专利号:US-11440989-B2 优先权日:2018-09-17 标题:Application of Mannich base in flame-retardant polyurethane material 发明人:GUAN YONGJIAN; LI PING; LI ZHIJUN; WANG FENG; LI YUBO 权利人:JIAHUA SCIENCE & TECH DEVELOPMENT SHANGHAI LTD; JIAHUA CHEMICALS INC 摘要:Application of a Mannich base in a flame-retardant polyurethane material is provided. The Mannich base has a structure represented by a formula (I). In the Mannich base, flame-retardant groups, i.e., halogens are introduced at the second, fourth and sixth positions of a phenyl group, and flame-retardant elements, i.e., halogens and nitrogen are introduced into synthesized polyether polyol, giving the synthesized polyether polyol good flame retardance. The amount of active hydrogen in the Mannich base is small so that occurrence of side reactions during the synthesis of the polyether polyol is reduced, and the viscosity of the flame-retardant polyether polyol is lowered. Due to autocatalytic performance of tertiary amido in the flame-retardant polyether polyol, use of a catalyst can be reduced and even avoided during the synthesis. A preparation method of the Mannich base is also provided.
专利号:US-11401375-B2 优先权日:2018-09-17 标题:Flame-retardant polyether polyol as well as preparation method and application thereof 发明人:GUAN YONGJIAN; LI PING; LI ZHIJUN; WANG FENG; LI YUBO 权利人:JIAHUA SCIENCE & TECH DEVELOPMENT SHANGHAI LTD; JIAHUA CHEMICALS INC 摘要:A flame-retardant polyether polyol is provided, including a Mannich base and an epoxide. The epoxide is selected from ethylene oxide, propylene oxide and butylene oxide. The Mannich base has a structure represented by a formula (I). In the Mannich base, flame-retardant groups, i.e., halogens are introduced at the second, fourth and sixth positions of a phenyl group, and flame-retardant elements, i.e., halogens and nitrogen are introduced into synthesized polyether polyol. The amount of active hydrogen in the Mannich base is small so that side reactions during synthesis of the polyether polyol are reduced, and the viscosity of the polyether polyol is lowered. A flame-retardant polyurethane material is also provided, synthesized from raw materials comprising the above-mentioned flame-retardant polyether polyol and an isocyanate. Due to autocatalytic performance of tertiary amido in the flame-retardant polyether polyol, use of a catalyst can be reduced and even avoided during the synthesis.
专利号:CN-117886760-A 优先权日:2023-12-18 标题 :Synthesis method of 3-(5-fluoropyrimidin-2-yl)-2-methoxyaniline
专利号:CN-110143852-A 优先权日:2019-06-28 标 题:A method of photocatalytic synthesis is at more bromophenol compounds in water phase
参考文献:10.1007/s11696-024-03579-z 摘要:Rita BH, Uemi M, Raminelli C. Selenium species-catalyzed biomimetic halogenations of aromatic and heteroaromatic compounds. Chem. Pap. 2024 Jun 22;78(12):6971–7. doi: 10.1007/s11696-024-03579-z. 参考文献:10.1007/bf01623498 摘要:Ventura F, Rivera J. Potential formation of bromophenols in Barcelona's tap water due to daily salt mine discharges and occasional phenol spills. Bulletin of Environmental Contamination and Toxicology. 1986 Dec;36(1):219–25. doi: 10.1007/bf01623498.