CAS: 35692-27-4; Trimethoxy(4-Methoxyphenyl)Silane

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CAS号2487-90-3 三甲氧基硅烷 | CAS号696-62-8 4-碘苯甲醚 | CAS号67-56-1 甲醇 | CAS号705-34-0 trichloro-(4-me... | CAS号53040-92-9 4-甲氧基-4-甲基-联苯 | CAS号2622-61-9 1-(4-METHOXYPHE... | CAS号729-17-9 4'-甲氧基-[1,1'-联苯... | CAS号58743-77-4 4-甲氧基-4'-氰基联苯 | CAS号732-80-9 4'-甲氧基-4-连苯基羧酸乙酯 | CAS号613-37-6 4-甲氧基联苯 | CAS号1208-86-2 4-甲氧基二苯胺 | CAS号2143-90-0 4-甲氧基-4'-硝基联苯 | CAS号2132-80-1 4,4-二甲氧基联苯 | CAS号7380-78-1 1-甲氧基-4-苯基乙炔苯

📜4-溴苯甲醚,正硅酸甲酯置于碘,Magnesium体系中,用 乙醚 作为反应溶剂,化学反应 4.0H,以57%的收率获得产物三甲氧基(4-甲氧苯基)硅烷
参考文献:铜催化的区域发散和对映选择性氢化硅烷化
标题:铜催化的区域发散和对映选择性氢化硅烷化
摘要:报道了铜催化的多种简单丙二烯的区域发散氢化硅烷化.通过明智地选择溶剂形成直链和支链烯丙基硅烷.此外,在前所未有的不对称丙二烯氢化硅烷化中,借助 C2 对称双膦配体,获得了具有高对映选择性(高达 97% 对映体过量)的支化烯丙基硅烷.
DOI:10.1021/jacs.2C00260

专利信息

专利号:US-10870917-B2
优先权日:2016-07-08
标 题:Functionalized foams
发明人：DARLING SETH B; ELAM JEFFREY W; MANE ANIL U; SNYDER SETH W
权利人:UCHICAGO ARGONNE LLC
摘要:A method of fabricating an foam includes providing a foam comprising a base material. The base material is coated with an inorganic material using at least one of an atomic layer deposition (ALD), a molecular layer deposition (MLD), or sequential infiltration synthesis (SIS) process. The SIS process includes at least one cycle of exposing the foam to a first metal precursor for a first predetermined time and a first partial pressure. The first metal precursor infiltrates at least a portion of the base material and binds with the base material. The foam is exposed to a second co-reactant precursor for a second predetermined time and a second partial pressure. The second co-reactant precursor reacts with the first metal precursor, thereby forming the inorganic material on the base material. The inorganic material infiltrating at least the portion of the base material. The inorganic material is functionalized with a material.