CAS: 71098-88-9; N-(Phenylseleno)Phthalimide

该化合物是一种有机化合物,其特征是存在一种硫酰胺和苯赛利基组,它一般是晶状固体,以其独特的化学特性而著称,其中包括由于存在原子而能够参与各种化学反应,该化合物经常用于有机合成,特别是形成含有锂的化合物,并可能表现出有趣的生物活动.该化合物的结构允许在医药化学和材料科学中进行潜在应用.原子的存在可影响该化合物的再活动性和稳定性,使其成为侧重于有机糖化学的研究的焦点.此外,N-(苯赛利诺)二硫化物可能表现出特定的溶性特征,取决于所使用的溶剂及其与其他化学物种的相互作用可导致多种衍生物的形成.

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上下游产品

CAS号5707-04-0 苯硒酰氯 | CAS号1074-82-4 邻苯二甲酰亚胺钾盐 | CAS号3481-09-2 N-氯代酞酰亚胺 | CAS号23974-72-3 Sodium benzenes... | CAS号109574-18-7 methyl 4-oxo-5-... | CAS号111735-16-1 (1-cyclohexyl-2... | CAS号111735-17-2 [2-cyclohexyl-2... | CAS号127489-35-4 6-phenylselanyl... | CAS号171005-00-8 1,1-bis(phenyls... | CAS号1666-13-3 二苯基二硒醚 | CAS号120368-14-1 3-(phenylseleno... | CAS号18255-05-5 benzylselanylbenzene

合成工艺路线路线简述

    📜邻苯二甲酸亚胺置于sodium Hypochlorite体系中,用 乙醚,水 作为反应溶剂,化学反应 3.0H,反应生成 N-(苯硒基)邻苯二甲酰亚胺
    参考文献:New Syntnesis Of Unstabilized Selenenamides
    标题:New Syntnesis Of Unstabilized Selenenamides
    摘要:
    DOI:10.1016/s0040-4039(00)94651-3

    海关参考信息

    专利信息


    专利号:US-6005097-A
    优先权日:1996-06-14
    标题 :Processes for high-yield diastereoselective synthesis of dideoxynucleosides
    发明人:CHEN SHU-HUI; LI XIUYAN
    权利人:VION PHARMACEUTICALS INC
    摘要:The present invention relates to methods for substantially enhancing the stereoselective synthesis of β-anomeric nucleoside analogs. In methods according to the present invention, the introduction of a phenylseleno group onto a blocked lactone sugar precursor may be selected so that the desirable phenylseleno substituent is introduced on the side of the blocked lactone away from the blocking group. This stereospecific introduction of the phenylseleno group in sugar precursor allows the synthesis of nucleoside analogs and in particular, 2',3',-dideoxy- and 2',3'-dideoxy-2',3'-didehydronucleoside analogs in very high yield. In certain preferred embodiments, the preferred phenylseleno blocked lactone is obtained in an amount representing approximately 90% or more of the total amount of the stereoisomers obtained. In even more preferred embodiments, the amount of the preferred stereoisomer is at least 95%, even more preferably at least about 97% of the total amount of phenylseleno blocked lactone produced.

    专利号:US-7968734-B2
    优先权日:2004-07-01
    标 题 :Organocatalysts and methods of use in chemical synthesis
    发明人:WANG WEI; WANG JIAN; LI HAO
    权利人:STC UNM
    摘要:The present invention pertains generally to compositions comprising organocatalysts that facilitate stereo-selective reactions and the method of their synthesis and use. Particularly, the invention relates to metal-free organocatalysts for facilitation of stereo-selective reactions, and the method of their synthesis and use.

    专利号:WO-9747635-A1
    优先权日:1996-06-14
    标 题:Processes for high-yield diastereoselective synthesis of dideoxynucleosides

    专利号:CN-102803236-A
    优先权日:2009-06-12
    标 题:Synthesis of TTX intermediates

    专利号:US-2012142911-A1
    优先权日:2009-06-12
    标题:Synthesis of ttx intermediates

    专利号:JP-2000512637-A
    优先权日:1996-06-14
    标 题:High yield diastereoselective synthesis of dideoxynucleosides

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Sano, H.; Nishimura, J., Science of Synthesis, (2010) 45, 499.
    摘要:Haufe, G., Science of Synthesis Knowledge Updates, (2019) 3, 245.
    摘要:Kashemirov, B. A.; Błażewska, K.; Justyna, K.; Lyu, J.; McKenna, C. E., Science of Synthesis Knowledge Updates, (2021) 1, 409.
    摘要:Mukherjee, S., Science of Synthesis: Asymmetric Organocatalysis, (2012) 1, 252.
    摘要:Wang, H.-Y.; Zhao, G., Science of Synthesis, (2019) , 236.
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