CAS: 135285-90-4; 2,4,6,8,10,12-Hexanitro-2,4,6,8,10,12-Hexaazaisowurzitane

📜2,4,6,8,12-Pentaacetyl-2,4,6,8,10,12-Hexaazatetracyclo[5.5.0.05,9.03,11]Dodecane置于硫酸,硝酸体系中,化学反应 10.0H,以97%的收率获得六硝基六氮杂异伍兹烷
参考文献:六硝基六氮杂异纤锌矿型结构烷烃的新前体(hniw,Cl-20)
标题:六硝基六氮杂异纤锌矿型结构烷烃的新前体(hniw,Cl-20)
摘要:合成了两个新的聚酰基六氮杂异纤锌矿.五乙酰基或五乙酰基甲酰基六氮杂异纤锌矿型结构烷烃可以是制备高能材料hniw的前体.
Doi:10.1002/jhet.5570370640

专利信息

专利号:US-7279572-B2
优先权日:2003-05-22
标题:Process for the 2-stage synthesis of hexanitrohexaazaisowurtzitane starting from a primary amine
发明人：CAGNON GUY; ECK GENEVIEVE; HERVE GREGOIRE; JACOB GUY
权利人:SNPE MATERIAUX ENERGETIQUES
摘要:A subject-matter of the present invention is a novel process for the synthesis of hexanitrohexaazaisowurtzitane (HNIW), a compound of use as energetic filler in powders, propellants and explosives. n This process comprises a first stage of reaction of an α,β-dicarbonyl derivative with a primary amine which makes it possible to form a hexasubstituted hexaazaisowurtzitane derivative. n The HNIW is subsequently obtained directly, in a single reaction stage, by nitration of the hexasubstituted hexaazaisowurtzitane derivative. n This process, in only 2 stages starting from a primary amine, is particularly simple and inexpensive.

专利号:US-11434209-B2
优先权日:2018-08-21
标 题 :Method for synthesis of TKX-50 using insensitive intermediate
发明人：KWON KUK TAE; LEE WOONG HEE; SHIM JEONG SUB; LEE SO JUNG
权利人:AGENCY DEFENSE DEV
摘要:The present disclosure relates to a method for synthesis of TKX-50 using an insensitive intermediate, and more specifically, to a method of manufacturing TKX-50 which includes: preparing DCG as a starting material; forming a THP-DAG intermediate from the DCG; and synthesizing TKX-50 through the THP-DAG intermediate.

专利号:WO-2025037082-A1
优先权日:2023-08-11
标题:Improved flow synthesis
发明人：MCWHIR NAIL; KENNEDY STUART; JONES CHRISTOPHER; DIDSBURY MATTHEW PAUL; JUBB DANIEL; THOMAS SIMON DAVID; MURRAY IAN EWART PATTERSON
权利人:BAE SYSTEMS PLC
摘要:The invention relates to a method for the flow synthesis manufacture of energetic materials with a two stage-temperature reactor. There is provided a flow reactor for the synthesis of energetic materials, comprising; i. a first input flow reagent, and a second input flow reagent ii. a flow reactor, comprising at least two temperature zones within the reactor. (Formula (I))

专利号:US-8492541-B1
优先权日:2007-07-16
标 题:Synthesis of azido heterocycles
发明人：DUDDU RAJA; DAVE PARITOSH; DAMAVARAPU REDDY; SURAPANENI RAO
权利人:DUDDU RAJA; DAVE PARITOSH; DAMAVARAPU REDDY; SURAPANENI RAO; US ARMY
摘要:Energetic candidate azido heterocycles and their synthesis are described.

专利号:US-7101955-B1
优先权日:1998-11-12
标题:Synthesis of energetic thermoplastic elastomers containing both polyoxirane and polyoxetane blocks
发明人：SANDERSON ANDREW J; EDWARDS WAYNE; CANNIZZO LOUIS F; WARDLE ROBERT B
权利人:ALLIANT TECHSYSTEMS INC
摘要:This thermoplastic elastomer is present in a substantially solid state suitable for use as a binder for a propellant, explosive, and/or gas generant of a supplemental restraint system. The thermoplastic elastomer is formed from a composition including A blocks which are crystalline at temperatures below about 75° C. and B blocks which are amorphous at temperatures above about −20° C. The A blocks are derived from oxetane derivatives and the B blocks are derived from oxiranes and derivatives thereof. The A blocks and B-blocks are end-capped with a diisocyanate having a first isocyanate moiety that is substantially more reactive with the terminal groups of the blocks than the second isocyanate moiety, whereby the more reactive first isocyanate moiety is capable of reacting with the terminal groups of the blocks, leaving the less reactive second isocyanate moiety free and unreacted. The end-capped A blocks and the end-capped B blocks are linked together with a linking compound having two isocyanate-reactive groups which are sufficiently unhindered to react with the free and unreacted isocyanate moieties of the end-capped polymers.

专利号:US-10119953-B1
优先权日:2015-03-20
标 题 :Metal chalcogenide quantum dots for the detection of nitroaromatic chemicals
发明人：BACA ALFRED J; MEYLEMANS HEATHER A; CAMBREA LEE R; BALDWIN LAWRENCE
权利人:US NAVY; US NAVY
摘要:The synthesis of AgInS 2 based quantum dots and their use as fluorometric probes for the selective detection of nitroaromatic explosive chemicals, without the use of ligands specific to nitroaromatic explosive chemicals. These quantum dots allow the detection of nitroaromatic explosive molecules by eye. The present invention also represents a simple patterning method for quantum dots on substrates, including low cost filter paper. The ease of fabrication, use of less toxic materials, and the selectivity to nitroaromatic explosive chemicals results in a practical solution to the development of a portable fluorescent probe based on quantum dots for the detection of nitroaromatic explosive chemicals.