CAS: 1610-17-9; Atraton

该化合物是主要用作除草剂的一种化学化合物,属于称为三氮的化合物类别,其特点是含有三氮原子的六环,已知其有效控制了农业环境中的各种杂草,特别是玉米和高梁等作物中的杂草.通过抑制目标植物中的光合作用,从而最终导致其死亡的复合工作.Atraton通常在出现前或出现后应用,视具体应用和目标杂草而定.水中的溶液和有机溶剂允许采用多种应用方法.然而,与许多除草剂一样,Atraton提出了有关其土壤持久性的环境关切及其对非目标物种的潜在影响.适当的处理和应用做法对于尽量减少其使用所带来的风险至关重要.关于任何化学物质,遵守安全准则和条例对于确保效率和环境保护至关重要.

结构式图片

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

methanol 6-chloro-N-ethyl-N'-isopropyl-1,3,5-triazine-2,4-diamineHydroxyatrazine Desisopropylatraton

合成工艺路线路线简述

  • 合成目标产物 Atraton 主要起始原料 Methanol And Atrazine
  • (文献来源)合成步骤主要原料 Methanol 和 Atrazine
📜甲醇,阿特拉津置于polymer (2-Sulfoethyl Methacrylate-Methacrylic Acid,体系中,用 氯仿 用作溶剂,化学反应 24.0H,反应生成阿特拉通
参考文献:Atrazine Transformation Using Synthetic Enzymes Prepared By Molecular Imprinting
标题:Atrazine Transformation Using Synthetic Enzymes Prepared By Molecular Imprinting
摘要:利用甲基丙烯酸和2-磺基乙基甲基丙烯酸酯的组合制备了阿特拉津印迹合成聚合物,该组合可将阿特拉津和其他6-氯三嗪类除草剂结合并转化为毒性较低的化合物.在含甲醇的溶剂中,三嗪类化合物6位上的氯被聚合物转化为甲氧基,其中印迹效应增强了催化活性.在存在结构相关的粘合剂氨丙啶的情况下,观测到了阿特拉津甲醇化的竞争性抑制作用,这表明催化反应在分子印迹过程产生的结合位点中进行.
Doi:10.1039/b407002J

海关参考信息

专利信息


专利号:US-9458471-B2
优先权日:2006-11-03
标题 :Engineered cellular pathways for programmed autoregulation of differentiation
发明人:WEISS RON; LEMISCHKA IHOR; PURNICK PRISCILLA; SCHANIEL CHRISTOPH; MILLER MILES; GUYE PATRICK
权利人:UNIV PRINCETON
摘要:The present invention provides compositions and methods for programming mammalian cells to perform desired functions. In particular, the present invention provides compositions and methods for programming stem cells to differentiate into a desired cell type. A quorum sensing systems that regulates the expression of cell fate regulators is introduced into mammalian host cells, such as stem cells. The quorum sensing systems generally comprises vectors that express the components of a bacterial quorum sensing pathway, including proteins which catalyze the synthesis of an autoinducer and a gene encoding a regulatory partner of the autoinducer, and vectors in which genes encoding cell fate regulators are operably linked to a promoter induced by the autoinducer/regulatory partner complex. The system can also comprise vectors in which genes encoding additional cell fate regulators are operably linked to a promoter that is induced by a factor synthesized in response to a first stage of differentiation, so that a second stage of differentiation is triggered.

专利号:WO-2024256370-A1
优先权日:2023-06-13
标 题 :Synthesis of glufosinate using an amidase-based process
发明人:ZIMMERMANN GUNTHER; POTT MORITZ STEFAN
权利人:BASF SE
摘要:The present invention relates to a method of preparing glufosinate, comprising the steps of hydrolysing an N-carbamoyl glufosinate amide with an Amidase enzyme to form an N- carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N- carbamoyl amino acid compound.

专利号:US-2022145335-A1
优先权日:2022-01-27
标 题 :Bio-catalyzed Synthesis of Potent Anti-inflammatory Agents from Medroxyprogesterone Acetate
发明人:CHOUDHARY MUHAMMAD IQBAL; BANO SAIRA; WAHAB ATIA-TUL; UL-HAQ ZAHEER; YOUSUF SAMMER; JABEEN ALMAS; RAHMAN ATTA-UR
权利人:CHOUDHARY MUHAMMAD IQBAL; BANO SAIRA; WAHAB ATIA TUL; UL HAQ ZAHEER; YOUSUF SAMMER; JABEEN ALMAS; RAHMAN ATTA UR
摘要:Biotransformation of medroxyprogesterone acetate (MPA) (1) with Cunninghamella blakesleeana (ATCC 8688) yielded five new analogues, i.e. 17α-acetoxy-6α-methylpregn-4-ene-3,11,20-trione (2), 17α-acetoxy-15β-hydroxy-6α-methylpregn-4-ene-3,11,20-trione (3), 17α-acetoxy-6β-hydroxy-6α-methylpregn-4-ene-3,11,20-trione (4), 17α-acetoxy-11β,15β-dihydroxy-6α-methylpregn-4-ene-3,20-dione (5), and 17α-acetoxy-6β,11β-dihydroxy-6α-methylpregn-4-ene-3,20-dione (6). In T-cell proliferation assay, metabolites 2, and 5 were found to be potent inhibitors with IC50<0.5 μM, metabolite 6 showed a significant activity with IC50=8.64±0.02 μM, while metabolites 3 and 4 were found to be moderately active with IC50=41.59±8.14, and 40.14±0.12 μM, as compared to substrate 1 (IC50=6.48±5.18 μM) and standard prednisolone (IC50=9.75±0.03 μM) in in vitro assay. To establish the binding mode of medroxyprogesterone acetate (MPA) and the bio-transformed derivatives, molecular docking simulations were carried out using Vina.

专利号:US-2025120400-A1
优先权日:2021-12-10
标题:Synthesis of glufosinate using a hydantoinase-based process
发明人:DITRICH KLAUS; BREUER MICHAEL; POTT MORITZ STEFAN; ZIMMERMANN GUNTHER; SEEMAYER STEFAN
权利人:BASF SE
摘要:The present invention relates to a method of manufacturing glufosinate, comprising the steps of hydrolysing a hydantoin with a Hydantoinase enzyme to form a N-carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N-carbamoyl amino acid compound.

专利号:US-2021386068-A1
优先权日:2018-11-07
标题 :Compositions comprising pyridine carboxylate herbicides and very long chain fatty acid (vlcfa) synthesis inhibitor herbicides
发明人:KISTER JEREMY; SATCHIVI NORBERT M
权利人:CORTEVA AGRISCIENCE LLC
摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a VLCFA synthesis inhibitor herbicide. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof, and (b) a VLCFA synthesis inhibitor herbicide.

专利号:US-2021352899-A1
优先权日:2018-11-07
标题 :Compositions comprising pyridine carboxylate herbicides and fatty acid and lipid synthesis inhibitor herbicides
发明人:KISTER JEREMY; SATCHIVI NORBERT M
权利人:CORTEVA AGRISCIENCE LLC
摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof.

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品牌试剂参考报价(招募中)

📌 第三方产品分析报告

✅ COA系统入驻 | 共享模式

主要参考文献


1: Labu S, Subramanian S, Cheseto X, Akite P, Kasangaki P, Chemurot M, Tanga CM, Salifu D, Egonyu JP. Agrochemical contaminants in six species of edible insects from Uganda and Kenya. Curr Res Insect Sci. 2022 Nov 1;2:100049. doi: 10.1016/j.cris.2022.100049.
2: Guo L, Xu X, Zhao J, Hu S, Xu L, Kuang H, Xu C. Multiple detection of 15 triazine herbicides by gold nanoparticle based-paper sensor. Nano Res. 2022;15(6):5483-5491. doi: 10.1007/s12274-022-4164-2. Epub 2022 Mar 15.
3: Xie Y, Wang M, Chen X, Wang S, Han D, Han Y, Yan H. 3-Aminophenol-glyoxylic acid resin for the determination of triazine herbicides in tomatoes. Anal Chim Acta. 2019 Jul 11;1061:122-133. doi: 10.1016/j.aca.2019.01.062. Epub 2019 Feb 10. 6(26):16943-16954. doi: 10.1021/acsomega.1c01877.

合成参考文献


参考文献:10.1186/1471-2148-11-216
摘要:Markolf M, Brameier M, Kappeler PM. On species delimitation: Yet another lemur species or just genetic variation BMC Ecology and Evolution. 2011 Jul 21;11(1):216. doi: 10.1186/1471-2148-11-216.
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