CAS: 16484-77-8; (2R)-2-(4-Chloro-2-Methylphenoxy)Propanoic Acid

该化合物是一种选择性除草剂,主要用于控制不同作物和草皮中的宽叶草,属于苯氧除草剂家族,其特点是能够模仿天然植物激素,导致无节制的生长,最终导致目标杂草死亡.该物质一般是一种白色晶状固体,在室内温度下可溶于有机溶剂,但水溶性有限.其行动方式涉及破坏植物的生长规范,在双叶植物中特别有效,同时避免单生植物. (+)-甲基丙丙酸经常与其他除草剂结合使用,以提高其功效,扩大除草剂控制范围.在处理该化学品时,安全措施至关重要,因为如果不按照准则使用,它可能对非目标生物和环境构成风险.适当应用技术和遵守监管标准对于减少潜在的生态影响至关重要.

结构式图片

相似化合物

93-65-2 7345-21-3 94-74-6

欧盟法规

统一分类与标签REACH注册ECHA物质ECHA物质欧盟农药活性物质C&L通报REACH预注册

上下游产品

CAS号115304-95-5 mecoprop methyl... | CAS号66513-22-2 (R)-Ethyl 2-(4-... | CAS号23844-56-6 2-甲基-4-氯丙酸甲酯 | CAS号1570-64-5 4-氯-2-甲基苯酚 | CAS号93-65-2 2-(4-氯-2-甲基苯氧基)丙酸 | CAS号27854-88-2 (R)-1-(吡啶-4-基)乙醇 | CAS号42383-63-1 2-(4-Chlor-2-me...

合成工艺路线路线简述

  • 合成目标产物 Mecoprop-P 主要起始原料 Propanoic Acid, 2-(4-Chloro-2-Methylphenoxy)-, Methyl Ester, (2R)-
  • (文献来源)合成步骤主要原料 Propanoic Acid, 2-(4-Chloro-2-Methylphenoxy)-, Methyl Ester, (2R)-
📜2-(4-氯-2-甲基苯氧基)丙酸置于r(+)-Alpha-甲基苄胺体系中,化学反应生成高2-甲-4-氯丙酸
参考文献:Matell,Arkiv Foer Kemi,1953,Vol. 6,P. 365,370
标题:Matell,Arkiv Foer Kemi,1953,Vol. 6,P. 365,370

海关参考信息

专利信息


专利号:WO-2024256370-A1
优先权日:2023-06-13
标 题 :Synthesis of glufosinate using an amidase-based process
发明人:ZIMMERMANN GUNTHER; POTT MORITZ STEFAN
权利人:BASF SE
摘要:The present invention relates to a method of preparing glufosinate, comprising the steps of hydrolysing an N-carbamoyl glufosinate amide with an Amidase enzyme to form an N- carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N- carbamoyl amino acid compound.

专利号:US-2025120400-A1
优先权日:2021-12-10
标题:Synthesis of glufosinate using a hydantoinase-based process
发明人:DITRICH KLAUS; BREUER MICHAEL; POTT MORITZ STEFAN; ZIMMERMANN GUNTHER; SEEMAYER STEFAN
权利人:BASF SE
摘要:The present invention relates to a method of manufacturing glufosinate, comprising the steps of hydrolysing a hydantoin with a Hydantoinase enzyme to form a N-carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N-carbamoyl amino acid compound.

专利号:US-12286399-B2
优先权日:2023-01-29
标 题:Synthesis of (R)(+)-2-(4-chloro-2-methyl phenoxy)propanoic acid in high enantiomeric excess
发明人:PATEL-FRAMROZE BOMI
权利人:PATEL FRAMROZE BOMI
摘要:Provided herein is a process to react optical active chloroalkyl acid alkyl ester and substituted phenols in an aromatic solvent in the presence of a catalytic quantity of a quaternary ammonium salt to yield an optically active substituted phenoxy alkyl acid.

专利号:US-11352311-B1
优先权日:2021-06-27
标题:Single-step stereospecific synthesis of (S)-2-chloropropionic acid alkyl ester
发明人:PATEL-FRAMROZE BOMI
权利人:PATEL FRAMROZE BOMI
摘要:Provided herein is a process to react optically pure alkyl lactates with thionyl chloride in the presence of a catalytic amount of a lewis base ionic liquid to produce optically pure chloropropionic acid alkyl esters.

专利号:US-2021386068-A1
优先权日:2018-11-07
标题 :Compositions comprising pyridine carboxylate herbicides and very long chain fatty acid (vlcfa) synthesis inhibitor herbicides
发明人:KISTER JEREMY; SATCHIVI NORBERT M
权利人:CORTEVA AGRISCIENCE LLC
摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a VLCFA synthesis inhibitor herbicide. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof, and (b) a VLCFA synthesis inhibitor herbicide.

专利号:US-2021352899-A1
优先权日:2018-11-07
标题 :Compositions comprising pyridine carboxylate herbicides and fatty acid and lipid synthesis inhibitor herbicides
发明人:KISTER JEREMY; SATCHIVI NORBERT M
权利人:CORTEVA AGRISCIENCE LLC
摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof.

供应商参考报价(招募中)

品牌试剂参考报价(招募中)

📌 第三方产品分析报告

✅ COA系统入驻 | 共享模式

主要参考文献

[参考文献]: Ali Yuzir, Et Al. Impact Of The Herbicide (Rs)-Mcpp On An Anaerobic Membrane Bioreactor Performance Under Different Cod/nitrate Ratios. Bioresour Technol. 2012 Apr:109:31-7.
[参考文献]: Andreas Ranz, Et Al. Optimized Derivatization Of Acidic Herbicides With Trimethylsilyldiazomethane For Gc Analysis. J Sep Sci. 2008 Mar;31(4):746-52.
[参考文献]: Avik J Ghoshdastidar, Et Al. Treatment Of 2,4-D, Mecoprop, And Dicamba Using Membrane Bioreactor Technology. Environ Sci Pollut Res Int. 2013 Aug;20(8):5188-97.
[参考文献]: C Caballo, Et Al. Stereoselective Quantitation Of Mecoprop And Dichlorprop In Natural Waters By Supramolecular Solvent-Based Microextraction, Chiral Liquid Chromatography And Tandem Mass Spectrometry. Anal Chim Acta. 2013 Jan 25:761:102-8.
[参考文献]: Christiane Hoppe-Jones, Et Al. The Role Of Microbial Adaptation And Biodegradable Dissolved Organic Carbon On The Attenuation Of Trace Organic Chemicals During Groundwater Recharge. Sci Total Environ. 2012 Oct 15:437:137-44.

合成参考文献


摘要:Zdravookhranenie Belorussii. Public Health Service of White Russia., 23(11)(83), 1977
摘要:S109 | PARCEDC | List of 7074 potential endocrine disrupting compounds (EDCs) by PARC T4.2 | DOI:10.5281/zenodo.10944198
参考文献:10.1007/s00253-003-1511-4
摘要:Mller TA, Kohler H-E. Chirality of pollutants effects on metabolism and fate. Applied Microbiology and Biotechnology. 2004 Apr 01;64(3):300–16. doi: 10.1007/s00253-003-1511-4.
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