📜1,5-已二烯置于铂 三氯硅烷体系中,用95%的收率获得5-己烯基三氯硅烷 参考文献:Method For Controlling Hydrosilylation In A Reaction Mixture 标题:Method For Controlling Hydrosilylation In A Reaction Mixture 摘要:该发明揭示了一种通过控制反应混合物中氧气的溶液浓度相对于反应混合物中存在的任何铂来控制氢硅烷化的方法.该发明进一步揭示了在氢硅烷化反应中通过向烯烃化合物中引入控制量的氧气来控制具有至少4个碳原子的线性或支链烯烃化合物的异构化的方法.该发明还揭示了一种通过在氧气和氢硅烷化催化剂存在下将卤代或烷氧基硅烷与不饱和环烯烃化合物反应来生产二环烷基取代硅烷的方法.
专利号:US-10870917-B2 优先权日:2016-07-08 标 题:Functionalized foams 发明人:DARLING SETH B; ELAM JEFFREY W; MANE ANIL U; SNYDER SETH W 权利人:UCHICAGO ARGONNE LLC 摘要:A method of fabricating an foam includes providing a foam comprising a base material. The base material is coated with an inorganic material using at least one of an atomic layer deposition (ALD), a molecular layer deposition (MLD), or sequential infiltration synthesis (SIS) process. The SIS process includes at least one cycle of exposing the foam to a first metal precursor for a first predetermined time and a first partial pressure. The first metal precursor infiltrates at least a portion of the base material and binds with the base material. The foam is exposed to a second co-reactant precursor for a second predetermined time and a second partial pressure. The second co-reactant precursor reacts with the first metal precursor, thereby forming the inorganic material on the base material. The inorganic material infiltrating at least the portion of the base material. The inorganic material is functionalized with a material.
参考文献:10.1007/bf02932997 摘要:Park JP, Lee SJ, Park TJ, Lee K, Choi IS, Lee SY, Kim M, Chung BH. Microcontact printing of biotin for selective immobilization of streptavidin-fused proteins and SPR analysis. Biotechnology and Bioprocess Engineering. 2004 Apr;9(2):137–42. doi: 10.1007/bf02932997.