CAS: 888711-54-4; Potassium Trifluoro(Piperidin-1-Ylmethyl)Borate
该化合物是一种化学化合物,具有三氟甲基组和三氟甲基代亚基的巨型阴离子,其特性为离子性质,由钾与双子An离子配成,由离子共构成,三氟甲基组的存在具有独特的电子特性,加强了化合物在包括药用化学和材料科学在内的各个领域的回作用和潜在应用.管里丁基甲基遗传性有助于化合物的生物活动,有可能影响其与生物系统的互动.此外,该化合物在极地溶剂中的稳定性和溶解性是可能影响其在化学反应和应用中行为的重要特征.
- 英文名称Potassium Trifluoro(Piperidin-1-Ylmethyl)Borate
- 中文名称三氟(哌啶-1-基甲基)硼酸钾
- IUPAC名称potassium trifluoro(piperidin-1-ylmethyl)borate
- 其它别名(1-哌啶基甲基)三氟硼酸钾; Potassium (Piperidin-1-yl)Methyltrifluoroborate
- CAS编号888711-54-4
- MFCD编号:MFCD10566509
- EINECS号:677-252-9
- 分子式:C6H12BF3KN分子量:205.07
- 产品CID: 1909072
- 产品分类有机原料→分子砌块→脂肪杂环类化合物→哌啶类化合物
相似化合物
1268340-93-7 1187582-53-1 1602719-53-8MSDS等安全信息
- GHS象形图
- GHS符号GHS07;
注释: Exclamation mark - 危险类别急性毒性 类别4(吸入)
急性毒性 类别4(经皮)
急性毒性 类别4(经口)
特定目标器官毒性 - 单次接触 类别3
皮肤腐蚀/刺激 类别2
严重眼刺激 类别2 - 警示词Warning(警告)
- 危险描述H332 |吸入有害.
H312 |皮肤接触有害.
H302 |吞咽有害.
H335 |可能引起呼吸道刺激.
H315 |造成皮肤刺激.
H319 |造成严重眼刺激. - 防范说明P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501
欧盟法规
C&L通报合成工艺路线路线简述
- 888711-44-2 = 888711-54-4
反应条件:1.1 30 Min,80 °C1.2 Reagents: Potassium Bicarbonate Solvents: Acetone; 20 Min,Rt
标题:Cu(Ii)-Catalyzed Ortho-Selective Aminomethylation Of Phenols
作者:Dai,Jin-Ling; Shao,Nan-Qi; Zhang,Jin; Jia,Run-Ping; Wang,Dong-Hui
参考文献:Journal Of The American Chemical Society 日期:2017 卷标:139(36) 页码:12390-12393]
888711-44-2 = 888711-54-4
反应条件:1.1 Rt; 0.5 H,80 °C1.2 Reagents: Potassium Bicarbonate Solvents: Acetone; 20 Min,Rt
标题:Synthesis Of Functionalized Organotrifluoroborates Via Halomethyltrifluoroborates
作者:Molander,Gary A.; Ham,Jungyeob
参考文献:Organic Letters 日期:2006 卷标:8(10) 页码:2031-2034]
888711-44-2 = 888711-54-4
反应条件:1.1 Solvents: Tetrahydrofuran; Rt; 50 Min,80 °C1.2 Reagents: Potassium Carbonate Solvents: Acetone; 70 Min,Rt
标题:Synthesis Of Arylethylamines Via C(Sp3)-C(Sp3) Palladium-Catalyzed Cross-Coupling
作者:Lippa,Rhys A.; Battersby,David J.; Murphy,John A.; Barrett,Tim N.
参考文献:Journal Of Organic Chemistry 日期:2021 卷标:86(4) 页码:3583-3604
📜(吡啶鎓-1-基甲基)三氟硼酸盐置于potassium Hydrogencarbonate体系中,用 丙酮 作为反应溶剂,化学反应生成 (1-哌啶基甲基)三氟硼酸钾
参考文献:Reinvestigation Of Aminomethyltrifluoroborates And Their Application In Suzuki−miyaura Cross-Coupling Reactions
标题:Reinvestigation Of Aminomethyltrifluoroborates And Their Application In Suzuki−miyaura Cross-Coupling Reactions
摘要:A Reinvestigation Into The Chemical Composition Of Potassium Aminomethyltrifluoroborates Is Reported. These Trifluoroborato Salts Have Been Reassigned As Zwitterionic Ammoniomethyltrifluoroborates. Minor Adjustments To The Previously Disclosed Reaction Conditions Are Reported That Permit A Similar Level Of Activity As Nucleophiles In Suzuki-Miyaura Cross-Coupling Reactions.
DOI:10.1021/jo2001066
海关参考信息
- 2921199090-其他无环单胺
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📌 第三方产品分析报告
合成参考文献
参考文献:10.1055/s-0030-1259331
摘要:Wu Y, Wu Y, Zou D, Cui H, Qin L, Li J. Aminomethylation via Cyclopalladated-Ferrocenylimine-Complexes-Catalyzed Suzuki-Miyaura Coupling of Aryl Halides with Potassium N,N-Dialkylaminomethyltrifluoroborates. Synlett. 2011 Jan 19;2011(03):349–56. doi: 10.1055/s-0030-1259331.
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