📜甲基二氯硅烷,三聚丙烯置于dihydrogen Hexachloroplatinate体系中,化学反应 0.5H,以90%的收率获得产物二氯甲基-N-丙基硅烷 参考文献:The Hydrosilylation Of Propylene 标题:The Hydrosilylation Of Propylene 摘要:The Reactions Of Separate And Competitive Hydrosilylation Of Propylene With Hsicl3,Mesihcl2,Me2Sihcl,And Meph2Sih In The Presence Of The Speier Catalyst (Sc) With Different Additives And A Catalyst Obtained From Sc And Propylene Were Studied. A Mutual Influence Of The Hydrosilanes In The Competitive Reactions Was Found. The Influence Various Additives To Sc On The Process Was Considered. DOI:10.1007/bf02494514
专利号:US-5455367-A 优先权日:1993-04-22 标 题:Method for the synthesis of silanes or organosilicon hydrides by the reduction of the corresponding silicon halides or organosilicon halides 发明人:KLEIN KLAUS-DIETER; KNOTT WILFRIED; KOERNER GOETZ 权利人:GOLDSCHMIDT AG TH 摘要:A method for the synthesis of silanes or organosilicon hydrides by the reduction of the corresponding silicon halides or organosilicon halides with a magnesium hydride in a liquid reaction medium is carried out by utilizing the following distinguishing features: n a) the use of non-pyrophoric, preferably autocatalytically produced, storage magnesium hydride as magnesium hydride, n b) the use of conventional ethers as reaction medium, and n c) the continuous removal of the magnesium halide formed being deposited on the surface of the magnesium hydride particles during the reaction by the action of mechanical energy or ultrasound so as to form a fresh surface.
专利号:US-11033507-B2 优先权日:2013-12-19 标 题 :Method of synthesis of silica vesicles and use thereof 发明人:YU CHENGZHONG; MITTER NEENA; ZHANG JUN 权利人:UNIV QUEENSLAND 摘要:The invention relates, in part, to a method of producing silica vesicles including under controlled conditions to thereby heavily influence the morphology and characteristics of the vesicles. The vesicles are shown to be effective as delivery agents for chemical and biological agents. They are also shown to be useful in methods of treatment and as components of an immunogenic composition.
专利号:US-4552973-A 优先权日:1984-03-23 标题 :Process for the preparation of dimethyldichlorosilane 发明人:FELDNER KURT; GRAPE WOLFGANG 权利人:BAYER AG 摘要:A process for the preparation of dimethyldichlorosilane from the low-boiling and high-boiling by-products of the direct synthesis of methylchlorosilane, comprising reacting methyltrichlorosilane simultaneously with the low-boiling components having a high content of methyl groups and with the high-boiling non-cleavable components, in the presence of a catalyst, at a temperature between about 250° C. and 400° C. and under a pressure of up to 100 bar.
专利号:US-2022355262-A1 优先权日:2019-07-22 标题 :System and method for manufacturing water-based hydrophobic aerogels and aerogel composites 发明人:SACHITHANADAM MAHESH; KHORASGANI SOGHRATI ELMIRA; NATARAJAN GAYATHRI 权利人:KROSSLINKER PTE LTD 摘要:Embodiments of the present invention provide users with a system and method for manufacturing water-based hydrophobic aerogels and aerogel composites. The system and method can be carried out in a manner which is more rapid than typical ways and can be readily scalable. The method of manufacture is useful for producing water based hydrophobic aerogels and aerogel composites on a large scale with good homogeneity and consistency. Advantageously, the method of manufacture also has the benefit of a shorter processing time due to the vacuum homogenizing and mixing processes, the use of microwave assisted vacuum freeze drying for ease of synthesis of water-based hydrophobic aerogels.
专利号:US-7285608-B2 优先权日:2004-04-21 标题:Metallocene ligands, metallocene compounds and metallocene catalysts, their synthesis and their use for the polymerization of olefins 发明人:SCHOTTEK JOERG; PACZKOWSKI NICOLA STEFANIE; WINTER ANDREAS; SELL THORSTEN 权利人:NOVOLEN TECH HOLDINGS CV 摘要:A catalyst system includes a metallocene compound having the formula R 9 L 1 L 2 M 1 R 1 R 2 wherein R 9 is a bridge between ligands L 1 and L 2 and M 1 is a metal of Group IVB of the Periodic Table such as titanium, zirconium and hafnium and R 1 and R 2 can be hydrogen or aliphatic or aromatic groups. Bridge R 9 can include silicon, germanium or tin. The metallocene compound of the invention as synthesized has a racemic to meso isomer ratio of greater than 5 to 1, thereby precluding the need for subsequent separation of the meso isomer.
专利号:US-2018193278-A1 优先权日:2013-12-19 标题 :Method of synthesis of silica vesicles and use thereof
参考标题:The Synthesis Of [bis(Trifluoromethyl)Amino-Oxy]-Substituted Dialkyldichlorosilanes And Their Conversion Into Polysiloxanes 作者:Graham E. Ducker,Anthony E. Tipping |发布日期:1994.3 摘要:(Cf3)2Noch2Ch2Ch2Simecl2 (29) Are Converted Into The Corresponding Polysiloxanes ('Prepolymers' Of Low Molecular Weight) By Reaction With Reagents Including Water, Acid, Base And Metal Oxides; Equilibration Of The Polysiloxane 'Prepolymer' 38, Derived From Dichlorosilane 29 By Heating With Powdered Koh, Affords A Solid Rubbery Polysiloxane.
合成参考文献
摘要:Compound: Silane, dichloromethylpropyl-, homopolymer 摘要:Pietruszka, J., Science of Synthesis, (2002) 4, 168. 摘要:Michael, J. P.; de Koning, C. B., Science of Synthesis, (2002) 4, 955.