📜以70%的收率获得产物氟化钽(V) 参考文献:Hahn,O.; Puetter,K. E.,Zeitschrift Fur Anorganische Und Allgemeine Chemie 标题:Hahn,O.; Puetter,K. E.,Zeitschrift Fur Anorganische Und Allgemeine Chemie
专利信息
专利号:US-8115002-B2 优先权日:2006-09-20 标 题:Preparation of substituted morphinan-6-ones and salts and intermediates thereof 发明人:WANG PETER X; MOSER FRANK W; CANTRELL GARY L; GROTE CHRISTOPHER W 权利人:WANG PETER X; MOSER FRANK W; CANTRELL GARY L; GROTE CHRISTOPHER W; MALLINCKRODT LLC 摘要:The present invention is directed to processes for the synthesis of morphinan-6-ones and salts, intermediates, and analogs thereof.
专利号:US-5068472-A 优先权日:1989-12-19 标 题 :Multistep synthesis of hexafluoropropylene 发明人:WEBSTER JAMES L; TROFIMENKO SWIATOSLAW; RESNICK PAUL R; BRUHNKE DOUGLAS W; LEROU JAN J; MANOGUE WILLIAM H; MANZER LEO E; MCCANN ELREY L; SWEARINGEN STEVEN H; TRAINHAM JAMES A; BONIFAZ CRISTOBAL 权利人:DU PONT 摘要:The present invention relates to multistep syntheses of hexafluoropropylene from hexachloropropylene. In all these syntheses the first step is a fluorination of the starting material; later steps convert the initial products to CF 3 --CFCl--CF 3 , which is dehalogenated to the desired product.
专利号:US-5026944-A 优先权日:1989-12-20 标题:Synthesis of isobutene from methane and acetylene 发明人:ALLENGER VINCENZA; PANDEY RAJ N; YARLAGADDA PRASAD 权利人:CA MINISTER ENERGY 摘要:A process is described in which methane is reacted with acetylene in the presence of a solid acid catalyst containing fluoride to produce isobutene in high yields. The process may take place at room temperature or lower and atmospheric pressure. The conversion of acetylene typically approaches 100% and the methane conversion has been found to surpass stoichiometric requirements.
专利号:US-7838677-B2 优先权日:2005-03-10 标 题:Processes for preparing morphinans and intermediates thereof 发明人:WANG PETER XIANQI; MOSER FRANK W; CANTRELL GARY L; BAO JIAN 权利人:MALLINCKRODT INC 摘要:The present invention is directed to processes for the synthesis of morphinans. In particular, a process for cyclizing a β,γ-bicyclic ketone compound to form a nordihydrothebainone product using the Grewe cyclization reaction is improved by forming a reaction mixture comprising a β,γ-bicyclic ketone compound, a cyclizing acid and a water scavenging cyclization additive. In one embodiment, the Grewe transformation occurs in the presence of an acid anhydride as the cyclization additive. Further, the present invention is directed to processes for converting α,β-bicyclic ketone compounds (e.g., by-products of the Grewe cyclization reaction) to β,γ-bicyclic ketone compounds, wherein the β,γ-bicyclic ketone compounds may be recovered to further undergo Grewe cyclization and form the nordihydrothebainone product.
专利号:EP-0434408-A1 优先权日:1989-12-19 标题 :Multistep synthesis of hexafluoropropylene
专利号:EP-0434408-B1 优先权日:1989-12-19 标 题 :Multistep synthesis of hexafluoropropylene
摘要:Merck Index - O'Neil MJ, Heckelman PE, Dobbelaar PH, Roman KJ (eds). The Merck Index, An Encyclopedia of Chemicals, Drugs, and Biologicals, 15th Ed. Cambridge, UK: The Royal Society of Chemistry, 2013. 摘要:ACGIH - Documentation of the TLVs and BEIs, 7th Ed. Cincinnati: ACGIH Worldwide, 2020.