CAS: 28286-79-5; 3-(Hydroxymethyl)Benzoic Acid

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CAS号34841-13-9 ethyl 3-(hydrox... | CAS号1877-71-0 异酞酸氢甲酯 | CAS号67853-03-6 3-羟甲基苯甲酸甲酯 | CAS号52010-98-7 3-(羟甲基)苯甲醛 | CAS号121-91-5 间苯二甲酸(IPA) | CAS号15852-73-0 3-溴苯甲醇 | CAS号823-78-9 间溴溴苄 | CAS号1129-28-8 3-溴甲基苯甲酸甲酯 | CAS号874-97-5 3-羟甲基苯甲腈 | CAS号1877-77-6 3-氨基苯甲醇 | CAS号67853-03-6 3-羟甲基苯甲酸甲酯 | CAS号619-21-6 3-羧基苯甲醛

3-溴苄溴置于正丁基锂,乙醚,Lead(II) Oxide,溶剂黄146体系中,化学反应生成3-羟甲基苯甲酸
参考文献:具有羟基,腈基和磺酰胺基的有机锂化合物.
标题:具有羟基,腈基和磺酰胺基的有机锂化合物.
摘要:
Doi:10.1021/ja01192A058

专利信息

专利号:US-5712367-A
优先权日:1989-10-02
标 题:Process for the solubilization of peptides and process for peptide synthesis
发明人：BERNARD JEAN-MARIE; BOUZID KAMEL; GERVAIS CHRISTIAN
权利人:RHONE POULENC CHIMIE
摘要:A process is disclosed for making peptides soluble in a water-immiscible organic solvent, comprising linking a lipophilic group with an amide or ester bond to the terminal carboxyl group of said peptide; when the lipophilic group is linked to L-serine, a molecule is obtained with a solubility in water at 25 DEG C. of less than 30 g/liter. This lipophilic group is non-polymeric and chemically defined. A process is also disclosed for the synthesis of peptides, optionally protected, in a liquid medium, wherein the starting material is an amino acid or peptide made soluble in an organic medium by a lipophilic group A-L linked to the carboxyl function of the starting amino acid or peptide, and are added to amino acids or peptides to be condensed which are activated on their acid function and protected on their amine function and are optionally protected on their side chain. The peptides resulting from the synthesis are used, where appropriate, for the synthesis of medicinal products, vaccines or agri-foodstuff or plant-protection.

专利号:PT-95478-B
优先权日:1989-10-02
标题:Process for the solution of peptides and process for the synthesis of peptides