CAS: 1074-12-0; Phenylglyoxal

相似化合物

78146-52-8 1603-79-8 582-24-1

上下游产品

CAS号582-24-1 2-羟基苯乙酮 | CAS号98-86-2 苯乙酮 | CAS号532-54-7 2-异亚硝基苯乙酮 | CAS号536-74-3 苯乙炔 | CAS号292638-84-7 phenylene-ethylene | CAS号93-56-1 (±)-1-苯基-1,2-乙二醇 | CAS号6175-45-7 2,2-二乙氧基苯乙酮 | CAS号70-11-1 2-溴苯乙酮 | CAS号19159-39-8 2,2-dimethoxy p... | CAS号103977-08-8 7-nitro-2-pheny... | CAS号105783-89-9 6-phenylfuro[2,... | CAS号51096-49-2 S-(-)-2-苄基氨基-1-苯基乙醇 | CAS号5271-26-1 2-苯基哌嗪 | CAS号41270-62-6 2-氯-6-苯基吡嗪 | CAS号98-85-1 苏合香醇 | CAS号98-86-2 苯乙酮 | CAS号93-56-1 (±)-1-苯基-1,2-乙二醇 | CAS号141542-10-1 1,1-dioxo-3-phe...

📜2-异亚硝基苯乙酮置于水,戴斯-马丁氧化剂体系中,用 二氯甲烷 用作溶剂,化学反应 0.33H,以92%的收率获得苯基丙醇水合物
参考文献:A Mild,Chemoselective,Oxidative Method For Deoximation Using Dess-Martin Periodinane
标题:A Mild,Chemoselective,Oxidative Method For Deoximation Using Dess-Martin Periodinane
摘要:Dess-Martin高碘烷(dmp,即[1,1,1-三乙酰氧基-1,1-二氢-1,2-苯并碘氧杂环戊烯-3(1H)-酮])能高效且快速地在温和条件下氧化脱氧肟化醛肟及酮肟,产率极高.在含有伯醇,仲醇,苄醇,O-甲基肟,对甲苯磺酰腙以及对酸敏感基团的条件下,脱氧肟化反应能够选择性地进行.
Doi:10.1055/s-1999-3476

专利信息

专利号:US-2004152905-A1
优先权日:2003-01-31
标题:Universal building blocks and support media for synthesis of oligonucleotides and their analogs
发明人：GUZAEV ANDREI P; MANOHARAN MUTHIAH
摘要:Compounds for the synthesis of oligomeric compounds, particularly oligonucleotides and chemically modified oligonucleotide analogs, are provided. In addition, methods for functionalization of a support medium with a first monomeric subunit and methods for the synthesis of oligomeric compounds utilizing the novel compounds bound to support media are provided.

专利号:US-2004242897-A1
优先权日:2002-07-31
标题 :Universal support media for synthesis of oligomeric compounds
发明人：GUZAEV ANDREI P; MANOHARAN MUTHIAH
摘要:Compounds for the synthesis of oligomeric compounds, particularly oligonucleotides and oligonucleotide mimetics, are provided. In addition, methods for functionalizing a support medium with a first monomeric subunit and methods for the synthesis of oligomeric compounds utilizing the novel compounds bound to support media are provided.

专利号:US-11542269-B2
优先权日:2018-01-03
标 题:Prins reaction and compounds useful in the synthesis of halichondrin macrolides and analogs thereof
发明人：CHOI HYEONG-WOOK; FANG FRANCIS G
权利人:EISAI R&D MAN CO LTD
摘要:The invention provides methods utilizing Prins reaction in the preparation of compounds that may be useful as intermediates in the synthesis of halichondrin macrolides and analogs thereof. The invention also provides compounds that may be useful as intermediates in the synthesis of a halichondrin macrolides and methods for preparing the same.

专利号:WO-2023102600-A1
优先权日:2021-12-06
标题:Synthesis of amphiphilic block copolymers and polymeric nanofibers produced therefrom
发明人：ZETTERLUND PER B; ISHIZUKA FUMI; KIM HYUN JIN; CHATANI SHUNSUKE; NIINO HIROSHI
权利人:NEWSOUTH INNOVATIONS PTY LTD
摘要:The present disclosure relates to the field of synthesis of block copolymers, and polymeric nanofibers having a core-shell morphology produced therefrom. The present disclosure relates to the field of synthesis of block copolymers where one block is more hydrophobic than the other block and is a different composition. The disclosure also relates to uses of these polymeric nanofibers in various applications, such as reinforcing a polymeric matrix and for coatings applications.

专利号:US-10913749-B2
优先权日:2015-05-07
标 题 :Macrocyclization reactions and intermediates and other fragments useful in the synthesis of halichondrin macrolides
发明人：FANG FRANCIS G; KIM DAE-SHIK; CHOI HYEONG-WOOK; CHASE CHARLES E
权利人:EISAI R&D MAN CO LTD
摘要:The invention provides methods for the synthesis of a halichondrin macrolides through a macrocyclization strategy. The macrocyclization strategy of the present invention involves subjecting a non-macrocyclic intermediate to a carbon-carbon bond-forming reaction (e.g., an olefination reaction (e.g., Horner-Wadsworth-Emmons olefination), catalytic Ring-Closing Olefin Metathesis, or Nozaki-Hiyama-Kishi reaction) to afford a macrocyclic macrolide. The invention also provides compounds useful as intermediates in the synthesis of a halichondrin macrolides and methods for preparing the same.

专利号:US-11136335-B2
优先权日:2016-06-30
标题:Prins reaction and intermediates useful in the synthesis of halichondrin macrolides and analogs thereof
发明人：CHASE CHARLES E; CHOI HYEONG-WOOK; ENDO ATSUSHI; FANG FRANCIS G; KIM DAE-SHIK
权利人:EISAI R&D MAN CO LTD
摘要:The invention provides methods for the synthesis of a halichondrin macrolides or analogs thereof through a cyclization reaction strategy. The strategy of the present invention involves subjecting an intermediate to Prins reaction conditions to afford a macrolide. The invention also provides compounds useful as intermediates in the synthesis of a halichondrin macrolides or analogs thereof and methods for preparing the same.