CAS: 14986-21-1; Trichloro(Trichlorosilyloxy)Silane

该化合物是一种氯化硅烷化合物,其特点是由于存在六种氯原子而具有高度反应性,并粘合到硅.有机硅中间体主要用于硅基材料的合成,作为改变表面特性或聚合物系统中交叉连接的前体.其对称结构和氯替代使其在受控反应中引入硅氧联系具有价值.该化合物在需要精确化学功能的应用方面特别有用,例如特殊涂层,粘合剂或硅酮活性器.适当的处理由于其湿度敏感度和对核素的潜在反应作用,是必不可少的.

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CAS号10026-04-7 四氯化硅 | CAS号7732-18-5 水 | CAS号7446-11-9 三氧化硫 | CAS号80937-33-3 oxygen | CAS号7782-50-5 氯气 | CAS号7440-21-3 硅 | CAS号10025-78-2 三氯氢硅 | CAS号107-46-0 六甲基二硅氧烷 | CAS号10028-15-6 臭氧 | CAS号4766-57-8 正硅酸丁酯 | CAS号18134-84-4 triis°Cyanato(t... | CAS号10026-04-7 四氯化硅 | CAS号112926-00-8 硅胶 | CAS号631-36-7 四乙基硅烷 | CAS号994-49-0 六乙基二硅氧烷 | CAS号26121-10-8 difluoro-bis(tr... | CAS号682-01-9 四丙氧基硅烷 | CAS号1048-08-4 四苯基硅烷 | CAS号10025-78-2 三氯氢硅

合成工艺路线路线简述

    📜Siloxene置于cl2体系中,用 四氯化碳 用作溶剂,化学反应生成六氯二硅氧烷
    参考文献:Gmelin Handbuch Der Anorganischen Chemie,Gmelin Handbook: Si: Mvol.B,216,Page 595-598
    标题:Gmelin Handbuch Der Anorganischen Chemie,Gmelin Handbook: Si: Mvol.B,216,Page 595-598

    专利信息


    专利号:US-2024286909-A1
    优先权日:2023-02-24
    标 题 :Production of hexachlorodisiloxane
    发明人：CHITTURI VENKATESWARA RAO; KOROLEV ANDREY
    权利人:WONIK MAT NORTH AMERICA LLC
    摘要:A method for the synthesis of perchlorodisiloxanes, and particularly hexachlorodisiloxane (Si2OCl6, HCDSO), using an amount of tetrachlorosilane (SiCl4) with an amount of molybdenum trioxide (MoO3). The method, in its broadest form, can be used to synthesize perchlorosiloxanes of the general formulae SixOx−1Cl2x+2. A catalytic amount of anhydrous HCl may be used to speed the reaction.

    专利号:US-11525049-B2
    优先权日:2017-03-29
    标 题:Polar additive for the synthesis of copolymers of vinylaromatic monomer and conjugated diene monomer having high vinylaromatic and low vinyl contents
    发明人：KOZAK RADOSLAW; BOGACZ ROBERT; WALENIA MALGORZATA; WEDA PAWEL
    权利人:Synthos Sa; SYNTHOS DWORY 7 SPOLKA Z OGRANICZONA ODPOWIEDZIALNOSCIA SPOLKA JAWNA
    摘要:The present invention relates to the use of N,N′,N″-substituted hexahydro-1,3,5-triazine in the anionic polymerization of conjugated diene monomer and vinylaromatic monomer. Use of this polar additive produces copolymers having both high vinylaromatic and low vinyl contents, while the blockiness of the vinylaromatic unit can be tailored.

    专利号:JP-2023052652-A
    优先权日:2017-03-29
    标 题 :Polar additive for synthesis of copolymers of vinylaromatic monomer and conjugated diene monomer having high vinylaromatic and low vinyl contents

    专利号:JP-7667190-B2
    优先权日:2017-03-29
    标题 :Polar additive for the synthesis of copolymers of vinyl aromatic monomers and conjugated diene monomers with high vinyl aromaticity and low vinyl content

    专利号:WO-2018178199-A1
    优先权日:2017-03-29
    标 题:Polar additive for the synthesis of copolymers of vinylaromatic monomer and conjugated diene monomer having high vinylaromatic and low vinyl contents

    专利号:KR-20190130011-A
    优先权日:2017-03-29
    标 题 :Polar additives for the synthesis of copolymers of conjugated diene monomers with vinylaromatic monomers having high vinylaromatics and low vinyls

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    合成参考文献


    参考文献:10.1007/978-3-642-68661-0_20
    摘要:Weber WP. Miscellaneous Reductions. 1983. In: Reactivity and Structure Concepts in Organic Chemistry.
    参考文献:10.1007/978-94-017-2504-0_15
    摘要:Saunders KJ. Silicones. 1973. In: Organic Polymer Chemistry.
    参考文献:10.1007/978-94-009-1195-6_17
    摘要:Saunders KJ. Silicones. 1988. In: Organic Polymer Chemistry.
    参考文献:10.1007/978-1-4615-8825-2_4
    摘要:Gutmann V. Bond-Length Considerations in the Crystalline State. 1978. In: The Donor-Acceptor Approach to Molecular Interactions.
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