CAS: 62871-09-4; 10-Bromodec-1-Ene

相似化合物

7766-50-9 267235-31-4 99828-63-4

上下游产品

9-Decen-1-ol dec-9-en-1-yl methanesulfonate 1,7-dibromoheptane ethyl 4-(n-dec-9-en-1-yloxy)benzoate 5-Dec-9-enyloxy-isophthalic acid diethyl ester 4-(dec-9-enyloxy)phenol N-ethyl-4-methyl-benzenesulfonamide2-dec-9-enyl-N-ethyl-4-methyl-benzenesulfonamide

Dec-9-En-1-Yl Methanesulfonate置于lithium Bromide体系中,用 N-甲基吡咯烷酮 作为反应溶剂,化学反应生成 10-溴-1-癸烯
参考文献:评估ω-不饱和酸在卤代内酯化过程中的内外比.
标题:评估ω-不饱和酸在卤代内酯化过程中的内外比.
摘要:考察了2-(ω-烯基)苯甲酸与双(可力丁)碘和双(可力丁)溴六氟磷酸盐的反应.除了仅获得外泌内酯的2-丁-3-烯基苯甲酸外,对于其他酸,总是得到外泌内酯的混合物.内酯的比例对于11个碳原子的酸链长度(形成12元环内酯)和高于14个碳原子的酸链长度都很重要.在分子计算的基础上,通过电子和空间效应之间的竞争解释了内酯的形成.后者是通过跨环相互作用(对于酸链长度为8-11)和/或由链采用的构象(对于酸链长度>或= 14)形成的,这不利于外泌内酯的形成.
DOI:10.1021/jo0017234

专利信息

专利号:EP-0444742-A1
优先权日:1990-02-26
标题 :Ester/alcohol synthesis
发明人：KRAMER PETRUS ANTHONIUS; WULLINK-SCHELVIS ANETTE MARIA
权利人:SHELL INT RESEARCH
摘要:A process for preparing an ester of the formula n n R¹-O-CO-R² n n wherein R¹ is an alkenyl group and R² is an alkyl, alkenyl or alkynyl group, which comprises reacting the corresponding halide of formula R¹Hal with the corresponding alkali metal acylate of the formula MOCOR², in the presence of an inert aprotic solvent and a phase-transfer catalyst, optionally followed by hydrolysis of the ester into the corresponding alcohol.

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优先权日:2011-09-14
标 题:Synthesis of 10-α / β-D-arabinofuranosyl-undecene as a potential antimycobacterial agent

专利号:JP-2014526502-A
优先权日:2011-09-14
标题:Synthesis of 10-α / β-D-arabinofuranosyl-undecene as a potential antimycobacterial agent

专利号:WO-2013038430-A1
优先权日:2011-09-14
标题 :SYNTHESIS OF 10-α/β-D-ARABINOFURANOSYL-UNDECENES AS POTENTIAL ANTI-MYCOBACTERIAL AGENTS

专利号:JP-H04211633-A
优先权日:1990-02-26
标 题:Synthesis of esters/alcohols

专利号:CN-102942644-B
优先权日:2012-12-11
标 题 :A kind of synthesis method of C2 bridged metallocene Zr-rare earth binuclear catalyst