CAS: 7212-44-4; 3,7,11-Trimethyldodeca-1,6,10-Trien-3-Ol

该化合物是一种以昆虫驱虫特性和温和气味而闻名的自然产生的除虫杆酒精,它实际上在不留下明显残留物的情况下驱蚊虫和滴虫,使其成为个人护理产品和虫害防治配方中具有吸引力的添加剂,其天然来源和生物降解性也对其吸引力有帮助.

结构式图片

相似化合物

40716-66-3 68931-30-6 78-70-6

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上下游产品

CAS号4602-84-0 法呢醇 | CAS号2387-68-0 3,7,11-trimethy... | CAS号689-67-8 6,10-二甲基-5,9-十一... | CAS号60-29-7 乙醚 | CAS号4602-84-0 法呢醇 | CAS号515-69-5 红没药醇 | CAS号17627-44-0 alpha-bisabolene | CAS号495-62-5 4-(1,5-二甲基-4-己烯... | CAS号125037-13-0 3,7,11-trimethy... | CAS号16106-95-9 2Z,6Z-Farnesol | CAS号3879-60-5 (E,Z)-3,7,11-Tr... | CAS号3790-71-4 顺式,反式-金合欢醇 | CAS号106-28-5 金合欢醇 | CAS号18794-84-8 (E)-β-金合欢烯

合成工艺路线路线简述

    金合欢醇置于bis(Acetylacetonate)Oxovanadium,Bisabolol体系中,174.0~176.0 °C,2.5 Kpa 条件下,反应 7.0H,反应生成 橙花叔醇
    参考文献:Method For Converting Farnesol To Nerolidol In The Presence Of Alpha-Bisabolol
    标题:Method For Converting Farnesol To Nerolidol In The Presence Of Alpha-Bisabolol
    摘要:在α-比沙烯醇存在的情况下,将芬尼醇转化为内洛利醇的方法包括提供或准备α-比沙烯醇,芬尼醇和一种或多种催化剂的混合物,以在α-比沙烯醇存在的情况下选择性异构化芬尼醇为内洛利醇,并将至少一部分芬尼醇转化为内洛利醇.

    海关参考信息

    专利信息


    专利号:US-9943544-B2
    优先权日:2015-03-18
    标 题:Process for bio synthesis of nano arsenic trioxide and its use in treatment of diseases including cancer
    发明人:BENDALE YOGESH NARAYAN; BENDALE VINEETA YOGESH
    权利人:BENDALE YOGESH NARAYAN; BENDALE VINEETA YOGESH
    摘要:The present invention is a process for bio synthesis of nano arsenic trioxide defined by its low toxicity, higher bio availability and nano particle size with the aid of buttermilk, goat urine, dolichos biflorous and other plant materials such as ginger, momordica charantia and musa paradisiaca . The invention is carried out in different steps involving purification of crude form of arsenic trioxide by boiling it with buttermilk, goat urine and extract of dolichos biflorous in subsequent steps, followed by the trituration of the bio purified arsenic trioxide with extracts of ginger and momordica charantia in subsequent steps and heating of the dry product obtained after trituration with musa paradisiaca resulting in the production of novel nano arsenic trioxide. The product is effective in the treatment of various diseases including different types of cancer in animals and humans. The product obtained through the process is less toxic with higher bio availability.

    专利号:US-4061660-A
    优先权日:1975-09-29
    标 题 :Process for synthesis of coenzyme Q compounds
    发明人:KIJIMA SHIZUMASA; YAMATSU ISAO; MINAMI NORIO; INAI YUICHI
    权利人:EISAI CO LTD
    摘要:A process for the synthesis of 2,3-dimethoxy-5-methyl-6-substituted-1,4-benzoquinones having the formula: ##STR1## wherein R is ##STR2## in which n is an integer of 0 to 9, and A and B are hydrogens or A--B is a direct valence bond between the carbon atoms to which they are attached, n Characterized by reacting 2-methyl-4,5,6-trimethoxyphenol with an aryl boronic acid, a lower alkyl boronic acid or an acid anhydride thereof to obtain a 2-methyl-4,5,6-trimethoxyphenol ester of boric acid, reacting the resulting ester with an n-prenol or iso-prenol having the formula: ##STR3## wherein R is as defined above, OR A REACTIVE DERIVATIVE OF SAID N- OR ISO-PRENOL, IN THE PRESENCE OF A SILICA-ALUMINA COMPOUND, TO OBTAIN A 2-METHYL-3-SUBSTITUTED-4,5,6-TRIMETHOXYPHENOL ESTER OF BORIC ACID, AND HYDROLYZING THE THUS-OBTAINED ESTER AND TREATING THE RESULTING 2-METHYL-3-SUBSTITUTED-4,5,6-TRIMETHOXYPHENOL HAVING THE FORMULA: ##STR4## wherein R is as defined above, WITH AN OXIDIZING AGENT.

    专利号:WO-2024042405-A1
    优先权日:2022-08-26
    标 题:Compositions and methods for the synthesis of bio-based polymers
    发明人:OLIVEIRA ANA; CAPÊTO ANA PAULA; PINTADO MANUELA
    权利人:AMYRIS BIO PRODUCTS PORTUGAL UNIPESSOAL LTDA; UNIV CATOLICA PORTUGUESA
    摘要:The present disclosure provides compositions and methods for the synthesis of bio-based polymers (e.g., polyurethanes and polyesters) from secondary materials produced during a fermentation process. The disclosure also features intermediates produced during these processes, as well as compositions containing the same.

    专利号:US-9981935-B2
    优先权日:2013-07-05
    标 题:Formation of chiral 4-chromanones using chiral pyrrolidines in the presence of acids
    发明人:MEDLOCK JONATHAN ALAN; LETINOIS ULLA; NETSCHER THOMAS; BONRATH WERNER
    权利人:DSM IP ASSETS BV
    摘要:The present invention relates to a synthesis of chromanones or chromanes in a stereospecific matter in view of the 2-position in the chromanone or chromane ring. It has been found that this synthesis is particularly possible in the presence of a chiral compound of a specific type and of at least one Bransted acid or in the presence a specific chiral compound having a Bransted acid functional group in the molecule.

    专利号:US-9815809-B2
    优先权日:2013-07-05
    标题:Formation of chiral 4-chromanones using chiral pyrrolidines in the presence of phenols or thiophenols
    发明人:LETINOIS ULLA; NETSCHER THOMAS
    权利人:DSM IP ASSETS BV
    摘要:The present invention relates to a synthesis of chromanones or chromanes in a stereospecific matter in view of the 2-position in the chromanone or chromane ring. It has been found that this synthesis is particularly possible in the presence of a chiral compound of formula of a specific type and of at least one phenol or thiophenol.

    专利号:US-9809565-B2
    优先权日:2013-07-05
    标 题 :Formation of chiral 4-chromanones using chiral pyrrolidines in the presence of ureas or thioureas
    发明人:LETINOIS ULLA; NETSCHER THOMAS; ACKERMANN STEPHAN
    权利人:DSM IP ASSETS BV
    摘要:The present invention relates to a synthesis of chromanones or chromanes in a stereospecific matter in view of the 2-position in the chromanone or chromane ring. It has been found that this synthesis is particularly possible in the presence of a chiral compound of formula of a specific type and of at least one urea or thiourea.
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    ✅ COA系统入驻 | 共享模式

    主要参考文献


    1: Saito AY, Sussmann RA, Kimura EA, Cassera MB, Katzin AM. Quantification of nerolidol in mouse plasma using gas chromatography-mass spectrometry. J Pharm Biomed Anal. 2015;111:100-3. doi: 10.1016/j.jpba.2015.03.030. Epub 2015 Apr 3.
    2: Chan WK, Tan LT, Chan KG, Lee LH, Goh BH. Nerolidol: A Sesquiterpene Alcohol with Multi-Faceted Pharmacological and Biological Activities. Molecules. 2016 Apr 28;21(5). pii: E529. doi: 10.3390/molecules21050529. Review. doi: 10.1111/fcp.12166. Epub 2015 Nov 22. doi: 10.1016/j.foodchem.2013.11.010. Epub 2013 Nov 28. doi: 10.3390/molecules19033793. doi: 10.1016/j.exppara.2014.10.011. Epub 2014 Oct 24. doi: 10.1007/s11064-013-1092-2. Epub 2013 Jun 14. doi: 10.1016/j.ijantimicag.2016.08.017. Epub 2016 Sep 30. doi: 10.1186/s12868-016-0293-4.
    11: Goel RK, Kaur D, Pahwa P. Assessment of anxiolytic effect of nerolidol in mice. Indian J Pharmacol. 2016 Jul-Aug;48(4):450-452.

    合成参考文献


    参考文献:10.1016/j.phytochem.2005.10.015
    摘要:Kenmogne M, Prost E, Harakat D, Jacquier MJ, Frédérich M, Sondengam LB, Zèches M, Waffo-Téguo P. Five labdane diterpenoids from the seeds of Aframomum zambesiacum. Phytochemistry. 2006 Mar;67(5):433–8. doi: 10.1016/j.phytochem.2005.10.015.
    参考文献:10.1371/journal.pone.0021742
    摘要:van Wijk M, de Bruijn PJA, Sabelis MW. Complex Odor from Plants under Attack: Herbivore's Enemies React to the Whole, Not Its Parts. PLoS ONE. 2011 Jul 13;6(7):e21742. doi: 10.1371/journal.pone.0021742.
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