CAS: 80-05-7; Bisphenol A

• ⚠️《化妆品禁用原料目录》
• 英文名称Bisphenol A
• 中文名称双酚A
• IUPAC名称4-[2-(4-hydroxyphenyl)propan-2-yl]phenol
• 其它别名2,2-Bis-4-hydroxyphenylpropane; 4,4'-Dihydroxy-2,2-diphenylpropane; 4,4'-Isopropylidenediphenol
• CAS编号80-05-7
• MFCD编号:MFCD00002366
• EINECS号:201-245-8
• 分子式:C15H16O2
• 分子量:228.29
• 产品CID: 2362060
• 产品分类有机原料→分子砌块→芳环类化合物→苯类化合物

• 相似结构搜索
• 产品信息参考;;;
• InChIKey: IISBACLAFKSPIT-UHFFFAOYSA-N
• InChI=1S/C15H16O2/c1-15(2,11-3-7-13(16)8-4-11)12-5-9-14(17)10-6-12/h3-10,16-17H,1-2H3…
• 计算化学: 氢键受体数2.0氢键供体数2.0可旋转键数2.0

物理性质

• 熔点158-159°C
• 沸点400.8±25.0 °C at 760 mmHg
• 闪点227°C
• 密度1.1±0.1 g/cm3
• pKa:10.29±0.10(预测)
• PSA:40.46
• LogP:3.4237
• 折射率1.599
• 蒸汽压0.0±1.0 mmHg at 25°C
• 溶解性水中的溶解度为0.12g/l
• 敏感性1、白色结晶粉末，具有苯酚气味。2、溶于醋酸、丙酮、甲醇、乙醇、异丙醇、丁醇、醚、苯和碱性溶液，微溶于四氯化碳，难溶于水。呈弱酸性。羟基的邻位很活泼，易被硝化、卤化、硫化、烃化等。低毒。
• 外观形态白色至淡棕色片或粉末
• 储存条件Store at room temperature
• 产品应用用于制环氧树脂,聚碳酸酯,聚酚氧等.
• 性质描述白色针晶或片状粉末.可燃.微带苯酚气味.纯品熔点155-158°C,工业品熔点150-152°C,沸点250-252°C(1.733kPa),相对密度1.195(25/25°C),闪点79.4°C.溶于乙醇,丙酮,乙醚,苯及稀碱液等,微溶于四氯化碳,几乎不溶于水.

MSDS等安全信息

• GHS象形图
• GHS符号GHS08 & GHS07 & GHS05 & GHS09;
  注释: Health hazard & Exclamation mark & Corrosion & Environment
• 危险类别生殖毒性 类别1B
  特定目标器官毒性 - 单次接触 类别3
  严重眼损伤 类别1
  皮肤致敏 类别1
  ED HH 1
  水生急性毒性 类别1
  水生慢性毒性 类别1
  ED ENV 1
  生殖毒性 类别2
  水生慢性毒性 类别2
  皮肤致敏 类别1B
  水生慢性毒性 类别3
  生殖毒性 类别1A
  Ox. Sol. 3
  急性毒性 类别4(经口)
  致癌性 类别1B
  Muta. 1B
  吸入危害 类别1
• 警示词Danger(危险)
• 危险描述H360 |可能损害生育能力或胎儿.
  H335 |可能引起呼吸道刺激.
  H318 |造成严重眼损伤.
  H317 |可能引起皮肤过敏反应.
  EUH380 |May cause endocrine disruption in humans
  H400 |对水生生物毒性极大.
  H410 |对水生生物毒性极大并具有长期持续影响.
  EUH430 |May cause endocrine disruption in the environment
  H361 |怀疑对生育能力或胎儿造成损害.
  H360F |可能损害生育能力.
  H411 |对水生生物有毒并具有长期持续影响.
  H336 |可能引起嗜睡或头晕.
  H412 |对水生生物有害并具有长期持续影响.
  H360D |可能对胎儿造成损害.
  H272 |可能加剧火灾;氧化剂.
  H302 |吞咽有害.
  H350 |可能致癌.
  H340 |可能导致遗传缺陷.
  H304 |吞咽并进入呼吸道可能致命.
  H370 |损害器官.
• 防范说明P261-P271-P272-P273-P280-P302+P352-P304+P340-P362+P364-P391-P405-P501
• 危险等级9
• UN编号3077.0
• 危险品标志Xn:Harmful
• 包装等级Ⅲ
• 安全声明S26-S36/37/39-S45-S46-S39-S36/37
• 危险类别码R43,R62,R41,R37
• WGK Germany2

欧盟法规

上下游产品

合成工艺路线路线简述

• 合成目标产物 Bisphenol A 主要起始原料 Tetrabromobisphenol A
• 25322-68-3 + 80-05-7 = 80-05-7 + 25322-68-3 [标题:Reaction Conditions
  标题:Preparation Of Epoxy Resin Emulsifiers With Different Structures And A Comparative Study Of Their Properties
  作者:Zhang,Yancheng; Huang,He
  参考文献:Chemistryselect 日期:2022 卷标:7(34)]
  
  = 80-05-7 + 837-08-1
  反应条件:1.1 Catalysts: Benzenesulfonic Acid,Divinylbenzene-Styrene Copolymer (Phenoxymethyl And Benzyl Derivatives)
  标题:Preparation Of Bisphenol A By The Condensation Of Phenol And Acetone In The Presence Of Acid Catalyst And Additives
  参考文献:European Patent Organization]
  
  = 80-05-7 + 46765-25-7 + 837-08-1
  反应条件:1.1 Catalysts: Silica; 70 - 120 °C; 3 - 9 H,70 - 120 °C
  标题:Synthesis Of Bisphenol A Catalyzed By H2So4-Sio2 Solid Acid
  作者:Hou,Lijie; Et Al
  参考文献:Gongye Cuihua 日期:2008 卷标:16(12) 页码:68-71]
  
  = 80-05-7 + 63661-69-8 + 472-41-3 + 837-08-1
  反应条件:1.1 Catalysts: Amberlyst 15
  标题:Preparation Of Bisphenol-A Zeolite Catalysts
  作者:Singh,A. P.
  参考文献:Catalysis Letters 日期:1992 卷标:16(4) 页码:431-5]
  
  24936-68-3 = 80-05-7
  反应条件:1.1 Catalysts: Iron Oxide (Fe3O4),Silica,Ammonia Solvents: Diethylene Glycol,Water; Rt -> 160 °C; 78 Min,160 °C
  标题:Magnetic Fe3O4/sio2/nh2 As The Recyclable Heterogeneous Nanocatalyst On Bisphenol-A Recovery From Polycarbonate Wastes
  作者:Emami,S.; Alavi Nikje,M. M.
  参考文献:Russian Journal Of Applied Chemistry 日期:2018 卷标:91(1) 页码:159-166]
  
  1675-54-3 = 80-05-7
  反应条件:1.1 Reagents: Potassium Tert-Butoxide Solvents: Toluene,Tetrahydrofuran; 48 H,160 °C
  标题:Base-Mediated Depolymerization Of Amine-Cured Epoxy Resins
  作者:Dipucchio,Rebecca C.; Stevenson,Katherine R.; Lahive,Ciaran W.; Michener,William E.; Beckham,Gregg T.
  参考文献:Acs Sustainable Chemistry & Engineering 日期:2023 卷标:11(48) 页码:16946-16954]
  
  80-05-7 + 463-79-6 = 80-05-7
  反应条件:1.1 Catalysts: Silanamine,1,1,1-Trimethyl-N-(Trimethylsilyl)-,Zinc Salt (2:1) Solvents: Toluene; 2 H,100 °C
  标题:Selective,Sequential,And "One-Pot" Depolymerization Strategies For Chemical Recycling Of Commercial Plastics And Mixed Plastics
  作者:Yang,Rulin; Xu,Guangqiang; Dong,Bingzhe; Guo,Xuanhua; Wang,Qinggang
  参考文献:Acs Sustainable Chemistry & Engineering 日期:2022 卷标:10(30) 页码:9860-9871]
  
  24936-68-3 = 80-05-7
  反应条件:1.1 Reagents: Methanol Catalysts: Iron Chloride (Fecl3),1-Butyl-3-Methylimidazolium Chloride; Rt -> 120 °C; 3 H,120 °C
  标题:Efficient Alcoholysis Of Polycarbonate Catalyzed By Recyclable Lewis Acidic Ionic Liquids
  作者:Guo,Jiao; Liu,Mengshuai; Gu,Yongqiang; Wang,Yuchen; Gao,Jun; Et Al
  参考文献:Industrial & Engineering Chemistry Research 日期:2018 卷标:57(32) 页码:10915-10921]
  
  24936-68-3 = 80-05-7
  反应条件:1.1 Catalysts: 1-Butyl-3-Methylimidazolium Chloride Solvents: Water; Rt -> 165 °C; 3 H,165 °C
  标题:Hydrolysis Of Polycarbonate Using Ionic Liquid [bmim][cl] As Solvent And Catalyst
  作者:Li,Lei; Liu,Fusheng; Li,Zhuo; Song,Xiuyan; Yu,Shitao; Et Al
  参考文献:Fibers And Polymers 日期:2013 卷标:14(3) 页码:365-368]
  
  80-05-7 + 463-79-6 = 80-05-7
  反应条件:1.1 Reagents: Water Catalysts: Sodium Hydroxide Solvents: 1,4-Dioxane; 8 H,100 °C
  标题:Preparation Of Bisphenol A From Waste Polycarbonate By Hydrolysis Process
  作者:Li,Zhuo; Liu,Fusheng; Yu,Shitao; Cui,Xiao; Ge,Xiaoping
  参考文献:Huagong Huanbao 日期:2009 卷标:29(4) 页码:348-351]
  
  79-94-7 = 80-05-7
  反应条件:1.1 Reagents: Triethylamine,Hydrogen Catalysts: Chitosan Solvents: Methanol,Water; 116 H,30 Bar,120 °C
  标题:A Biomass-Derived Non-Noble Cobalt Catalyst For Selective Hydrodehalogenation Of Alkyl And (Hetero)Aryl Halides
  作者:Sahoo,Basudev; Surkus,Annette-Enrica; Pohl,Marga-Martina; Radnik,Joerg; Schneider,Matthias; Et Al
  参考文献:Angewandte Chemie 日期:2017 卷标:56(37) 页码:11242-11247]
  
  25322-68-3 + 80-05-7 = 80-05-7 + 25322-68-3
  反应条件:1.1 Solvents: 1-Methoxy-2-Propanol; Rt -> 70 °C1.2 Catalysts: Boron Trifluoride Etherate; 3 H,70 °C; 70 °C; 70 °C -> 95 °C; 9 H,95 °C; 95 °C -> 60 °C
  标题:Preliminary Results On Preparation And Performance Of A Self-Emulsifying Waterborne Epoxy Curing Agent At Room Temperature
  作者:Pi,Zhenzhen; Deng,Changyu; Pan,Hongmei; Pei,Kemei
  参考文献:Polymers (Basel 日期:2023 卷标:15(7)]
  
  25322-68-3 + 80-05-7 = 80-05-7 + 25322-68-3
  反应条件:1.1 4 H,120 °C
  标题:Preparation Of High-Strength,Water-Resistant Starch Adhesive And Its Bonding Mechanism To Cotton Stalk
  作者:Li,Kui; Zuo,Yingfeng; Zheng,Long; Wang,Huifen; Wu,Yiqiang
  参考文献:Industrial Crops And Products 日期:2023 卷标:194]
  
  19438-60-9 + 1675-54-3 = 80-05-7 + 538-43-2 + 764-93-2 + 85-42-7 + 591-49-1 + 493-08-3
  反应条件:1.1 Solvents: Water; 30 Min,280 °C
  标题:Decomposition Behavior And Decomposition Products Of Epoxy Resin Cured With Mehhpa In Near-Critical Water
  作者:Gong,Xianyun; Et Al
  参考文献:Journal Of Wuhan University Of Technology 日期:2013 卷标:28(4) 页码:781-786]
  
  59562-82-2 + 24936-68-3 = 80-05-7 + 34619-03-9
  反应条件:1.1 Catalysts: 1,5,7-Triazabicyclo[4.4.0]Dec-5-Ene Solvents: 2-Methyltetrahydrofuran; 12 H,Rt
  标题:Chemical Recycling Of Poly(Bisphenol A Carbonate): 1,5,7-Triazabicyclo[4.4.0]-Dec-5-Ene Catalyzed Alcoholysis For Highly Efficient Bisphenol A And Organic Carbonate Recovery
  作者:Do,Taeyang; Baral,Ek Raj; Kim,Jeung Gon
  参考文献:Polymer 日期:2018 卷标:143 页码:106-114]
  
  24936-68-3 = 80-05-7
  反应条件:1.1 Reagents: Methanol Catalysts: 1,5,7-Triazabicyclo[4.4.0]Dec-5-Ene Solvents: Dichloromethane; 2.5 H,75 °C
  标题:Versatile Imidazole-Anion-Derived Ionic Liquids With Unparalleled Activity For Alcoholysis Of Polyester Wastes Under Mild And Green Conditions
  作者:Liu,Mengshuai; Guo,Jiao; Gu,Yongqiang; Gao,Jun; Liu,Fusheng
  参考文献:Acs Sustainable Chemistry & Engineering 日期:2018 卷标:6(11) 页码:15127-15134]
  
  = 80-05-7
  反应条件:1.1 Reagents: Potassium Hydroxide; 2 H,160 °C
  标题:Catalytic,Aerobic Depolymerization Of Epoxy Thermoset Composites
  作者:Navarro,Carlos A.; Ma,Yijia; Michael,Katelyn H.; Breunig,Hanna M.; Nutt,Steven R.; Et Al
  参考文献:Green Chemistry 日期:2021 卷标:23(17) 页码:6356-6360]
  
  24936-68-3 = 80-05-7
  反应条件:1.1 Catalysts: Tetramethylammonium Chloride,Zinc Oxide (Zno) Solvents: Water; 7 H,100 °C
  标题:Degradation Of Waste Polycarbonate Via Hydrolytic Strategy To Recover Monomer (Bisphenol A) Catalyzed By Dbu-Based Ionic Liquids Under Metal- And Solvent-Free Conditions
  作者:Liu,Mengshuai; Guo,Jiao; Gu,Yongqiang; Gao,Jun; Liu,Fusheng
  参考文献:Polymer Degradation And Stability 日期:2018 卷标:157 页码:9-14]
  
  = 80-05-7 + 837-08-1
  反应条件:1.1 Catalysts: 1-Propanethiol,Ethanesulfonic Acid; 24 H,100 °C
  标题:Enhanced Cooperative,Catalytic Behavior Of Organic Functional Groups By Immobilization
  作者:Zeidan,Ryan K.; Et Al
  参考文献:Journal Of Catalysis 日期:2006 卷标:239(2) 页码:299-306

海关参考信息

• 2902600000-乙苯
  2902700000-异丙基苯
  2908199090-其他酚的卤化衍生物
  2908999090-其他酚的硝化衍生物
• 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
• 详情请参考：📖 海关编码查询和海关进出口税则

其他信息查阅

• ➥ 象形图和危险代码
• ➥ 防范代码详解
• ➥ 危险代码说明
• ➥ Globally Harmonized System
• ➥ REACH监管