CAS: 1720-38-3; 1,9-Decadiyne

相似化合物

764-93-2 765-10-6 3452-09-3

上下游产品

CAS号88736-98-5 trimethyl(10-tr... | CAS号629-03-8 1,6-二溴己烷 | CAS号1066-26-8 乙炔化钠,二甲苯溶液 | CAS号629-09-4 1,6-二碘己烷 | CAS号110-52-1 1,4-二溴丁烷 | CAS号106-96-7 溴代丙炔 | CAS号31699-38-4 2,10-十二碳二炔 | CAS号1697-71-8 cyclohexadeca-1... | CAS号1647-16-1 1,9-癸二烯 | CAS号24854-67-9 Oxirane,2,2'-(1... | CAS号16538-91-3 癸烷-2,9-二酮 | CAS号80220-89-9 undeca-2,10-diy... | CAS号65111-03-7 dodeca-2,10-diy... | CAS号88736-98-5 trimethyl(10-tr... | CAS号45037-67-0 decanedial

📜1,9-癸二烯置于吡啶,正丁基锂,Pyridinium Hydrobromide Perbromide,N,N-二乙基乙二胺体系中,用 2-甲基四氢呋喃,正己烷,乙腈 用作溶剂,化学反应 0.5H,反应生成1,9-癸二炔
参考文献:Grazoprevir的功能化反式环丙氧基结构单元的不对称合成
标题:Grazoprevir的功能化反式环丙氧基结构单元的不对称合成
摘要:报道了用于制备hcv Ns3 / 4A蛋白酶抑制剂格拉佐普韦的官能化反式-环丙氧基结构单元的实用和不对称合成.分子内s N 2置换-环闭合,然后进行baeyer-Villiger氧化,可制得所需的反式-环丙醇,并完全控制非对映选择性.然后使用linh(ch 2)2 Net 2有效地安装末端炔烃.从(S)-表氯醇开始,以51%的总收率制备了环丙氧基结构单元,光学纯度> 99.8%,无需分离任何中间体.
Doi:10.1021/acs.Orglett.7B02867

专利信息

专利号:US-3578724-A
优先权日:1968-03-04
标 题:Migration and isomerization of acetylenes
发明人：HUBERT ANDRE JULES
权利人:UNION CARBIDE CORP
摘要:PROCESS FOR THE MIGRATION OF ACETYLENIC BONDS AND A PROCESS FOR THE ISOMERIZATION OF HYDROCARBONS CONTAINING ACETYLENIC BONDS TO HYDROCARBONS CONTAINING CONJUGATED UNSATURATION, BY CONTACTING A COMPOUND CONTAINING ONE OR TWO ACETYLENIC BONDS WITH POTASSIUM AMIDE ON ALUMINA. THE UNSATURATED COMPOUNDS PRODUCED BY THE PROCESS OF THE INVENTION ARE USEFUL AS ULTRAVIOLET LIGHT ABSORBERS, AS CROSS-LINKING AGENTS FOR POLYOLEFINIC ELASTOMERS, AND AS INTERMEDIATES IN THE SYNTHESIS OF NEW COMPOUNDS.

专利号:US-11359049-B2
优先权日:2017-09-21
标题:Gold catalyzed polymerization reactions of unsaturated substrates
发明人：AZOULAY JASON D; TROPP JOSHUA; KING ERIC
权利人:AZOULAY JASON D; TROPP JOSHUA; KING ERIC; THE UNIV OF SOUTHERN MISSISSIPPI
摘要:The present invention provides novel methods and processes for polymerizing unsaturated substrates, such as alkyne bearing monomers, with arenes. The polymerizations are catalyzed by gold (Au) catalysts/complexes and/or other cocatalysts. The invention further provides novel structurally complex polymers prepared in high yield via an intermolecular polyhydroarylation mechanism. Such resulting products comprise oligomeric and polymeric materials with novel molecular architectures and microstructures, which subsequently impart unique properties. The invention includes both the synthesis methods and processes and the resulting compounds and compositions of matter.

专利号:TW-I523857-B
优先权日:2011-08-05
标题 :Synthesis of Polycyclic Aromatic Compounds, Aromatic Polymers, and Aromatic Compounds