSKI JOSEPH; WERTZ JASON T
权利人:IBM
摘要:A process includes receiving information associated with a target molecule to be synthesized via a synthetic pathway engine user interface. The process also includes determining, using a synthetic pathway engine, synthetic pathway data for synthesis of the target molecule. In some cases, the process further includes generating a synthetic pathway report user interface that includes information associated with the synthetic pathway data. In other cases, the process further includes initiating automated synthesis of the target molecule using automated chemical synthesis equipment according to the synthetic pathway data.