CAS: 131211-27-3; Di(Adamantan-1-yl)Phosphine

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CAS号126683-99-6 双(1-金刚烷基)膦酰氯 | CAS号157282-19-4 双(1-金刚烷基)氯化磷 | CAS号131266-79-0 二-1-氯代金刚烷三甲基氧膦 | CAS号23906-91-4 (1-adamantyl)di... | CAS号281-23-2 金刚烷 | CAS号321921-71-5 正丁基二(1-金刚烷基)膦 | CAS号395116-70-8 苄基二金刚烷基膦 | CAS号622-97-9 4-甲基苯乙烯 | CAS号131266-79-0 二-1-氯代金刚烷三甲基氧膦 | CAS号33534-88-2 2-(4-methylphen... | CAS号157282-19-4 双(1-金刚烷基)氯化磷

金刚烷置于aluminum (III) Chloride,Lithium Aluminium Tetrahydride,三氯化磷体系中,用 四氢呋喃 用作溶剂,化学反应 1.0H,反应生成二-1-金刚烷基膦
参考文献:钯催化交叉偶联反应中的芳基-二金刚烷膦配体:合成,结构分析和应用
标题:钯催化交叉偶联反应中的芳基-二金刚烷膦配体:合成,结构分析和应用
摘要:合成了大体积的二金刚烷基芳基膦配体,并将其用于空间要求的邻位取代的芳基氯化物的buchwald-Hartwig偶联反应中.在甲苯磺酰also和芳基卤化物的偶联中,配体还显示出增强的催化活性.
Doi:10.1002/ejoc.201901834

专利信息

专利号:US-2024424116-A1
优先权日:2023-06-16
标题:Pegylated-AU(III) Reagents for Rapid Cysteine S-Arylation of Biomolecules
发明人：MAYNARD HEATHER D; SPOKOYNY ALEXANDER; AYTAC HAYDEN MONTGOMERY; MESSINA MARCO; DOUD EVAN
权利人:UNIV CALIFORNIA
摘要:Compositions and methods for cysteine arylation of polypeptides using Au(III) organometallic complexes are disclosed herein. The bioconjugation reactions proceed rapidly at ambient temperature in various buffers. The compositions and methods enable the synthesis of PEGylated polypeptide conjugates with selectivity and high efficiency, allowing facile modification of complex biomolecules.

专利号:US-2016223559-A1
优先权日:2015-02-02
标题:Tetrazine-containing compounds and synthetic methods thereof
发明人：DEVARAJ NEAL K; WU HAOXING; YANG JUN
权利人:UNIV CALIFORNIA
摘要:Described herein are tetrazine derivatives and efficient synthetic methods of synthesis thereof using elimination-Heck cascade reaction. Provided herein is the synthesis of conjugated tetrazines from the tetrazine derivatives. Also provided herein are methods of use of the conjugated tetrazines as fluorogenic probes for live-cell imaging.

专利号:CN-110831941-A
优先权日:2018-06-11
标 题 :Synthesis of substituted heterocycle fused gamma-carboline compound

专利号:US-8981126-B2
优先权日:2011-02-24
标 题:Cyclopropenylidene-stabilized phosphenium cations
发明人：ALCARAZO MANUEL; BRUNS HANS; PETUSKOVA JEKATERINA
权利人:ALCARAZO MANUEL; BRUNS HANS; PETUSKOVA JEKATERINA; Studiengesellshaft Kohle mbH
摘要:Phosphenium compounds with the general formula I: n nin whichn R 1 , R 2 , R 3 and R 4 are identical or different and represent a linear or branched C 1 -C 6 -alkyl radical, which can optionally be substituted, or R 1 and R 2 and/or R 3 and R 4 are bonded to one another with the formation of a ring, R 5 and R 6 stand for a saturated or unsaturated and linear or branched alkyl group, alkenyl group or aryl group, which can have suitable substituents, even heteroatoms as substituents, or a heteroatom-comprising hydrocarbon group, which can have suitable substituents, and the R 5 and R 6 radicals can form a ring which can be 4- to 20-membered, saturated or unsaturated and alicyclic or heteroalicyclic and can exhibit suitable substituents, X − represents an anion, a process for the preparation thereof, and also the use of these compounds in metal complexes which can be used as catalysts in organic synthesis, are claimed.

专利号:WO-2013159229-A1
优先权日:2012-04-24
标 题:Silanyloxyaryl phosphine ligand and uses thereof in c-n cross-coupling
发明人：STRADIOTTO MARK JOHN
权利人:UNIV DALHOUSIE
摘要:The present invention pertains to silanyloxyaryl phosphine ligands of formula (I) and their uses with transition metal catalyst precursors for organic synthesis reactions. More particularly, the present invention pertains to the use of silanyloxyaryl phosphine ligands and with transition metal catalyst precursors in C-N cross-coupling reactions.

专利号:US-11794180-B2
优先权日:2015-10-29
标 题 :Tri-(adamantyl)phosphines and applications thereof
发明人：CARROW BRAD P; CHEN LIYE
权利人:UNIV PRINCETON
摘要:In one aspect, phosphine compounds comprising three adamantyl moieties (PAd3) and associated synthetic routes are described herein. Each adamantyl moiety may be the same or different. For example, each adamantyl moiety (Ad) attached to the phosphorus atom can be independently selected from the group consisting of adamantane, diamantane, triamantane and derivatives thereof. Transition metal complexes comprising PAd3 ligands are also provided for catalytic synthesis including catalytic cross-coupling reactions.