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参考文献:Critical Role Of Catalysts And Boranes For Controlling The Regioselectivity In The Rhodium-Catalyzed Hydroboration Of Fluoroolefins
标题:Critical Role Of Catalysts And Boranes For Controlling The Regioselectivity In The Rhodium-Catalyzed Hydroboration Of Fluoroolefins
摘要:[graphics]Catalytic Hydroboration Of Perfluoroalkylethylenes (Rfch=ch2) With Cationic And Neutral Rhodium Complexes Allows For Selective Access To Either Regioisomeric Alcohol After Hydroboration With Catechol And Pinacolboranes,Followed By Oxidation With Alkaline Hydrogen Peroxide.
DOI:10.1021/ol9909583