CAS: 434-85-5; Bianthrone

该化合物其结构特征为结构,由两个炭蛋单位组成,它看起来是深蓝色或绿色的固体,以其荧光特性著称,在包括染料和颜料在内的各种应用中有用.Bianthrone在正常条件下相对稳定,但在接触光时可以进行光化学反应.它溶于氯仿和二氯甲烷等有机溶剂,但水溶解.该化合物在有机电子中的潜在应用,特别是有机发光二极管(OLEDs)和有机光伏,由于其电子特性,已经进行了研究.此外,二苯hrone在充电运输和发光方面可以表现出有趣的行为,使其在材料科学和有机化学研究中具有兴趣.在处理双硝酮时,应当采取安全防范措施,因为与许多有机化合物有关的潜在健康危害,因此在处理双硝酮时,应该采取安全防范措施.

结构式图片

相似化合物

84-65-1 3029-32-1 1090-13-7

上下游产品

pyridine acetyl chloride bianthronyl isopentyl nitrite10,10'-diphenyl-10H,10'H-[9,9']bytrancenylidene-10,10'-diol H,10'H-[9,9']bianthrylidene-10,10'-diol10,10'-bis-(4-chloro-phenyl)-10H,10'H-[9,9']bianthrylidene-10,10'-diol 9,10-dihydroanthracene 9,10-phenanthrenequinone

合成工艺路线路线简述

  • 合成目标产物 Bianthrone 主要起始原料 Anthrone
  • (文献来源)合成步骤主要原料 Anthrone
📜蒽醌置于硝酸体系中,用 溶剂黄146 作为反应溶剂,化学反应生成 二蒽酮
参考文献:缓冲二恶烷水溶液中邻苯二甲酸乙醇自氧化为蒽醌的动力学
标题:缓冲二恶烷水溶液中邻苯二甲酸乙醇自氧化为蒽醌的动力学
摘要:已经通过测压法在碱性缓冲的二恶烷水溶液中于约35°动力学研究了蒽醇未催化的自氧化为蒽醌.以速率p H 9.50-10.60被表示为:V = ķ [蒽酮] [oh-] P,其中p是氧的分压.观测到的结果提示了一种机制,该机制涉及速率确定分子氧对蒽酚阴离子的攻击以形成蒽氧基自由基,该自由基迅速被氧化以反应生成蒽醌.
DOI:10.1016/s0040-4020(01)98061-5

海关参考信息

专利信息


专利号:US-6214847-B1
优先权日:1997-08-14
标题 :Crystalline 10,10-Bis((2-fluoro-4-pyridinyl)methyl)-9(10H)-Anthracenone and an improved process for preparing the same
发明人:PESTI JAAN A; FORTUNAK JOSEPH M; HUHN GEORGE F; MAURIN MICHAEL; YIN JIANGUO
权利人:DU PONT PHARM CO
摘要:The present invention relates to processes for the synthesis of a crystalline polymorph of 10,10-Bis((2-fluoro-4-pyridinyl)methyl)-9(10H)-Anthracenone in high purity. The product is useful in the synthesis of pharmaceutical compounds for the reduction of cholinergic system dysfunction.

专利号:US-7696386-B2
优先权日:2006-09-29
标 题:Method of producing diol, polydiol, secondary alcohol or diketone compound
发明人:HOSONO HIDEO; BUCHAMMAGARI HARITHA; TODA YOSHITAKE; HIRANO MASAHIRO; OSAKADA KOHTARO; TAKEUCHI DAISUKE
权利人:JAPAN SCIENCE & TECH AGENCY
摘要:The invention is a process of using, as a reducing agent, a 12CaO.7Al 2 O 3 electride containing electrons in a number of 10 19 or more and 2.3×10 21 cm −3 or less in its cages to subject a carbonyl compound to reductive coupling in a solvent, thereby synthesizing a diol or polydiol. The invention is also a process of reducing a ketone compound in a solvent, thereby synthesizing a secondary alcohol or diketone compound. According to the process of the invention, it is possible to synthesize a diol or polydiol, or a secondary alcohol or diketone compound through simple operations in a short period without using an expensive and harmful metal hydride or metal salt nor limiting the atmosphere for the synthesis to an inert gas atmosphere as in conventional processes.

专利号:CN-111253235-A
优先权日:2020-03-30
标题:Synthesis method and synthesis device of high-purity hypericin

专利号:CN-106966891-A
优先权日:2017-02-07
标题:A kind of total synthesis process of rhein

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品牌试剂参考报价(招募中)

📌 第三方产品分析报告

✅ COA系统入驻 | 共享模式

主要参考文献

[参考文献]: Yang Jb, Et Al. Uhplc-Qqq-Ms/ms Assay For The Quantification Of Dianthrones As Potential Toxic Markers Of Polygonum Multiflorum Thunb: Applications For The Standardization Of Traditional Chinese Medicines (Tcms) With Endogenous Toxicity. Chin Med. 2021 Jul 3;16(1):51.

合成参考文献


摘要:S109 | PARCEDC | List of 7074 potential endocrine disrupting compounds (EDCs) by PARC T4.2 | DOI:10.5281/zenodo.10944198
参考文献:10.1107/s0108768111009657
摘要:Johnstone RD, Allan D, Lennie A, Pidcock E, Valiente R, Rodríguez F, Gonzalez J, Warren J, Parsons S. The effect of pressure on the crystal structure of bianthrone. Acta Crystallogr B. 2011 Jun;67(Pt 3):226–37. doi: 10.1107/s0108768111009657.
参考文献:10.1007/s00436-020-06787-0
摘要:Ghodsian S, Taghipour N, Deravi N, Behniafar H, Lasjerdi Z. Recent researches in effective antileishmanial herbal compounds: narrative review. Parasitol Res. 2020 Dec;119(12):3929–46. doi: 10.1007/s00436-020-06787-0.
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