专利号:US-8609801-B2 优先权日:2011-09-29 标题:Polymers and copolymers containing 2H-benzimidazol-2-one moieties 发明人:HAY ALLAN S; MIR AABID; HLIL ANTISAR R; MATSUMURA SUMIKO 权利人:UNIV MCGILL; UNIV MCGILL 摘要:Polymers and copolymers containing 1H-benzo[d]imidazol-2(3H)-one units have been synthesized under conditions generally used for the synthesis of poly(aryl ether)s. 1H- n nbenzo[d]imidazol-2(3H)-one behaves like a biphenol in the polymerization reaction.n n The soluble homopolymer has a very high glass transition temperature (348° C.), good thermal stability, and forms flexible transparent films. Because of the low molecular weight (134.14) of the benzoimidazolone monomer in the copolymer formed with 4,4′-biphenol that contains 30 mole % of the benzimidazolone unit, only 8.9 weight % is required to raise the Tg of the poly(arlyl ether)sulfone from 220° C. to 269° C.
专利号:US-2025042877-A1 优先权日:2021-11-30 标题:Organic compound, organic device, light-emitting apparatus, and electronic appliance 发明人:HAYASHI YUKI; KAWAKAMI SACHIKO; HASHIMOTO NAOAKI 权利人:SEMICONDUCTOR ENERGY LAB 摘要:A novel compound, a synthesis method thereof, and an organic device including the novel compound are provided. A compound represented by General Formula (G1) is provided. In General Formula (G1), each of R1, R2, and R5 to R7 independently represents any of hydrogen (including deuterium), an alkyl group having 1 to 10 carbon atoms, a substituted or unsubstituted aryl group having 1 to 60 carbon atoms, and a substituted or unsubstituted heteroaryl group having 1 to 60 carbon atoms. R3 represents a condensed ring composed of 4 to 10 rings containing nitrogen as an element forming the ring, and R4 represents any of a substituted or unsubstituted condensed ring having 1 to 60 carbon atoms, a substituted or unsubstituted aryl group with a molecular weight of 78 or more, and a substituted or unsubstituted heteroaryl group with a molecular weight of 80 or more. At least one of A1 to A3 represents nitrogen, and each of the others represents substituted carbon. Each of substituents of A1 to A3 independently represents any of hydrogen (including deuterium), an alkyl group having 1 to 10 carbon atoms, a substituted or unsubstituted aryl group having 1 to 60 carbon atoms, and a substituted or unsubstituted heteroaryl group having 1 to 60 carbon atoms.
参考文献:10.1007/s13361-012-0512-x 摘要:Lobodin VV, Savory JJ, Kaiser NK, Dunk PW, Marshall AG. Charge Reversal Fourier Transform Ion Cyclotron Resonance Mass Spectrometry. Journal of The American Society for Mass Spectrometry. 2013 Jan 08;24(2):213–21. doi: 10.1007/s13361-012-0512-x.