CAS: 2844-89-5; Dichloro(Cyclohexyl)Phosphane

上下游产品

Chlor-diethylamino-cyclohexyl-phosphan cyclohexane cyclohexylmagnesiumchloride cyclohexyl chloridechlorodicyclohexylphosphane dicyclohexylphosphonous acid 2-cyclohexyl-[1,3,2]dioxaphospholane 2-Thiazo-2-cyclohexyl-1.3.2-dioxaphospholan

📜氯代环己烷置于三氯化铝,三氯化磷体系中,化学反应生成环己二氯膦
参考文献:含有辅助2,2'-联吡啶或1,10-菲咯啉配体的四核磷酸铜(II)的合成,结构,磁性和核酸酶活性
标题:含有辅助2,2'-联吡啶或1,10-菲咯啉配体的四核磷酸铜(II)的合成,结构,磁性和核酸酶活性
摘要:的反应 环己基膦酸(c 6 H 11 Po 3 H 2),无水氯化铜2 和 2,2'-联吡啶 (py) 在......的存在下 三乙胺 跟一个 复分解反应用kno 3,得到[铜4(μ-Cl)的2(μ 3-C 6 ħ 11 Po 3)2(联吡啶)4 ](no 3)2(1).在涉及cu(oac)2 .h 2 O的类似反应中,络合物[cu 4(µ-Ch 3 Coo)2(µ 3-C 6 H 11 Po 3)2(2,2'-Bpy)4 ] (ch 3 Coo)2(2)已被隔离.涉及cu(no 3)2 .3H 2 O的三组分反应,环己基膦酸 和 2,2'-联吡啶 在......的存在下 三乙胺 提供了四核 部件[铜4(μ-Oh)(μ 3-C 6 ħ 11 Po 3)2(2,2'-联吡啶)4(h 2 O)2 ](no 3)3(3).更换2,2'-联吡啶 和 1,10-菲咯啉 (苯酚)在上述反应导致[铜4(μ-Oh)(μ
Doi:10.1039/b712876B

专利信息

专利号:US-4096182-A
优先权日:1976-03-19
标 题:Process for the simultaneous preparation of 2,5-dioxo-1,2-oxa-phospholanes and β-halogenpropionic acid halide
发明人：RUPP WALTER; FINKE MANFRED
权利人:HOECHST AG
摘要:2,5-Dioxo-1,2-oxa-phospholanes of the formula (I) ##STR1## wherein R 1 is an organic radical and R 2 and R 3 each also represents an organic radical or hydrogen, are prepared by reacting 2-haloformylethyl-phosphinic acid halides of the formula (II) ##STR2## wherein R 1 , R 2 and R 3 are defined as in formula (I) and X means Cl or Br, preferably Cl, with an approximatey equimolar quantity of acrylic acid. The compounds (II) may also be produced in the reaction batch and in situ by reacting about equimolar quantities of a dihalophosphine of the formula (III) ##STR3## with an α,β-unsaturated acid (IV) n n R.sup.4 -- OH (IV) n n In the formulae (III) and (IV) R 1 , R 2 , R 3 and X are defined as indicated above. n In the reaction there is formed, in addition to the compounds (I), practically exclusively β-halopropionic acid and no free hydrogen halide. n The phospholanes (I) are valuable flame retarding agents for plastics, intermediates, for example, for the synthesis of biocidals etc.

专利号:CN-117603071-A
优先权日:2023-10-25
标 题:Organocatalytic C-H functionalization of alkenes for selective synthesis of axially chiral 1,3-diene derivatives