CAS: 961-27-3; 2,7-Diacetylfluorene

该化合物其结构特征为:氟乙烯单体,以乙基组和乙基酮功能组替代,其特性为:氟乙基,在室温下一般是固体,并因其芳香特性而闻名,因为它有氟乙烯环,有助于其稳定性和潜在再活性;乙酰基组引入一种碳基功能,使它成为可参与各种化学反应(例如核糖核毒添加)的甲酮,其独特结构可能具有特定的光学特性,使其在材料科学和有机合成等领域具有兴趣;此外,该化合物可能展示生物活动,但需要进行具体研究,以阐明其药理特性;与许多有机化合物一样,由于潜在的毒性或再活性,应当观察适当的处理和安全防范措施.

英文名称2,7-Diacetylfluorene
中文名称1,1'-(9H-芴-2,7-二基)双(乙烷-1-酮)
IUPAC名称1,1'-(9H-fluorene-2,7-diyl)bis(ethan-1-one)
其它别名2,7-二乙酰芴; 2,7-Diacetylfluorene
CAS编号961-27-3
MFCD编号:MFCD00045332
分子式:C17H14O2分子量:250.29
产品CID: 2016366
产品分类有机原料→分子砌块→芳环类化合物→苯类化合物

相似结构搜索
InChIKey: RIRYGERFWHUZBT-UHFFFAOYSA-N
InChI=1S/C17H14O2/c1-10(18)12-3-5-16-14(7-12)9-15-8-13(11(2)19)4-6-17(15)16/h3-8H,9H2,1-2H3
计算化学: 氢键受体数2.0氢键供体数0可旋转键数2

物理性质

熔点173 °C
沸点459.6±38.0 °C at 760 mmHg
闪点171.0±23.8 °C
密度1.2±0.1 g/cm3
PSA:34.14
LogP:3.663
折射率1.616
蒸汽压0.0±1.1 mmHg at 25°C
溶解性Chloroform (Slightly), Ethyl Acetate (Slightly, Sonicated)
外观形态淡黄色固体
储存条件-20°C 冷藏
产品应用该化合物用于反应剂.

上下游产品

合成工艺路线路线简述

86-73-7 = 961-27-3
反应条件:1.1 Catalysts: Aluminum Chloride Solvents: 1,2-Dichloroethane; 40 Min,Rt; 40 Min,Rt; 23 H,Reflux
标题:Alkyl-Substituted Bis(4-((9H-Fluoren-9-Ylidene)Methyl)Phenyl)Thiophenes,Weakening Of Intermolecular Interactions And Additive-Assisted Crystallization
作者:Sonina,Alina A.; Becker,Christina S.; Kuimov,Anatoly D.; Shundrina,Inna K.; Komarov,Vladislav Yu.; Et Al
参考文献:Crystengcomm 日期:2021 卷标:23(14) 页码:2654-2664]

86-73-7 = 961-27-3
反应条件:1.1 Reagents: Aluminum Chloride Solvents: 1,2-Dichloroethane; Rt; 30 Min,Rt1.2 Solvents: 1,2-Dichloroethane; 5 H,0 °C
标题:Design Of A Mof Based On Octa-Nuclear Zinc Clusters Realizing Both Thermal Stability And Structural Flexibility
作者:Ma,Yunsheng; Tang,Xiaoyan; Chen,Ming; Mishima,Akio; Li,Liangchun; Et Al
参考文献:Chemical Communications (Cambridge 日期:2022 卷标:58(8) 页码:1139-1142]

= 961-27-3 [标题:Reaction Conditions
标题:Benzo[c]Fluorenones. Iv. Elucidation Of The Position Of The Succinoyl Group Introduced In 2,7-Diethylfluorene And The Conversion Of This Compound Into 1,2,3,4-Tetrahydro-5,9-Diethylbenzo[c]Fluorene
作者:Gindy,Munir; Eskander,Emile
参考文献:Journal Fuer Praktische Chemie (Leipzig) 日期:1972 卷标:314(5-6) 页码:673-81]

86-73-7 = 961-27-3 + 781-73-7
反应条件:1.1 Catalysts: Aluminum Chloride Solvents: 1,2-Dichloroethane; 5 Min,Rt; 1 H,Rt; Rt -> Reflux; 23 H,Reflux1.2 Reagents: Hydrochloric Acid Solvents: Water; Cooled
标题:The Synthesis Of Mono- And Diacetyl-9H-Fluorenes. Reactivity And Selectivity In The Lewis Acid Catalyzed Friedel-Crafts Acetylation Of 9H-Fluorene
作者:Titinchi,Salam J. J.; Kamounah,Fadhil S.; Abbo,Hanna S.; Hammerich,Ole
参考文献:Arkivoc (Gainesville 日期:2008 卷标:(13) 页码:91-105]

86-73-7 = 961-27-3
反应条件:1.1 Reagents: Aluminum Chloride
标题:The Influence Of Alkoxy Chain Length On The Ferroelectric Properties Of Chiral Fluorenol Liquid Crystals
作者:Roberts,Jeffrey C.; Hudson,Zachary M.; Lemieux,Robert P.
参考文献:Journal Of Materials Chemistry 日期:2008 卷标:18(28) 页码:3361-3365]

86-73-7 = 961-27-3
反应条件:1.1 Reagents: Aluminum Chloride Solvents: Tetrachloroethylene; 0 °C; 0 °C -> 25 °C1.2 Solvents: Tetrachloroethylene; 25 °C; 1.5 H,Reflux; Reflux -> 25 °C1.3 Reagents: Hydrochloric Acid Solvents: Water; Ph 1,Cooled
标题:Diphenoquinones Redux
作者:Neron,Sebastien; Morency,Mathieu; Chen,Liguo; Maris,Thierry; Rochefort,Dominic; Et Al
参考文献:Journal Of Organic Chemistry 日期:2022 卷标:87(12) 页码:7673-7695]

86-73-7 = 961-27-3
反应条件:1.1 Catalysts: Aluminum Chloride Solvents: 1,2-Dichloroethane
标题:Electron-Transport Properties And Use In Organic Light-Emitting Diodes Of A Bis(Dioxaborine)Fluorene Derivative
作者:Domercq,Benoit; Grasso,Cara; Maldonado,Jose-Luis; Halik,Marcus; Barlow,Stephen; Et Al
参考文献:Journal Of Physical Chemistry B 日期:2004 卷标:108(25) 页码:8647-8651]

= 961-27-3 [标题:Reaction Conditions
标题:Bisphenyl Compounds And Antiviral Agents Containing Them
参考文献:Japan]

= 961-27-3 [标题:Reaction Conditions
标题:Cyclic Carbonyl Compounds
参考文献:United States]

= 961-27-3 [标题:Reaction Conditions
标题:Clemmensen Reduction Of 2-Acetylfluorene. Pathways For The Formation Of 2,3-Di(2-Fluorenyl)Butane And Its Homologues
作者:Minabe,Masahiro; Yoshida,Masaaki; Fujimoto,Minoru; Suzuki,Kazuo
参考文献:Journal Of Organic Chemistry 日期:1976 卷标:41(11) 页码:1935-8]

= 961-27-3 [标题:Reaction Conditions
标题:Tricyclic Compounds
参考文献:Federal Republic Of Germany]

= 961-27-3 [标题:Reaction Conditions
标题:Chemical Carcinogenesis; Syntheses Of 2,7-Bis-(Acetamido)Fluorenes With Increased Molecular Thickness By 9-Substitution
作者:Fishel,Derry L.; Kletecka,George; Muralidhara,R.
参考文献:Ohio Journal Of Science 日期:1970 卷标:70(6) 页码:371-8

📜芴置于aluminium Chloride 乙酸酐体系中,用 1,2-二氯乙烷作为反应溶剂,化学反应生成 2-氨基-4,5-二甲氧基苯甲腈
参考文献:Cyclic Carbonyl Compounds
标题:Cyclic Carbonyl Compounds
摘要:某些氟酮和蒽醌化合物,每个化合物都在2-位被羧基或盐,酯或可选择地取代的酰胺基团取代,并且每个化合物在5,6-,7-或8-位可选择地被第二个羧基,盐,酯或可选择地取代的酰胺基团取代,氟酮化合物的5,6-,7-或8-位的取代基还可选择自氰基,卤素,硝基,烷基,烷氧基和酰基,对于缓解或预防过敏症状是有用的.