CAS: 880-36-4; 2-N-Octylthiophene
该化合物是一种有机化合物,属于含有硫磺的硫苯类,是五人组成的芳香热循环体,其特点是环球侧链,它能增强有机溶剂的溶性,有助于其作为半导体材料的特性;该化合物的特点是其相对较高的热稳定性和良好的导电性,使它适合用于有机电子产品,如有机现场有效晶体管和有机太阳能电池. 2-有机环硫苯在紫外光谱中展示了一种不同的吸收频谱,受到其同源结构的影响,使其能够有效地参与电子过渡.此外,该化合物有一个中度熔点,通常根据温度作为液体或固体进行处理.其合成往往涉及硫苯衍生物的聚合,并且由于在电子设备中形成稳定的胶片和界面的能力而受到重视.在处理该化合物时,应当采取安全防范措施,因为许多有机化学品都具有潜在的健康危险.
物理性质
MSDS等安全信息
上下游产品
thiophene 1-bromo-°Ctane 2-Iodothiophene 8-[2]thienyl-°Ctan-2-one 5-°Ctyl-2-thiophenecarboxylic acid 2-bromo-5-°Ctan-1-yl-thiophene 4,4,5,5-tetramethyl-2-(5-°Ctylthiophen-2-yl)-1,3,2-dioxaborolane dithieno[3, 4-b:3',4'-d]thiophene合成工艺路线路线简述
- 629-27-6 = 880-36-4
反应条件:1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran; 15 Min,-78 °C1.2 Overnight,-80 °C -> Rt
标题:Synthesis Of Soluble Oligothiophenes Bearing Cyano Groups,Their Optical And Electrochemical Properties
作者:Balandier,Jean-Yves; Et Al
参考文献:Tetrahedron 日期:2010 卷标:66(49) 页码:9560-9572]
111-83-1 = 880-36-4
反应条件:1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran,Hexane; -78 °C; 50 Min,-78 °C1.2 -78 °C -> Rt; 16 H,Rt
标题:Photochromism Of 1,2-Bis(2-N-Alkyl-5-Formyl-3-Thienyl)Perfluorocyclopentene Derivatives
作者:Pu,Shouzhi; Et Al
参考文献:Journal Of Molecular Structure 日期:2009 卷标:921(1-3) 页码:89-100]
3248-78-0 = 880-36-4 [标题:Reaction Conditions
标题:Product Subclass 39: Tetraaryl- And Tetraalkylborates And Related Organometallic Compounds
作者:Kaufmann,D. E.; Et Al
参考文献:Science Of Synthesis 日期:2004 卷标:6 页码:1217-1233]
2786-07-4 + 3248-78-0 = 880-36-4
反应条件:1.1 Reagents: Iodine
标题:2-Alkylation Reactions Of Thiophene And 1-Methylpyrrole With Trialkylboranes
作者:Sotoyama,Toshiki; Et Al
参考文献:Bulletin Of The Chemical Society Of Japan 日期:1979 卷标:52(6) 页码:1865-6]
69340-26-7 + 693-04-9 = 880-36-4
反应条件:1.1 Catalysts: 1,3-Butadiene,Dicarbonylchloro(η5-2,4-Cyclopentadien-1-Yl)Iron Solvents: Tetrahydrofuran; -78 °C; 2 H,0 °C; 22 H,Rt1.2 Reagents: Ammonium Chloride Solvents: Water
标题:Cross-Coupling Reaction Of Alkyl Halides With Alkyl Grignard Reagents Catalyzed By Cp-Iron Complexes In The Presence Of 1,3-Butadiene
作者:Iwasaki,Takanori; Et Al
参考文献:Chemistry Letters 日期:2018 卷标:47(6) 页码:763-766]
14403-26-0 + 1160755-78-1 = 880-36-4
反应条件:1.1 Reagents: 1,2-Dibromoethane Catalysts: Iron(Iii) Acetylacetonate Solvents: Tetrahydrofuran; Rt -> 0 °C; 0 °C; 0 °C -> Rt; 3 H,Rt1.2 Reagents: Hydrochloric Acid Solvents: Water; Rt
标题:Iron-Catalyzed Oxidative Heterocoupling Between Aliphatic And Aromatic Organozinc Reagents: A Novel Pathway For Functionalized Aryl-Alkyl Cross-Coupling Reactions
作者:Cahiez,Gerard; Et Al
参考文献:Angewandte Chemie 日期:2009 卷标:48(16) 页码:2969-2972]
111-83-1 = 880-36-4
反应条件:1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran,Hexane; -20 °C -> 10 °C; 10 Min,10 °C; 10 °C -> Rt1.2 Rt -> 50 °C; 30 Min,50 °C
标题:The Synthesis,Structural Features And Thermal Behavior Of Thiophene-Containing Dithiocarboxylate Complexes Of Zinc(Ii)
作者:Thomas,Mary S.; Et Al
参考文献:Polyhedron 日期:2006 卷标:25(18) 页码:3562-3568]
111-83-1 = 880-36-4
反应条件:1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran,Hexane; 0 °C; 0 °C -> 20 °C1.2 4 H,Reflux
标题:Bent-Core Mesogens With Thiophene Units
作者:Geese,Karina; Et Al
参考文献:Journal Of Materials Chemistry 日期:2010 卷标:20(43) 页码:9658-9665]
1003-09-4 + 111-83-1 = 880-36-4
反应条件:1.1 Reagents: Magnesium Solvents: Tetrahydrofuran; Reflux; 1 H,Reflux1.2 Catalysts: Dichloro[1,1′-(1,3-Propanediyl)Bis[1,1-Diphenylphosphine-Kp]]Nickel Solvents: Tetrahydrofuran; Overnight,Reflux1.3 Reagents: Hydrochloric Acid Solvents: Water
标题:Micro Continuous Flow-Through Synthesis Of Triangular Silver Nanoprisms And Their Incorporation In Complexly Composed Polymer Microparticles
作者:Knauer,Andrea; Et Al
参考文献:Chemical Engineering Journal (Amsterdam 日期:2013 卷标:227 页码:191-197]
1003-09-4 + 111-83-1 = 880-36-4
反应条件:1.1 Reagents: Butyllithium1.2 1 H,-78 °C
标题:Suppressing The Surface Recombination And Tuning The Open-Circuit Voltage Of Polymer/fullerene Solar Cells By Implementing An Aggregative Ternary Compound
作者:Galli,Diana; Et Al
参考文献:Acs Applied Materials & Interfaces 日期:2018 卷标:10(34) 页码:28803-28811]
629-27-6 + 5713-61-1 = 880-36-4
反应条件:1.1 Catalysts: Cobalt Chloride (Cocl2),Trans-(-)-N,N,N′,N′-Tetramethyl-1,2-Cyclohexanediamine Solvents: Tetrahydrofuran; 15 Min,25 °C
标题:Cobalt(Diamine)-Catalyzed Cross-Coupling Reaction Of Alkyl Halides With Arylmagnesium Reagents: Stereoselective Constructions Of Arylated Asymmetric Carbons And Application To Total Synthesis Of Ah13205
作者:Ohmiya,Hirohisa; Et Al
参考文献:Journal Of The American Chemical Society 日期:2006 卷标:128(6) 页码:1886-1889]
1003-09-4 + 3386-35-4 = 880-36-4
反应条件:1.1 Reagents: Magnesate(1-),Dichloro(1-Methylethyl)-,Lithium (1:1) Solvents: Tetrahydrofuran; 20 Min,-40 °C1.2 Reagents: Zinc Iodide,Magnesium,Chloro[(Trimethylsilyl)Methyl]- Solvents: Tetrahydrofuran; -40 °C; 1 H,< 0.1 Torr1.3 Reagents: N,N,N′,N′-Tetramethylethylenediamine Catalysts: Iron Chloride (Fecl3) Solvents: Tetrahydrofuran; 0 °C; 12 H,40 °C1.4 Reagents: Ammonium Chloride Solvents: Water
标题:Iron-Catalyzed Cross-Coupling Of Alkyl Sulfonates With Arylzinc Reagents
作者:Ito,Shingo; Et Al
参考文献:Organic Letters 日期:2009 卷标:11(19) 页码:4306-4309]
30711-41-2 = 880-36-4
反应条件:1.1 Reagents: Hydrazine Hydrate (1:1) Solvents: Diethylene Glycol,Water
标题:Further Studies In The Synthesis Of Long Chain Hydroxy Acids
作者:Miller,Kenneth E.; Et Al
参考文献:Journal Of Organic Chemistry 日期:1961 卷标:26 页码:5217-19]
30711-41-2 = 880-36-4
反应条件:1.1 Reagents: Mercury,Zinc,Hydrochloric Acid
标题:Some Derivatives Of 2-Acylthiophenes
作者:Campaigne,E.; Et Al
参考文献:Journal Of The American Chemical Society 日期:1948 卷标:70 页码:391-2]
3248-78-0 = 880-36-4
反应条件:1.1 Reagents: Butyllithium,N,N,N′,N′-Tetramethylethylenediamine,Iodine,Hydrogen Peroxide Solvents: Diethyl Ether,Water
标题:Formation Of Carbon-Carbon And Carbon-Heteroatom Bonds Via Organoboranes And Organoborates
作者:Negishi,Ei-Ichi; Et Al
参考文献:Organic Reactions (Hoboken 日期:1985 卷标:33]
69340-26-7 + 693-04-9 = 880-36-4
反应条件:1.1 Catalysts: Cupric Chloride Solvents: Tetrahydrofuran; Rt; Rt -> -78 °C1.2 Reagents: 1,3-Butadiene Solvents: Tetrahydrofuran; -78 °C; 48 H,40 °C1.3 Reagents: Hydrochloric Acid Solvents: Water
标题:Copper-Catalyzed Alkyl-Alkyl Cross-Coupling Reactions Using Hydrocarbon Additives: Efficiency Of Catalyst And Roles Of Additives
作者:Iwasaki,Takanori; Et Al
参考文献:Journal Of Organic Chemistry 日期:2014 卷标:79(18) 页码:8522-8532]
111-83-1 + 5713-61-1 = 880-36-4
反应条件:1.1 Catalysts: 1,3-Bis(Diphenylphosphino)Propane,Cobalt Chloride (Cocl2) Solvents: Tetrahydrofuran; 0.5 H,-15 °C1.2 Reagents: Ammonium Chloride Solvents: Water
标题:Cobalt-Catalyzed Cross-Coupling Reactions Of Alkyl Halides With Aryl Grignard Reagents And Their Application To Sequential Radical Cyclization/cross-Coupling Reactions
作者:Ohmiya,Hirohisa; Et Al
参考文献:Tetrahedron 日期:2006 卷标:62(10) 页码:2207-2213]
193978-23-3 + 111-83-1 = 880-36-4
反应条件:1.1 Reagents: Ethanamine,N-Methyl-,Lithium Salt Catalysts: 2413474-02-7 (Thf-Deficient (~ 0.75)) Solvents: Benzene; Rt -> 50 °C; 24 H,50 °C1.2 Reagents: Ammonium Chloride Solvents: Water
标题:Rational Design Of An Iron-Based Catalyst For Suzuki-Miyaura Cross-Couplings Involving Heteroaromatic Boronic Esters And Tertiary Alkyl Electrophiles
作者:Crockett,Michael P.; Et Al
参考文献:Angewandte Chemie 日期:2020 卷标:59(13) 页码:5392-5397]
= 880-36-4
反应条件:1.1 Reagents: Titanium Tetrachloride Solvents: Dichloromethane1.2 Reagents: Potassium Hydroxide,Hydrazine Hydrate (1:1) Solvents: Diethylene Glycol; Reflux
标题:Exploring The Mesomorphic Potential Of 2,4-Disubstituted Thiophenes: A Structure-Property Study
作者:Matharu,A. S.; Et Al
参考文献:Liquid Crystals 日期:2011 卷标:38(2) 页码:207-232
📜2-辛酰基噻吩置于hydrazine Hydrate,Potassium Hydroxide体系中,用 辛醇 作为反应溶剂,化学反应 6.0H,以7.5 G的收率获得产物2-正辛基噻吩
参考文献:高性能有机场效应晶体管的1,8取代的ene衍生物
标题:高性能有机场效应晶体管的1,8取代的ene衍生物
摘要:The衍生物作为有机半导体的应用已有许多报道,但1,8取代的pyr半导体发展较差.合成了两个p型1,8-取代的pyr衍生物,它们由a核,噻吩或联噻吩臂和封端的辛基链组成.这些结构不是完全对称的,并且core核与相邻的噻吩单元之间的二面角具有大约两个度的差.这些材料的场效应性能已在各种介电表面上进行了测试.在sio 2(ps处理的sio 2)上具有旋涂聚苯乙烯层的两种材料的性能均优于在sio 2上具有十八烷基三氯硅烷自组装单层的材料的性能(ots处理的sio 2),主要归因于低漏电和高电容ps膜上存在大晶粒.含噻吩的化合物在ps处理的sio 2上的空穴迁移率高达0.18 Cm 2 V-1 S-1,这是含双噻吩化合物的空穴迁移率的45倍,这归因于较低的位阻,较高的结晶度和晶粒大.
DOI:10.1002/asia.201801408
海关参考信息
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- 详情请参考：📖 海关编码查询和海关进出口税则
专利信息
专利号:WO-2012163976-A1
优先权日:2011-06-03
标题:Continuous process for the synthesis of ternary or quaternary semiconducting nanoparticles based on ib, iiia, via elements of the periodic classification
发明人：RAUSCHER FRANK; FU MIN; MLECZKO LESLAW; HOHEISEL WERNER
权利人:BAYER IP GMBH; RAUSCHER FRANK; FU MIN; MLECZKO LESLAW; HOHEISEL WERNER
摘要:A process for the continuous production of ternary or quaternary semiconducting nanoparticles based on IB, IIIA, VIA elements of the periodic classification, in particular low-toxic AglnS2; and CuInS2 in the liquid phase is described. A uniform size of semiconducting nanoparticles is obtained in a size range from 1 nm to 20 nm, showing chalcopyrite or wurzite crystal structure. The size and crystal structure of the semiconducting nanoparticle can be controlled by adjusting reaction parameters in particular concentration, temperature, flow and selected ligands.
专利号:US-6432294-B1
优先权日:2000-12-14
标题 :Electrochemical activation of organic disulfides for electrophilic substitution
发明人：GLASS RICHARD S; JOUIKOV VIATCHESLAV V; BOJKOVA NINA V
权利人:UNIV ARIZONA
摘要:Electrochemical oxidation of organic disulfides is conducted in an electrolytic solution containing an arene (e.g., anthracene, acenaphthylene, phenanthrene), and depending on the arene used and/or the product desired, an organic base (e.g., pyridine) to effect the synthesis of organothiated products in good yields.
专利号:US-11274247-B2
优先权日:2017-02-02
标题:Methods for the synthesis of transition metal dichalcogenide (TMDC) nanoparticles
发明人：DANIELS STEVEN
权利人:NANOCO TECHNOLOGIES LTD
摘要:Methods of synthesizing transition metal dichalcogenide nanoparticles include forming a metal-amine complex, combining the metal-amine complex with a chalcogen source in at least one solvent to form a solution, heating the solution to a first temperature for a first period of time, and heating the solution to a second temperature that is higher than the first temperature for a second period of time.
专利号:WO-2019217116-A1
优先权日:2018-05-06
标 题 :Method for solution-phase peptide synthesis
发明人：SEIFERT COLE
权利人:GAP PEPTIDES LLC
摘要:The present disclosure relates in general to the field of peptide synthesis. In general, the system provides for solution-phase peptide synthesis methods in organic solvents, some of which are immiscible with aqueous solutions, alkane solvents, or both, that allow for purification with minimal chromatography, recrystallization, or polymer supports, and allows for high overall yield and purity. The disclosed systems and methods support a wide variety of scenarios and include various products and services.
专利号:US-12024537-B2
优先权日:2018-05-31
标题 :Compositions and methods for chemical synthesis
发明人：SEIFERT COLE
权利人:SEDERMA SA
摘要:The disclosure relates to chemical compositions that can include anchor molecules for chemical synthesis. GAP anchor molecules can include GAP constituents, linker constituents, and spacer constituents. Anchor molecules can be used to synthetically manufacture peptides. A novel method of solution-phase peptide synthesis is also disclosed that utilizes novel group-assisted purification protecting groups to facilitate efficient, scalable chemistry to synthetically manufacture peptides.
专利号:US-6207838-B1
优先权日:1999-04-30
标 题 :Electrochemically generated organothiating reagents and their use
发明人：GLASS RICHARD S; JOUIKOV VIATCHESLAV V
权利人:UNIV ARIZONA
摘要:Electrolysis of organic disulfides in liquid sulfur dioxide is used to obtain organothiating agents, which can then be reacted with appropriate substrates to effect the synthesis of organothioaromatic compounds efficiently and in high yields. With appropriate phenolic compounds, regioselective substitution occurs in which para substitution greatly exceeds ortho substitution.
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
合成参考文献
摘要:Schatz, J.; Seler, M., Science of Synthesis Knowledge Updates, (2011) 2, 394.
📝 需求与反馈
尽可能描述清楚需求与问题信息
