专利号:US-5256799-A 优先权日:1992-07-14 标 题 :Preparation of 6-hydroxyindolines and their use for preparation of novel laser dyes 发明人:FIELD GEORGE F; HAMMOND PETER R 权利人:US OF AMERICAS AS REPRESENTED 摘要:A novel method for the synthesis of 6-hydroxyindolines and new fluorescent dyes produced therefrom, which dyes are ring-constrained indoline-based rhodamine class dyes. These dyes have absorption and emission spectra which make them particularly useful in certain dye laser applications.
专利号:US-6153744-A 优先权日:1996-05-20 标 题 :Nucleoside derivatives with photolabile protective groups 发明人:PFLEIDERER WOLFGANG; BUEHLER SIGRID 权利人:WOLFGANG PFLEIDERER 摘要:The invention relates to nucleo-side derivatives with photo-unstable protective groups of the general formula (I) in which R1 is H, NO2, CN, OCH3, halogen, alkyl or alkoxyalkyl with 1 to 4 C atoms, R2 is H, OCH3, R3 is H, F, Cl, Br, NO2 or an aliphatic acyl radical with 2 to 5 C atoms, R4 is H, halogen, OCH3, an alkyl radical with 1 to 4 C atoms or a possibly substituted aryl radical, R5 is H or a conventional functional group for producing oligonucleotides, R6 is H, OH, halogen or XR8, where X is O or S and R8 is a conventional protective group in nucleotide chemistry, B is adenine, cytosin, guanine, thymine, uracil, 2,6-diaminopurin-9-yl, hypoxanthin-9-yl, 5-methylcytosin-1-yl, 5-amino-4-imidazol carboxylic acid amid-1-yl or 5-amino-4-imidazol carboxylic acid amide-3-yl, where, if B is adenine, cytosin or guanine, the primary amino function may have a permanent protective group. These derivatives may be used for the light-controlled synthesis of oligonucleotides on a DNA chip.
专利号:WO-9640693-A1 优先权日:1995-06-07 标 题 :Process for the synthesis of vinyl sulfenic acid derivatives
专利号:EP-0830362-A1 优先权日:1995-06-07 标 题:Process for the synthesis of vinyl sulfenic acid derivatives
参考标题:Synthesis Of Olefins From Nitroesters 作者:P. M. Kochergin,L. S. Blinova,G. A. Karpov,I. S. Mikhailova,E. V. Aleksandrova,O. V. Korol |发布日期:1999.1 摘要:Olefins Of The Aromatic, Heterocyclic, And Aliphatic Series. Most Thoroughly Studied Was The Conversion Of 4-Nitrophenylnitrate (1) Into 4-Nitrostyrene (II) [12]. It Was Established That Nitroester I Intensively Reacts In Alcohol Solutions With Sodium Ethylate, Sodium Hydroxide, And Triethyibenzylammonium Hydroxide To Form Olefin Ii. The Reaction With Triethylamine Proceeds On Heating. The Yield Of