CAS: 610-49-1; 1-Anthramine

该化合物是分子式C14H11N 的多环芳烃,其特征为1点方位的炭疽脊柱,以氨基组替代;该化合物主要用作染料,色素和荧光材料合成的中间体,因其相交芳香结构,其硬性平面几何和富电性使其在有机电子和光化学应用中具有价值. 1-氨基甲色素在标准条件下表现出稳定性,并显示电子替代和混合反应中的可预见再活动.在处理过程中,由于对光和氧化的潜在敏感度,应谨慎行事.其纯度和一贯性对于研究和工业过程中的再生效果至关重要.

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779-03-3 79015-49-9 46710-42-3

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合成工艺路线路线简述

    📜1-蒽酚置于氨,Calcium Chloride体系中,化学反应生成 1-氨基蒽
    参考文献:Pisovschi,Chemische Berichte,1908,Vol. 41,P. 1435
    标题:Pisovschi,Chemische Berichte,1908,Vol. 41,P. 1435

    海关参考信息

    专利信息


    专利号:US-5965746-A
    优先权日:1997-06-02
    标题:Efficient method for the synthesis of N-cyclic maleamic acids and N-cyclic maleimides
    发明人:FUJITA SATOSHI; REDDY PAIDI YELLA; TORU TAKESHI
    权利人:AISIN SEIKI
    摘要:Provided are methods for the synthesis of N-cyclic maleamic acids and N-cyclic maleimide derivatives, as well as N-cyclic maleamic acids and N-cyclic maleimides synthesized thereby. The method for synthesis of an N-cyclic maleamic acid involves reacting an amino group-containing N-cyclic compound with maleic anhydride in acetic acid to obtain an N-cyclic maleamic acid. An N-cyclic maleimide can be formed by adding hexamethyldisilazane to an N-cyclic maleamic acid prepared according to the above-described method, thereby cyclizing a maleamic acid site of the N-cyclic maleamic acid. The described methods allow for the products to be obtained at high yields.

    专利号:US-10973847-B2
    优先权日:2017-06-30
    标题 :Core-to-surface polymerization for the synthesis of star polymers and uses thereof
    发明人:JOHNSON JEREMIAH A; GOLDER MATTHEW R
    权利人:MASSACHUSETTS INST TECHNOLOGY
    摘要:Disclosed are methods, compositions, reagents, systems, and kits to prepare star polymers, as well as compositions and uses thereof. Various embodiments show that synthesis of these polymers contain low metal concentration to provide polymers for diverse biomedical applications including in vivo applications.

    专利号:WO-9410327-A1
    优先权日:1992-10-28
    标 题 :Enzymatic synthesis of polyaniline
    发明人:ZEMEL HAYA; QUINN JOHN F
    权利人:ALLIED SIGNAL INC
    摘要:This invention relates to a process for the enzymatic synthesis of electrically conductive substituted and unsubstituted polyanilines. Aniline monomer(s), an oxidizing agent, which comprises an enzyme and an electron acceptor, and an acidifying agent are reacted together to form polyanilines.

    专利号:US-5420237-A
    优先权日:1991-08-29
    标 题:Enzymatic synthesis of polyaniline
    发明人:ZEMEL HAYA; QUINN JOHN F
    权利人:ALLIED SIGNAL INC
    摘要:This invention relates to a process for the enzymatic synthesis of electrically conductive substituted and unsubstituted polyanilines. Aniline monomer(s), an oxidizing agent, which comprises an enzyme and an electron acceptor, and an acidifying agent are reacted together to form polyanilines.

    专利号:US-6541653-B2
    优先权日:2001-04-26
    标题 :Synthesis of carbamate through low pressure heterogeneous oxidative carbonylation of amines
    发明人:CHUANG STEVEN S C; CHI YAWU; CHEN BEI; TOOCHINDA PISANU
    摘要:The process disclosed herein satisfies the need in the art for an industrially viable oxidative carbonylation catalytic system, and is capable of producing carbamates at a significantly higher rate than those processes reported in journal and patent literature. This reaction process takes place via a reaction mechanism that does not involve drastic conditions. Specifically, the catalytic system of the present invention employs Group VIII metal catalysts and/or copper-based catalysts with halide promoters to produce carbamates through heterogeneous oxidative carbonylation at atmospheric pressure and relatively non-drastic temperatures in a gas-solid carbonylation process.

    专利号:US-2002183541-A1
    优先权日:2001-04-26
    标题:Synthesis of carbamate through low pressure heterogeneous oxidative carbonylation of amines

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    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献

    参考标题:Copper(Ii) Mediated Ortho C-H Alkoxylation Of Aromatic Amines Using Organic Peroxides: Efficient Synthesis Of Hindered Ethers
    作者:Souvik Sarkar,Tapan Sahoo,Chiranjit Sen,Subhash Chandra Ghosh
    摘要:Synthesis Of Hindered Alkyl Aryl Ether Derivatives (R-O-Ar) Remains A Huge Challenge And Highly Desirable In Organic And Medicinal Chemistry Because Extensive Substitution On The Ether Bond Prevents The Undesired Metabolic Process And Thus Avoids Rapid Degradation In Vivo. Herein, We Report An Unprecedented Hindered Alkoxylation Of Picolinamide Attached Aromatic Amines Using Economic Copper Salt And

    合成参考文献


    参考文献:10.1016/j.bmc.2008.03.030
    摘要:Zhan J, Gunatilaka AA. Microbial metabolism of 1-aminoanthracene by Beauveria bassiana. Bioorg Med Chem. 2008 May 01;16(9):5085–9. doi: 10.1016/j.bmc.2008.03.030.
    参考文献:10.1007/s00204-017-1938-5
    摘要:Efferth T, Volm M. Multiple resistance to carcinogens and xenobiotics: P-glycoproteins as universal detoxifiers. Arch Toxicol. 2017 Jul;91(7):2515–38. doi: 10.1007/s00204-017-1938-5.
    参考文献:10.1007/s12223-019-00725-z
    摘要:Nguyen PA, Strub C, Lagrée M, Bertrand-Michel J, Schorr-Galindo S, Fontana A. Study of in vitro interaction between Fusarium verticillioides and Streptomyces sp. using metabolomics. Folia Microbiol (Praha). 2020 Apr;65(2):303–14. doi: 10.1007/s12223-019-00725-z.
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