CAS: 107-74-4; Hydroxycitronellol

该化合物是一种分支二醇化合物,其特点是位于二甲基代八烷主骨1和7碳原子的两个氢氧基组,具有中度的水益性和反应性,适合特殊聚合物,表面活性剂和香味中间体的应用.其分支烷基链会增加有机基质的溶性,同时有助于低挥发性和增强稳定性.二醇的功能允许进一步的化学改变,如酯化或化醚化,使其得以用于自定义合成.该化合物的平衡性使其在精细化学和工业配方中成为多功能的中间体.

结构式图片

相似化合物

107-75-5 78-69-3 38376-28-2

欧盟法规

REACH注册ECHA物质C&L通报REACH预注册

上下游产品

ethanol R)-7-hydroxy-3,7-dimethyl-°Ctanal(R)-7-hydroxy-3,7-dimethyl-°Ctanal aluminum ethoxide (3R)-citronellol7-hydroxy-3,7-dimethyl-°Ctanal 2,6-dimethyl-hept-6-en-2-ol

合成工艺路线路线简述

    羟基香茅醛置于十二/十四烷基二甲基氧化胺,(1,4-Dimethyl-5,7-Diphenyl-1,2,3,4-Tetrahydro-6H-Cyclopenta[b]Pyrazin-6-One) Irontricarbonyl Complex3,Potassium Formate体系中,用 乙醇 用作溶剂,化学反应 24.0H,以99%的收率获得羟基香茅醇
    参考文献:铁催化的化学选择性氢化物转移反应
    标题:铁催化的化学选择性氢化物转移反应
    摘要:二氨基环戊二烯酮三羰基铁络合物已用于减少化学选择性的氢转移.该双官能铁络合物在温和条件下的各种反应中显示出广泛的适用性,例如醛在酮上的还原,各种官能化胺与官能化醛的还原烷基化以及α,β-不饱和酮还原为相应的饱和酮.通过这种实用的方法,已经以优异的收率分离了多种功能化的底物.
    Doi:10.1016/j.Tet.2021.132187

    海关参考信息

    专利信息


    专利号:US-4056573-A
    优先权日:1975-04-24
    标题:Synthesis of acyclic, terpene alcohols
    发明人:CLOSE RALPH E; DERFER JOHN M
    权利人:SCM CORP
    摘要:Shown is a process for the synthesis of acyclic, terpene alcohols, such as 3,7-dimethyloctan-1-o1 and 7-substituted hydroxy or ethoxy derivatives thereof, wherein 3-methylbut-1-yn or the 3-substituted hydroxy or ether derivative thereof is coupled with a C5 coupling reagent having the configuration X being a leaving group such as chloride, bromide, iodide, tosylate and mesylate; R being or OR', R' being a lower alkyl up to 5 carbon atoms, phenyl, substituted phenyl up to 10 carbon atoms, cycloalkyl or aralkyl up to 10 carbon atoms, followed by hydrogenation and saponification or deetherification.

    专利号:US-2010240923-A1
    优先权日:2007-11-29
    标题:Enzymatic synthesis of (meth)acrylic esters of hydroxy-functional aromas
    发明人:HAERING DIETMAR; WINTER GABI; SCHNELLER ARNOLD; AULENTA FRANCESCA
    权利人:BASF SE
    摘要:A process for preparing (meth)acrylic esters (F) of hydroxy-functional aromas (A), in which at least one hydroxy-functional aroma (A) in the presence of at least one enzyme (E) is esterified with (meth)acrylic acid (S), or transesterified with at least one (meth)acrylic ester (D), the reaction in the case of the transesterification being effected in the absence of solvents.

    专利号:US-4294727-A
    优先权日:1979-05-05
    标 题 :Perfume composition containing 4,5-dioxa-5-alkyl-tricyclo[7.2.1.0 2,8 ]dodec-10-enes and its use as an odorant
    发明人:CONRAD JENS; UPADEK HORST; BRUNS KLAUS
    权利人:HENKEL KGAA
    摘要:This invention is directed to perfume compositions comprising 4,6-dioxa-5-C1-C8-alkyl or C2-C8-alkenyl-tricyclo[7.2.1.02,8]dodec-10-enes, the use of said tricyclododecenes as an odorant, the synthesis of said tricyclododecenes, and novel tricyclododecenes.

    专利号:US-3062874-A
    优先权日:1958-09-15
    标题:Synthesis of mixed terpene esters from myrcene hydrohalides
    发明人:BAY PAUL G
    权利人:GLIDDEN CO

    专利号:CA-1084952-A
    优先权日:1977-09-06
    标 题 :Synthesis of acyclic, terpene alcohols

    专利号:US-8865624-B2
    优先权日:2010-09-01
    标题 :Inhibitor for tobacco axillary bud growth and method for inhibiting tobacco axillary bud growth
    发明人:TANAKA MOTOKI; TANAKA KEIJITSU; SHIBUYA TAKESHI; IKUTA EIJI; YOSHINAGA KOTARO; YAMAGUCHI YUKI
    权利人:TANAKA MOTOKI; TANAKA KEIJITSU; SHIBUYA TAKESHI; IKUTA EIJI; YOSHINAGA KOTARO; YAMAGUCHI YUKI; SDS BIOTECH CORP
    摘要:The present invention relates to an inhibitor for tobacco axillary bud growth, the inhibitor comprising, as an active ingredient, one or more kinds of very-long chain fatty acid synthesis inhibitors such as a chloroacetamide-based herbicide, fentrazamide, cafenstrole or indanofan; an inhibitor for tobacco axillary bud growth, the inhibitor comprising the aforesaid very-long chain fatty acid synthesis inhibitor together with clorthal-dimethyl or an aliphatic alcohol having 6 to 20 carbon atoms; and a method for inhibiting tobacco axillary bud growth which comprises applying the inhibitor for tobacco axillary bud growth. The inhibitor for tobacco axillary bud growth of the present invention shows sustained drug efficacy at a low concentration, induces neither chemical injury nor disease, and can contribute to the improvement in labor productivity.
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    合成参考文献


    摘要:Cormier, M.; Goddard, J.-P., Science of Synthesis, (2020) , 131.
    摘要:van der Puyl, V.; Shenvi, R. A., Science of Synthesis: Base-Metal Catalysis, (2023) 2, 637.
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