CAS: 527-18-4; 2,3,5,6-Tetramethylbenzene-1,4-Diol

该化合物其结构特征为:一个有四组附于芳香环的四甲基组;该化合物在室内温度下是无色的,可粉黄的,以其抗氧化特性而著称,因此在各种应用中,包括在塑料中作为稳定剂和作为有机合成中的一种减少剂,都有用.该物质在乙醇和丙酮等有机溶剂中具有溶解性,但水溶解性有限.其化学配方为C10H14O2, 其熔点因纯度和具体条件而异.其结构中存在氢氧基组有助于其再活动,使其得以参与各种化学反应,包括氧化和聚合过程.由于其特性,还研究该物质在药物和化妆品中的潜在应用,如乙醇和丙酮等,但水溶解性有限.然而,处理工作应谨慎进行,如许多有机化合物,以确保安全并尽量减少接触.

结构式图片

上下游产品

Duroquinone 4-Hexadecyloxy-2,3,5,6-tetramethyl-phenol 1,4-bis-hexadecyloxy-2,3,5,6-tetramethyl-benzene mercaptoacetic acidButyl-(4-hydroxy-2.3.5.6-tetramethyl-phenyl)-aether 1,4-dibutoxy-2,3,5,6-tetramethyl-benzene 4-Hexadecyloxy-2,3,5,6-tetramethyl-phenol 1,4-bis-hexadecyloxy-2,3,5,6-tetramethyl-benzene

合成工艺路线路线简述

  • 8068-05-1 = 527-18-4 + 831-00-5 + 88-32-4 + 2219-78-5 + 65565-33-5 + 13037-79-1 + 77879-82-4 + 33963-27-8 + 527-35-5 + 3238-38-8 + 89-83-8 + 615-90-7 + 98-29-3 + 2416-94-6 + 13199-54-7 + 7743-14-8 + 92617-73-7 + 520-43-4
    反应条件:1.1 Catalysts: Sodium Hydroxide Solvents: Methanol; 7 H,220 °C
    标题:Thermochemical Lignin Depolymerization And Conversion To Aromatics In Subcritical Methanol: Effects Of Catalytic Conditions
    作者:Singh,Sunit Kumar; Et Al
    参考文献:New Journal Of Chemistry 日期:2016 卷标:40(4) 页码:3677-3685
📜杜醌置于sodium Hydroxide,锌体系中,化学反应生成 四甲基氢醌
参考文献:What Women And Men Should Be,Shouldn'T Be,Are Allowed To Be,And Don'T Have To Be: The Contents Of Prescriptive Gender Stereotypes
标题:What Women And Men Should Be,Shouldn'T Be,Are Allowed To Be,And Don'T Have To Be: The Contents Of Prescriptive Gender Stereotypes
摘要:本文提出了一个四类框架,用于描述规范性性别刻板印象的内容.该框架区分了因为一个人的性别而加强的规定和禁忌,以及因为一个人的性别而放松的规定和禁忌.两项研究考察了这个框架在美国社会(第一项研究)和普林斯顿大学这个高度男性化的环境中(第二项研究)描述规范性性别刻板印象的效用.结果显示了传统性别规定在两个环境中的持续存在,但也揭示了每种性别在社会警惕和宽容方面的明显区别.此外,结果表明相对于社会标准,女性被看待得更积极,而男性则相反.我们考虑了这个框架对于研究对性别刻板印象异类和性别歧视反应的影响.
DOI:10.1111/1471-6402.T01-1-00066

海关参考信息

专利信息


专利号:US-4895922-A
优先权日:1988-05-05
标 题 :Low temperature synthesis of polyesteramides
发明人:OGATA NAOYA
权利人:GOODYEAR TIRE & RUBBER
摘要:This invention disclosed a process for the synthesis of polyesteramides. By utilizing the phosphorus containing catalyst systems of the present invention, such polyesteramides can be synthesized at relatively low temperatures. The present invention specifically discloses a process for the synthesis of a polyesteramide which comprises polymerizing at least one diamine, at least one diol, and at least one dicarboxylic acid in the presence of (1) at least one acid acceptor; (2) at least one halogenated organic compound; and (3) at least one phosphorus containing compound selected from the group consisting of (a) triphenylphosphine, (b) triphenylphosphine oxide, (c) triphenylphosphine sulfide, (d) polymeric agents having pendant diphenylphosphine groups, (e) silicon-phosphorus compositions which contain at least one divalent oxygen atom which is bonded directly to a tetravalent silicon atom and a trivalent or pentavalent phosphorus atom; (f) compounds with the structural formula (C 6 H 5 ) 3 P=N-R, wherein R is a hydrogen atom or an alkyl group containing from 1 to 10 carbon atoms; and (g) compounds with the structural formula (C 6 H 5 )PR 1 R 2 wherein R 1 and R 2 can be the same or different, wherein R 1 is selected from the group consisting of alkyl groups containing from 1 to 10 carbon atoms and phenyl groups, and wherein R 2 is an alkyl group containing from 1 to 10 carbon atoms.

专利号:US-2024336586-A1
优先权日:2021-07-29
标题:Methods for synthesis of racemic, scalemic, and chiral alpha-tocotrienol quinone
发明人:GIANNOUSIS PETER; MOLLARD PAUL; GOUDEDRANCHE SEBASTIEN; KARASAWA TOMOYA
权利人:PTC THERAPEUTICS INC
摘要:The application discloses methods useful for the synthesis of racemic, scalemic, and chiral alpha-tocotrienol quinone, including synthetic intermediates and methods for making said synthetic intermediates.

专利号:US-4923839-A
优先权日:1987-02-05
标题:Low temperature synthesis of condensation polymers
发明人:OGATA NAOYA
权利人:GOODYEAR TIRE & RUBBER
摘要:Condensation polymers of high molecular weight, such as polyesters, polyureas, and polyamides, are usually prepared at temperatures of 200° C. or greater. However, by utilizing the catalyst systems of the present invention, condensation polymers can be synthesized at much lower temperatures. The polycondensation catalyst systems of the present invention are particularly useful for synthesizing aliphatic polyesters, such as polyethylene terephthalate, from dicarboxylic acids and aliphatic glycols. The present invention more specifically discloses a process for the synthesis of an aliphatic polyester comprising polymerizing at least one dicarboxylic acid with at least one aliphatic glycol in the presence of (1) at least one phosphorus containing compound which contains at least one trivalent or pentavalent phosphorus atom which is bonded directly to at least one phenyl group, (2) an acid acceptor, and (3) at least one halogenated organic compound. It is preferred to utilize a polymeric agent having bound acid acceptor groups as the acid acceptor in the process of the present invention.

专利号:US-4843053-A
优先权日:1987-02-05
标 题 :Low temperature synthesis of condensation polymers
发明人:OGATA NAOYA
权利人:GOODYEAR TIRE & RUBBER
摘要:Condensation polymers of high molecular weight, such as polyesters, polyureas, and polyamides, are usually prepared at temperatures of 200° C. or greater. However, by utilizing the catalyst systems of the present invention, condensation polymers can be synthesized at much lower temperatures. The polycondensation catalyst systems of the present invention are particularly useful for synthesizing aliphatic polyesters, such as polyethylene terephthalate, from dicarboxylic acids and aliphatic glycols. The present invention more specifically discloses a process for the synthesis of an aliphatic polyester comprising polymerizing at least one dicarboxylic acid with at least one aliphatic glycol in the presence of (1) at least one phosphorus containing compound which contains at least one trivalent or pentavalent phosphorus atom which is bonded directly to at least one phenyl group, (2) an acid acceptor, and (3) at least one halogenated organic compound. It is preferred to utilize a polymeric agent having bound acid acceptor groups as the acid acceptor in the process of the present invention.

专利号:US-4996178-A
优先权日:1987-02-05
标题 :Low temperature synthesis of condensation polymers
发明人:OGATA NAOYA
权利人:GOODYEAR TIRE & RUBBER
摘要:Condensation polymers of high molecular weight, such as polyesters, polyureas, and polyamides, are usually prepared at temperatures of 200° C. or greater. However, by utilizing the catalyst systems of the present invention, condensation polymers can be synthesized at much lower temperatures. The polycondensation catalyst systems of the present invention are particularly useful for synthesizing aliphatic polyesters, such as polyethylene terephthalate, from dicarboxylic acids and aliphatic glycols. The present invention more specifically discloses a process for the synthesis of an aliphatic polyester comprising polymerizing at least one dicarboxylic acid with at least one aliphatic glycol in the presence of (1) at least one phosphorus containing compound which contains at least one trivalent or pentavalent phosphorus atom which is bonded directly to at least one phenyl group, (2) an acid acceptor, and (3) at least one halogenated organic compound. It is preferred to utilize a polymeric agent having bound acid acceptor groups as the acid acceptor in the process of the present invention.

专利号:WO-2025080581-A1
优先权日:2023-10-10
标题 :Parallelized electrochemical polynucleotide synthesis
发明人:BUGGA PRADEEP; LEE HENRY HUNG-YI
权利人:KERN SYSTEMS INC
摘要:The present disclosure provides methods and devices for synthesis of nucleic acid molecules. Devices of the present disclosure may include a substrate, a first electrode, a second electrode, and a plurality of initiator molecules. Methods of the present disclosure may include providing a template-independent DNA polymerase to the device. The template-independent DNA polymerase may be usable to extend the initiator molecules, thereby synthesizing nucleic acid molecules. The first and second electrode may be usable modulate or otherwise control the activity of the template-independent DNA polymerase.

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✅ COA系统入驻 | 共享模式

合成参考文献


摘要:J. H. Baxendale and H. R. Hardy, Trans. Faraday Soc. 49, 1140 (1953).
参考文献:10.1007/bf00744205
摘要:Vambutas V, Beattie DS, Moazzami G. Anion (and cation) requirements of the coupled electron flow in spinach thylakoids. Journal of Bioenergetics and Biomembranes. 1985 Aug;17(4):225–37. doi: 10.1007/bf00744205.
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