CAS: 3512-18-3; 2,3,6-Trifluoropyridine

• 英文名称2,3,6-Trifluoropyridine
• 中文名称2,3,6-三氟吡啶
• IUPAC名称2,3,6-trifluoropyridine
• 其它别名2,3,6-Trifluoropyridine; Pyridine, 2,3,6-Trifluoro-; 2,3,6-Trifluoro-Pyridine; 2,3,6-Tris(Fluoranyl)Pyridine; Hrliangjwpjfkw-Uhfffaoysa-N
• CAS编号3512-18-3
• MFCD编号:MFCD03001158
• EINECS号:680-721-0
• 分子式:C5H2F3N
• 分子量:133.07
• 产品CID: 1356988
• 产品分类有机原料→分子砌块→芳杂环类化合物→吡啶类化合物

• 相似结构搜索
• 产品信息参考
• InChIKey: HRLIANGJWPJFKW-UHFFFAOYSA-N
• InChI=1S/C5H2F3N/c6-3-1-2-4(7)9-5(3)8/h1-2H…
• 计算化学: 氢键受体数1.0氢键供体数0.0可旋转键数0.0

相似化合物

物理性质

• 熔点115-116 °C
• 沸点100-102 °C at 760 mmHg
• 闪点30°C
• 密度1,499 g/cm3
• pKa:-8.51±0.10(预测)
• PSA:12.89
• LogP:1.4989
• 折射率1.42
• 蒸汽压15.9 mmHg at 25 °C
• 溶解性Not Miscible Or Difficult To Mix In Water.
• 敏感性常温常压下稳定
• 外观形态透明,红色液体
• 储存条件2-8°C
• 产品应用该化合物用于有机合成物和药物中的中间体.

MSDS等安全信息

• GHS象形图
• GHS符号GHS02 & GHS07;
  注释: Flame & Exclamation mark
• 危险类别易燃液体 类别3
  皮肤腐蚀/刺激 类别2
  严重眼刺激 类别2
  特定目标器官毒性 - 单次接触 类别3
  皮肤腐蚀 类别1B
  严重眼刺激 类别2A
• 警示词Warning(警告)
• 危险描述H226 |易燃液体和蒸气.
  H315 |造成皮肤刺激.
  H319 |造成严重眼刺激.
  H335 |可能引起呼吸道刺激.
  H314 |造成严重皮肤灼伤和眼损伤.
• 防范说明P210-P233-P235-P240-P241-P242-P243-P261-P264-P271-P280-P304+P340-P362-P370+P378-P405-P501
• 危险等级3
• UN编号1993.0
• 危险品标志Xi,F,C
• 风险等级Flammable/Irritant
• 包装等级Ⅲ
• 安全声明26-36/37/39-37
• 危险类别码36/37/38-10

欧盟法规

上下游产品

合成工艺路线路线简述

• 700-16-3 + 99476-19-4 = 3512-18-3 + 76469-41-5 + 71902-33-5 + 372-47-4 + 84476-99-3
  反应条件:1.1 Solvents: Toluene; 3 D,Rt2.1 Reagents: Triethylsilane Catalysts: Di-μ-Hydrobis[1,1′-(1,3-Propanediyl)Bis[1,1-Bis(1-Methylethyl)Phosphine-Kp]]Dirh... Solvents: Benzene-D6; 48 H,Rt -> 50 °C
  标题:Catalytic Hydrodefluorination Of Fluoroaromatics With Silanes As Hydrogen Source At A Binuclear Rhodium Complex: Characterization Of Key Intermediates
  作者:Zamostna,Lada; Et Al
  参考文献:Journal Of Fluorine Chemistry 日期:2013 卷标:155 页码:132-142]
  
  2875-18-5 = 3512-18-3 + 76469-41-5 + 71902-33-5 + 372-47-4 + 84476-99-3
  反应条件:1.1 Reagents: Triethylsilane Catalysts: Di-μ-Hydrobis[1,1′-(1,3-Propanediyl)Bis[1,1-Bis(1-Methylethyl)Phosphine-Kp]]Dirh... Solvents: Benzene-D6; 48 H,Rt -> 50 °C
  标题:Catalytic Hydrodefluorination Of Fluoroaromatics With Silanes As Hydrogen Source At A Binuclear Rhodium Complex: Characterization Of Key Intermediates
  作者:Zamostna,Lada; Et Al
  参考文献:Journal Of Fluorine Chemistry 日期:2013 卷标:155 页码:132-142]
  
  700-16-3 = 3512-18-3 + 76469-41-5 + 71902-33-5 + 372-47-4 + 84476-99-3
  反应条件:1.1 Reagents: Triethylsilane Catalysts: Di-μ-Hydrobis[1,1′-(1,3-Propanediyl)Bis[1,1-Bis(1-Methylethyl)Phosphine-Kp]]Dirh... Solvents: Benzene-D6; 48 H,Rt -> 50 °C2.1 Reagents: Triethylsilane Catalysts: Di-μ-Hydrobis[1,1′-(1,3-Propanediyl)Bis[1,1-Bis(1-Methylethyl)Phosphine-Kp]]Dirh... Solvents: Benzene-D6; 48 H,Rt -> 50 °C
  标题:Catalytic Hydrodefluorination Of Fluoroaromatics With Silanes As Hydrogen Source At A Binuclear Rhodium Complex: Characterization Of Key Intermediates
  作者:Zamostna,Lada; Et Al
  参考文献:Journal Of Fluorine Chemistry 日期:2013 卷标:155 页码:132-142]
  
  6485-79-6 = 3512-18-3 + 76469-41-5 + 71902-33-5 + 372-47-4 + 84476-99-3
  反应条件:1.1 Solvents: Toluene-D8; 2 H,Rt2.1 Solvents: Toluene; 3 D,Rt3.1 Reagents: Triethylsilane Catalysts: Di-μ-Hydrobis[1,1′-(1,3-Propanediyl)Bis[1,1-Bis(1-Methylethyl)Phosphine-Kp]]Dirh... Solvents: Benzene-D6; 48 H,Rt -> 50 °C
  标题:Catalytic Hydrodefluorination Of Fluoroaromatics With Silanes As Hydrogen Source At A Binuclear Rhodium Complex: Characterization Of Key Intermediates
  作者:Zamostna,Lada; Et Al
  参考文献:Journal Of Fluorine Chemistry 日期:2013 卷标:155 页码:132-142]
  
  = 3512-18-3 + 76469-41-5 + 71902-33-5 + 372-47-4 + 84476-99-3
  反应条件:1.1 Solvents: Toluene-D8; 8 H,Rt -> 50 °C2.1 Solvents: Toluene; 3 D,Rt3.1 Reagents: Triethylsilane Catalysts: Di-μ-Hydrobis[1,1′-(1,3-Propanediyl)Bis[1,1-Bis(1-Methylethyl)Phosphine-Kp]]Dirh... Solvents: Benzene-D6; 48 H,Rt -> 50 °C
  标题:Catalytic Hydrodefluorination Of Fluoroaromatics With Silanes As Hydrogen Source At A Binuclear Rhodium Complex: Characterization Of Key Intermediates
  作者:Zamostna,Lada; Et Al
  参考文献:Journal Of Fluorine Chemistry 日期:2013 卷标:155 页码:132-142]
  
  = 3512-18-3 + 76469-41-5 + 71902-33-5 + 372-47-4 + 84476-99-3
  反应条件:1.1 Solvents: Toluene-D8; 8 H,Rt -> 50 °C2.1 Solvents: Toluene; 3 D,Rt3.1 Reagents: Triethylsilane Catalysts: Di-μ-Hydrobis[1,1′-(1,3-Propanediyl)Bis[1,1-Bis(1-Methylethyl)Phosphine-Kp]]Dirh... Solvents: Benzene-D6; 48 H,Rt -> 50 °C
  标题:Catalytic Hydrodefluorination Of Fluoroaromatics With Silanes As Hydrogen Source At A Binuclear Rhodium Complex: Characterization Of Key Intermediates
  作者:Zamostna,Lada; Et Al
  参考文献:Journal Of Fluorine Chemistry 日期:2013 卷标:155 页码:132-142]
  
  617-86-7 = 3512-18-3 + 76469-41-5 + 71902-33-5 + 372-47-4 + 84476-99-3
  反应条件:1.1 Solvents: Toluene-D8; -30 °C; 20 H,-15 °C2.1 Solvents: Toluene-D8; 2 H,Rt3.1 Solvents: Toluene; 3 D,Rt4.1 Reagents: Triethylsilane Catalysts: Di-μ-Hydrobis[1,1′-(1,3-Propanediyl)Bis[1,1-Bis(1-Methylethyl)Phosphine-Kp]]Dirh... Solvents: Benzene-D6; 48 H,Rt -> 50 °C
  标题:Catalytic Hydrodefluorination Of Fluoroaromatics With Silanes As Hydrogen Source At A Binuclear Rhodium Complex: Characterization Of Key Intermediates
  作者:Zamostna,Lada; Et Al
  参考文献:Journal Of Fluorine Chemistry 日期:2013 卷标:155 页码:132-142]
  
  6485-79-6 = 3512-18-3 + 76469-41-5 + 71902-33-5 + 372-47-4 + 84476-99-3
  反应条件:1.1 Solvents: Toluene-D8; -30 °C; 20 H,-15 °C2.1 Solvents: Toluene-D8; 8 H,Rt -> 50 °C3.1 Solvents: Toluene; 3 D,Rt4.1 Reagents: Triethylsilane Catalysts: Di-μ-Hydrobis[1,1′-(1,3-Propanediyl)Bis[1,1-Bis(1-Methylethyl)Phosphine-Kp]]Dirh... Solvents: Benzene-D6; 48 H,Rt -> 50 °C
  标题:Catalytic Hydrodefluorination Of Fluoroaromatics With Silanes As Hydrogen Source At A Binuclear Rhodium Complex: Characterization Of Key Intermediates
  作者:Zamostna,Lada; Et Al
  参考文献:Journal Of Fluorine Chemistry 日期:2013 卷标:155 页码:132-142

海关参考信息

• 2933310010-吡啶
  2939800000-其他生物碱
• 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
• 详情请参考：📖 海关编码查询和海关进出口税则

专利信息

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• ➥ 象形图和危险代码
• ➥ 防范代码详解
• ➥ 危险代码说明
• ➥ Globally Harmonized System
• ➥ REACH监管