CAS: 104934-52-3; 3-Dodecylthiophene

相似化合物

65016-55-9 65016-62-8 110851-66-6

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CAS号872-31-1 3-溴噻吩 | CAS号15890-72-9 十二烷基溴化镁 | CAS号143-15-7 溴代十二烷 | CAS号905966-46-3 3-噻吩硼酸新戊二醇酯 | CAS号10157-76-3 对甲苯磺酸十二酯 | CAS号112-52-7 1-氯十二烷 | CAS号112-53-8 月桂醇 | CAS号139100-06-4 2-溴-3-十二烷基噻吩 | CAS号148256-63-7 2,5-二溴-3-十二烷基噻吩 | CAS号919079-93-9 2-(4-dodecylthi...

十二烷醇置于吡啶,Copper(L) Iodide,Lithium Tert-Butoxide体系中,用 N,N-二甲基甲酰胺 用作溶剂,化学反应 15.5H,反应生成3-十二烷基噻吩
参考文献:铜催化有机硼化合物与伯烷基卤化物和拟卤化物的交叉偶联反应
标题:铜催化有机硼化合物与伯烷基卤化物和拟卤化物的交叉偶联反应
摘要:非活化的烷基亲电试剂,包括烷基碘,溴化物,甲苯磺酸盐,甲磺酸盐,甚至氯化物,与芳基硼化合物和烷基9-Bbn试剂进行铜催化交叉偶联(见方案; 9-Bbn = 9-硼环[3.3 .1]壬烷).该反应具有实用的反应性,因此可以补充钯和镍催化的烷基卤的suzuki-Miyaura偶联反应.
Doi:10.1002/anie.201008007

专利信息

专利号:US-9379335-B2
优先权日:2012-04-08
标题:Benzodipyrrolidones and their polymers: synthesis and applications for organic electronics and optoelectronics
发明人：CUI WEIBIN; WUDL FRED
权利人:UNIV CALIFORNIA
摘要:Disclosed is the synthesis of benzodipyrrolidone and their polymers and small molecules for electronic and optoelectronic applications. Also disclosed are devices that incorporate such polymers and small molecules.

专利号:US-7834106-B2
优先权日:2005-04-01
标题:Living synthesis of conducting polymers including regioregular polymers, polythiophenes, and block copolymers
发明人：MCCULLOUGH RICHARD D; SHEINA ELENA E; IOVU MIHAELA C
权利人:UNIV CARNEGIE MELLON
摘要:Regioregular poly(3-alkylthiophenes) and other polythiophenes can be prepared by living polymerization which have good solubility, processability and environmental stability. The polymerization method can afford regioregular poly(3-alkylthiophenes) in high yields. Kinetic study of polymerization revealed the living character of this process. The molecular weight of poly(3-alkylthiophenes) is a function of the molar ratio of the monomer to nickel initiator, and conducting polymers with relatively narrow molecular weight distribution (PDI<1.5) are now readily available. Sequential monomer addition resulted in new block copolymers containing different poly(3-alkylthiophene) segments, which further confirms the “livingness†of this system. Other synthetic methods can be used as well to conduct living polymerization. Blends and electronic devices can be prepared.

专利号:WO-2007007735-A1
优先权日:2005-07-12
标 题 :Synthesis of organic conductive polymerizable material onto metal oxide surface through light irradiation
发明人：TACHIBANA YASUHIRO
权利人:UNIV OSAKA; KANSAI TECH LICENSING ORG CO; TACHIBANA YASUHIRO
摘要:Disclosed is a composite material having a nanostructure containing metal oxide fine particles and an organic conductive polymerizable material. In this composite material, the metal oxide fine particles are joined with one another and the organic conductive polymerizable material is contained in the spaces between the fine particles. In this connection, the organic conductive polymerizable material is a copolymer which is composed of a polythiophene derivative, a thiophene or a derivative thereof and pyrrole, aniline, fluorene, furan or a derivative thereof. Also disclosed is a method for producing such a composite material. This composite material is useful for display elements such as electronic paper.

专利号:US-2006278867-A1
优先权日:2005-04-01
标 题 :Living synthesis of conducting polymers including regioregular polymers, polythiophenes, and block copolymers

专利号:US-2009043052-A1
优先权日:2005-04-01
标 题 :Living synthesis of conducting polymers including regioregular polymers, polythiophenes, and block copolymers

专利号:EP-1872405-A2
优先权日:2005-04-01
标题 :Living synthesis of conducting polymers including regioregular polymers, polythiophenes, and block copolymers